Electrochemical behavior of a series of azobenzene self-assembled monolayers on gold

Conclusion This work shows that the structures of C_n AzoC₂ (n = 1, 2, 3, 4) SAMs are significantly different and influence the observed electrochemical behavior of these novel azobenzene systems. The sluggish electron-transfer kinetics of azobenzene SAMs were explained by the alkyl spacer between azobenzene and electrode, the spatial inhibition for structural change in the redox process of azobenzene, as well as the ion-transportation barriers. For decrease of the apparent electrontransfer rate constants with increasing the length of end-groups, and the electrochemical inaccessibility of C₄AzoC₂ SAMs, the spatial inhibition for structure conformational change and ion-transportation was considered as the predominant factor.     

Organic solvents enhanced spectrofluorimetric method for determination of laccase activity

A novel fluorimetric method for determination of laccase activity in organic solvents is proposed, based on the oxidation ofo-phenylenediamine (1,2-diaminobenzene, OPDA) catalyzed by laccase yielding 2,3-diaminophenazine. The optimal conditions for laccase in organic media areT=55°C, pH=6.5, 1.0×10⁻²mol/L OPDA, 1.25 mL ethanol, 1.25 mL 1,4-dioxane and 1.25 mL acetone. The linear range of the method proposed in ethanol, 1,4-dioxane and acetone media were 0.44–19.33, 0.11–20.85, 0.38–21.05 U with the detection limit of 0.088, 0.022, 0.076 U, respectively. The proposed method has been applied to the analysis of laccase activity of real samples with more accurate and sensitive than that of the previous method reported. Supported by the National Natural Science Foundation of China and the Special Founds of State Education Committee for Doctorate Research Huang Zuyun: born in 1963, Ph.D     

The dissociation of nickel-oxine in surfactant micelles

The dissociation kinetics of Ni complex (NiL₂) of Oxine (HL) by H⁺ was investigated in neutral (Brij-35), cationic (CTAN), and anionic (SDS) micelles. The kinetic results have been interpreted by using the distribution model. The relevant distribution constants were determined independently by spectrophotometry. Supported by Natidnal Science Foundation of China Cai Ruxiu: born in Nov. 1939, Professor     

关于虚位移独立性的研究

从虚位移方程的基础解系出发探讨虚位移的独立性，并根据Четаев定义将其结果推广到高阶非完整系统。同时，根据对实位移的相应讨论，明确指出实位移是不相互独立的。     

己内酰胺与酰氯和酸酐反应的研究

己内酰胺在碱性介质中与酰氯反应,生成 N—酰基取代己内酰胺,后者也可以用相应的酸酐与己内酰胺在加热条件下制得。己内酰胺与等摩尔的邻苯二甲酰氯在碱性介质中的反应产物经水解后,和己内酰胺与等摩尔的邻苯二甲酸酐在加热条件下制得的产物不同。本文应用有机合成法并侧重用近代波谱解析阐明上述各步反应中的产物分子结构,澄清了文献中的分岐,合成了一些新化合物,提出上述有关反应的机理。     

工业企业热电联产系统评价准则的研究

评价热电联产系统的准则可分为能量利用性评价准则,经济性评价准则,以及能量利用与经济性相结合的评价准则。本文对现有各种准则进行了分析,找出了适用于评价工业企业热电联产系统的能量利用性准则和经济性准则,并在此基础上提出了新的能量利用与经济性相结合的评价准则——修正净现值。该新准则适用于评价工业企业热电联产系统,而现有的该类准则只能评价区域性热电厂。     

川西南山地轮歇地、撩荒地与荒芜人工草地的群落结构研究

本文论述了川西南山地不同演替阶段,不同人为影响下的轮歇地、撩荒地及荒芜人工草地的环境生态,植物种类组成,群落数量特征,优势度与生产能力,特别比较了不同演替年限的植被经济类群比例。着眼于合理利用,提出通过人工生态因素的渗透促进植被的进展演替和重建优化的次生群落。     

通信网的过载及其控制

网络过载是影响网络效率、造成长话接通率降低的一个重要原因.本文通过对网络过载的模拟,分析了过载的特性及其导致拥塞的原因,探讨和比较了两种过载控制方法的有效性.     

高维时空中静态和慢旋转球体的内解

本文从高维 Einstein 场方程导出了高维 Tolman 方程,从而得到了高维时空中静态球体的一个解析内解。从这个解得到的状态方程为 P=αρ,α为与时空维数有关的常数.另外还利用这个解析的静态内解得到了匀速慢旋转和带特殊旋转函数流体球的二个解析内解。     

一个确定吸收介质特征参量的方法

提出了一个能同时测定横向弛豫时间T_2,小信号吸收系数α_0和饱和光强I_(?)等吸收介质特征参量的简单方法.用可调谐CW CO_2激光和SF_6气体为样品的实验证实了我们的理论分析结果.实验测得对SF_6(0.2托)T_2=1.24×10~(-11)s,α_0=0.27cm~(-1),I_(?)=1.11W/cm~2.