The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

卤化物与水玻璃复合物的抑尘性能

在恒温箱中测定了粉尘试样添加ＣａＣｌ２或ＭｇＣｌ２和水玻璃后的含水率与环境温度、湿度、有效抑尘时间等因素之间的关系．研究结果表明：（１）当环境温度低于３１℃，相对湿度高于６０％，粉尘试样中ＣａＣｌ２和水玻璃含量的质量分数分别达到２０％和１０％（ＭｇＣｌ２和水玻璃含量的质量分数为２３％和１１．５％）时，试样的含水率就能保持大于５％（质量分数）；（２）当环境温度低于４０℃，相对湿度高于５０％，粉尘试样中ＣａＣｌ２和水玻璃含量的质量分数分别达到２６％和１３％（ＭｇＣｌ２和水玻璃含量的质量分数为３０％和１５％）时，试样的含水率就能保持大于５％（质量分数）；（３）ＣａＣｌ２或ＭｇＣｌ２与水玻璃复合后，其粘尘功能进一步增强，而且其溶液的弱酸性得到进一步降低。     

一种动态载荷的识别方法

提出了一种逆优化系统识别动态载荷的方法。该方法避免了一般载荷识别中频响函数求逆运算中由于矩阵病态而引起的运算及运算失败，从而提高了识别精度，为动态载荷，特别是宽频带、瞬态冲击载荷的识别提供了一种有效途径。     

小波变换及图象的VQ压缩

利用小波变换可实现图象的多分辨率分解，但分解后数据量并没有得到压缩，用ＶＱ对分解后的细节图象进行编码时，根据分解后矢量的均值，方差分类设计码本，该方法不但可有效地提高编码时搜索速度，而且重建后图象的也有所提高。     

MSEM增压系统一维非定常流计算模型的改进

对ＭＳＥＭ增压系统一维非定常流数值模拟中影响计算精度的四个主要因素：气阀端、变截面段、质量添加段及计算时间步长进行了分析，并提出了改进措施。计算结果表明，流量误差得到显著减小。     

A STUDY ON FLORISTIC FEATURE AND DIVERSITY OF DEHANG REGION SEED PLANTS IN HUNAN

1IntroductionDehangisascenicspotlocatedatthesouthofWulingMTsintheCentralChil1a,between2815'and2843'N,lo93o'andlO945lE,risingfroml89.4mto964.6mabovesealevel,withanareaof225km.Thisre-gionhasacomplicatedtopography.Itissituatedinsubtropicmonsoonclimateareaandrichinlimestone.Ev-ergreebroad-leavedforest,Bambooforestandlowsimountainevergreenconiferousforestaremainvegeta-tionshere'Moreover,Miaonationalitypeoplehhvebeenlivinghereforalongtimeanditenjoysgreatnation-a1navour.Thenoraisrichandthevegeta…     

JG工艺协作计算机报价系统的研制

介绍一个齿轮类工艺协作计算机报价系统．作者意图是使企业在工艺协作中，报价合理、规范和快速．文中较详细地介绍了系统的特点和各类模块功能．     

Binding Sites of La~(3 ) on Camodulin

ＢｉｎｄｉｎｇＳｉｔｅｓｏｆＬａ３＋ｏｎＣａｍｏｄｕｌｉｎ＊ＦｅｎｇＹｕｐｉｎｇ（冯玉萍），ＹｕａｎＨａｏｄａｎ（袁浩丹）＋，ＺｈｏｕＹｕｘｉａｎｇ（周玉祥）＋，ＮｉｎｇＹｏｎｇｃｈｅｎｇ（宁永成），ＺｈａｎｇＲｉｑｉｎｇ（张日清）＋Ｄｅｐａｒｔｍｅ...