盐酸羟胺自氧化法测定SOD活性的电化学方法研究

盐酸羟胺在碱性水溶液中发生自氧化反应,可产生O2-.,其自身被氧化为亚硝酸根离子,在酸性介质中SCN-催化亚硝酸根离子与二苯胺-4-磺酸反应生成具有电活性的亚硝基化合物在-0.60V处有一波形很好的二阶导数极谱峰。在一定条件下,极谱峰电流的大小与亚硝酸根离子的浓度呈线性关系。体系中加入SOD,使生成的亚硝酸根离子的量减小。由此建立了通过检测亚硝酸根离子的生成量来测定超氧化歧化酶活性的电化学方法,测定了酶活力曲线,并研究了常见的黄酮类化合物对O2-.的清除作用。     

Fast and accurate measurement of diffusion coefficient by Taylor’s dispersion analysis

This investigation aimed at improving the performance of Taylor's dispersion analysis for the fast and accurate measurement of diffusion coefficient of a minute solute in various solvents. The investigation was carried out on a capillary electrophoresis instrument by monitoring the UV absorption peak of a solute pulse and calculating the diffusion coefficient by peak efficiency. With L-phenylalanine as a main testing solute, some key factors were afterward disclosed including especially the capillary size, carrier flow velocity, injection volume and capillary conditioning. Peak tailing, large volume of sample injection and slow migration were found to underestimate the diffusion coefficient while very fast migration and high sample concentration caused overestimation. At a moderate flow velocity of 0.1―1 cm/s with a capillary of 72.44 μm I.D.×60 cm (50 cm effective) maintained at 25℃, the diffusion coefficient of aqueous L-phenylalanine was determined, giving a value of 7.02×10-6 cm2/s with error＜2% and relative standard deviation＜0.2% (n=3). The method was shown to be applicable to the measurement of various samples such as aqueous phenylalanine, acetone, phenol, toluene and benzene, and nonaqueous benzene (in ethanol or 1-butanol).     

Energetic particle radiations measured by particle detector on board CBERS-1 satellite

Using the data measured by energetic particle detector on board CBERS-01 and -02 for the past five years, statistics was made to show the general features of MeV electrons and protons along a solar synchronous orbit at an altitude of 780 km. This height is in the bottom region of the Earth's radiation belts. Detectors are inside the satellite cabinet and such continuous monitoring of particle radiation environment inside a satellite has seldom conducted so far. After a proper and careful treatment, it is indicated that the data inside satellite are well correlated with the radiation environment outside. Be-sides the agreement of the general distribution characteristics of energetic electrons and protons with similar observations from other satellites, attention is particularly paid to the disturbed conditions. Variations of particle fluxes are closely related with solar proton events, in general, electron fluxes of outer belt are well correlated with Dst index after three days' delay while the electron injection occurred almost at the same day during great magnetic storms. It is confirmed that both energetic electrons and protons appear in the Polar Cap region only after the solar proton events.     

单节锂离子电池保护电路的改进

提出了一种低成本的单节锂电池保护回路系统,采用0.6μm混合信号CMOS工艺和修调技术使芯片具有低功耗、高精度检测电压等特点.通过基准电路和取样电路设计的改进,使保护电路实现了多种保护功能,并且具有很高的检测电压精度.模拟结果表明,该电路在温度为25℃时过充电保护电压的检测精度达到了±25mV,耗电流仅为3.5μA,满足高精度检测电压的要求.     

机械产品功能建模及其求解策略的研究

简要阐述用于产品功能建模的标准功能基(SFB),并在SFB基础上完成产品功能建模;建立包括元功能层、功能对象层、行为层、结构组件层和结构关系层的功能求解模型,提出多层次柔性求解策略用于完成从功能到结构的映射;以实例对所提出的方法进行验证。     

Blurred Defocused Image Restoration Based on FRFT

A technique for restoring the blurred image resulted from defocusing of the lens is proposed in this paper, which is based on fractional Fourier transform （FRFT）.The FRFT, as a powerful tool for the analysis of time-varying signals, is closely connected with the optical imaging system. FRFT also can describe optical imaging process just like Fresnel diffractions, so a defocused imaging model based on FRFT is established to explain the blur phenomena of defocusing image. The defocused imaging model is greatly different from the traditional point spread function （PSF） model, and enables to uncover the blur nature of non-focus image. Then, an image restoration method using the novel model is proposed to handle the blurred defocused image. The method adopted a new iterative phase retrieval approach which can approximately estimate phase signals from intensity signals of a single defocused image by means of FRFT. Restoring image may acquire sharp image by implementing inverse FRFT on complex image signal made from the estimated phase signals and intensity signals. Experimental results demonstrate that the method is effective in restoring blurred defocused image.     

Investigation of Highly Designable Dented Structures in HP Model with Hydrogen Bond Energy

Some highly designable protein structures have dented on the surface of their native structures, and are not full compactly folded. According to hydrophobic-polar （HP） model the most designable structures are full compactly folded. To investigate the designability of the dented structures, we introduce the hydrogen bond energy in the secondary structures by using the secondary-structure-favored HP model proposed by Ou-yang etc. The result shows that the average designability increases with the strength of the hydrogen bond. The designabilities of the structures with same dented shape increase exponentially with the number of secondary structure sites. The dented structures can have the highest designabilities for a certain value of hydrogen bond energy density.     

浅谈公路旧桥的加固

作者根据近年对超限运输桥梁及大中型桥梁的加固实践经验,介绍了公路旧桥各组成部分的加固方法和施工措施。     

PVDF介电吸收电流的研究

研究了0℃和35℃下PVDF样品的吸收电流,发现吸收电流和释放电流不相等,所遵循的规律也不相同。吸收电流依赖于样品的历史,与样品的老化有关,遵从随机驰豫规律。依照铁电陶瓷受束缚的空间电荷激活模型,及结晶高聚物与铁电陶瓷空间电荷分布的类似性,上述现象可得到解释。     

二维主同的变换及其存在和唯一性证明

由于主同的变换能消除各次采样相对目的物的平移、旋转和比例放缩所产生的对数据组的影响而简化了数据的处理过程,因而在模式识别和数据处理中得到了应用,本文给出了二维主同的变换的具体形式及其存在和唯一性的证明。