Synthesis and luminescence properties of Mn4+-dopant Ca14Zn6Ga10−xAlxO35 solid solution

Mn~(4+)-activated oxide phosphors,owing to their desirable spectral features,eco-friendly and low cost,are emerging as a new class of non-rare-earth red phosphors for warm white LEDs.However,these phosphors possess low photoluminescence quantum efficiency excited by blue chip currently.Herein we report an isostructural solid solution of Ca_(14)Zn_6Ga_(10-x)Al_xO_(35):0.15Mn~(4+)(0≤x≤10)synthesized by a traditional solidstate reaction route.The microstructure and luminescent performance of this red-emitting phosphor are investigated in detail with the aids of X-ray diffraction,diffuse reflection spectra,photoluminescence spectra/decay/QE,and temperature-dependent PL/QE measurements.Blue shift of energy peaks of~4A_2→~4T_1and~4A_2→~4T_2transition is illustrated by the Tanabe–Sugano diagram and the configurational coordinate diagram.The crystal field strength(Dq)and the Racah parameters(B and C)are carefully calculated to estimate the nephelauxetic effectβrespectively.Particularly we achieve external and internal quantum efficiencies as high as26.1%and 40.3%for Ca_(14)Zn_6Ga_6Al_4O_(35):0.15Mn~(4+)excited by 466 nm,the highest one ever reported in Mn~(4+)activated oxide phosphors under the similar condition.     

A New Method with High Confidence for Validation of Computer Simulation Models of Flight Systems

Computer simulation models may by used to gain further information about missile performance variability. Model validation is an important aspect of the test program for a missile system. Validation provides a basis for confidence in the model's results and is a necessary step if the model is to be used to draw inference about the behavior of the real missile. This paper is a review of methods useful for validation of computer simulation models of missile systems and provides a new method with high degree of confidence for validation of computer simulation models of missile systems. Some examples of the use of the new method in validating computer simulation models are given.     

维修性评定

对维修时间服从指数、正态、对数正态分布的情况,本文给出了评定维修性、MTTR、最大维修时间、中位维修时间的置信上(下)限方法。     

增加XENIX系统屏幕编辑命令的文件加密功能

本文叙述了一种在XENIX系统中为屏幕编辑命令增加文件加密功能的实现方法及途径。     

Chiral <Emphasis Type="Italic">N</Emphasis>-formyl amino alcohol as Lewis basic organocatalyst for enantioselective hydrosilylation of ketimines

Easily accessible (1R,2S)-1,2-diphenyl-2-formamidoethanol has been developed as an effective Lewis base catalyst in the enanti-oselective hydrosilylation of ketimines, affording high isolated yields (up to 94%) and moderate to high enantioselectivities (up to 82% ee) for a broad range of ketimines.     

基于小型无人机的高位危岩快速调查与稳定性评价

危岩体多孕育于高陡岩质斜坡之上,具有明显的隐蔽性和突发性,其早期的快速识别与稳定性评价一直是地质灾害防治工作中重要的技术难题之一.以重庆万州狮子头为例,利用小型无人机合理规划航线获取高清影像,生成二三维模型.通过遥感信息提取技术与地质灾害分析相结合,为危岩体稳定性研究提供基础数据.运用图像识别技术识别危岩体结构面,并利...     

扇形内翅片石墨管层流强化传热性能

利用数值模拟方法对一种高黏度的油类介质在6种不同布置交错角度(0°,30°,45°,60°,75°,90°)的扇形内翅片石墨换热管中层流的强化传热和流动规律进行了研究.结果表明,扇形内翅片的强化换热效果明显.与无翅片的石墨换热管相比,6种布置角度的扇形内翅片对流换热系数分别增大22.69%,42.49%,62.28%,63.44%,65.47%,66.47%.就流动性能而言,扇形内翅片的石墨管6种布置角度下的阻力分别增大了191.88%,252.01%,333.10%,364.33%,385.51%,400.43%.为了明确石墨管内添加扇形内翅片后的强化传热效应,采用了换热性能评价指标(PEC)对6种布置角度进行了评价研究,结果显示45°布置角度时PEC评价准则数的平均值达到最大,为1.265,说明布置角度为45°时强化换热效果最理想.     

产业结构地区分类方法及应用

为了把各地区按产业结构的相似程度进行分类，以确定相应的经济区域，本文采用了地区间产业结构的相似程度指标构造相似关系矩阵，然后把它转化为对称的０－１矩阵。最后通过运用对称的０－１矩阵的性质，把地区按产业结构的相似性分成若干类。应用实例说明，这种分类方法是可行的和有用的。     

基于声压测量的结构模态参数识别研究

为克服接触式测量传感器附加质量的影响,本文采用非接触式声压测量获取结构近场的辐射声压信号,提出Hilbert-Huang变换二次滤波时频分析方法对非平稳的近场声压辐射信号进行分析,实现了在强噪声环境中对桥梁结构模态参数的识别。在实验室对一跨径为11.2m的H型简支钢梁开展试验,结果表明：该方法能准确识别钢梁的前3阶固有频率,平均误差在0.5%以内,并成功获取结构的模态振型。该方法为桥梁结构模态参数获取和结构健康监测提供新的手段。     

溶解性有机质-四环素-Zn共存体系中土壤对四环素和Zn的吸附作用

以畜禽粪便中的典型组分——溶解性有机质、四环素和锌作为研究对象,以东北典型黑土为供试土壤,采用批次实验法,研究了溶解性有机质、四环素和锌三元混合体系中土壤对四环素和锌的吸附作用。结果表明,土壤对四环素的吸附符合Freundlich吸附模型,土壤对Zn的吸附既符合Langmuir吸附模型,也符合Freundlich吸附模型;四环素和锌之间存在着相互促进吸附的作用;溶解性有机质抑制了四环素在土壤上的吸附,促进了Zn在土壤上的吸附;在溶解性有机质-四环素-Zn混合体系中,四环素和溶解性有机质共存促进了Zn的吸附;而对于四环素的吸附,溶解性有机质和Zn的共存可以表现为促进作用,也可以表现为抑制作用,二者的相对浓度是决定其作用的关键因素。