四角场S=2离子ZFS高阶微扰公式的收敛性

本文以~５Ｂ＿２为基态，在强场图象下用微扰理论推导出了轴向零场分裂参量Ｄ的１到４阶微扰计算公式（~５Ｄ近似），并就公式的微扰收敛性进行了系统的讨论．通过计算和分析表明，当第一激发态靠近基态使得其能量与旋轨耦合常数ζ可比拟时．微扰公式是发散的．这时，微扰近似方法将不再有效。但在大多数情况下，公式保持有较好的收敛性．同时，给出了使微扰松式有效的晶场参量Ｄ＿９、δ和μ的近似取值范围，为~５Ｄ近似公式的应用提供了有价值的参考。     

THE TRANSFER BEHAVIOUR OF SOME CATIONS AT WATER／NITROBENZENE INTERFACE BY SEMIDIFFERENTIAL CYCLIC VOLTAMMETRY

The transfer of Sr~(2+) and Ba~(2+) ion, facilitated by 18-Crown-6 present in the aqueous phase, and of succinylcholine ion at w/nb interface were investigated by semi-differential cyclic voltammetry. A good polarographic curve of succinylcholine ion dissolved in water was obtained in the system of 0.01 mol/l LiCl (w)——0.01 mol/l TBATPB (nb). The peak current is directly proportional to the concentration of SC~(2+) ion. It can be used for the determination of SC and the detection limit is 1.05×10~(-5) mol/l.The apparent D~w and D~(nb) have been estimated. The transfer of Sr~(2+) and of Ba~(2+) at the interface are facilitated by 18-Crown-6 present in the aqueous phase and the peak current is directly proportional to the concentration of 18-Crown-6 in water. This method can be used for the determination of the complexing agent and for the stability constant of the complex formed in the aqueous phase.All the experimental results are in keeping with the theoretical.     

杂环基二硅烷的合成与波谱表征

由2—噻吩基锂和N-吡咯格氏试剂分别与氟五甲基二硅烷反应,制得了2—噻吩基、五甲基二硅烷(Ⅰ)和N-吡咯基五甲基二硅烷(Ⅱ)。两种二硅烷都是无色液体。Ⅰ在室温下空气中是稳定的,Ⅱ在空气中逐渐转变成绿褐色。元素分析,IR,~1H MR和MS分析证实了其结构。Ⅰ和Ⅱ的最大紫外吸收峰分别为242.0nm和220.1nm。     

关于C_(11)A_7·CaF_2稳定性的研究

本文采用X射线衍射分析方法,研究了影响C_(11)A_7·CaF_2稳定性的因素,结果表明C_(11)A_7·CaF_2在1450℃以内,能够稳定存在;Mgo,K_2O对C_(11)A_7·CaF_2稳定性没有影响;Na_2O、P_2O_5和CaO能与C_(11)A_7·CaF_2发生反应、分别生成少量NC_6A_3、Ca_5F(PO_4)_3和C_3A,但在硅酸盐水泥熟料的正常煅烧制度下,反应程度较低,对C_(11)A_7·CaF_2稳定性不大.熟料中铝酸盐相存在的形式,主要取决于氟在熟料中的分布,CaF_2掺量较低,温度超过1350℃,C_(11)A_7CaF_2消失,生成C_3A;CaG_2掺量较高时,温度高达1450℃,熟料中的铝酸盐相仍为C_(11)A_7·CaF_2,而不生成C_2A.     

科斯社会成本问题与政府管制的效率实现

科斯在其社会成本一文中提出经济行为具有相互性,并很好地将交易成本理论运用在经济行为中,通过交易成本为零的理想世界到交易成本为正的现实世界进行条件转换分析,提出了外在性存在的根源及解决途径主要包括自愿协商(市场)、企业、政府和法律四种;提出由市场解决不好的问题,不一定政府就解决的很好;提出应从社会净收益最大化的角度来看,关键在于避免较严重的损害的观点,即如何使损失最小化或使社会经济运行效率最大化。他的这些思想,使经济学家注意到了交易成本的各种后果,大大地提高了经济的解释力。为政府更有效地进行管制提供了理论支撑。     

新世纪图书馆员社会角色转换研究综述

就近几年图书馆界关于新世纪馆员意识转换及社会角色转换等方面的研究进行了综述，指出新时期的馆员要实现自我社会角色的转换，首先是要明确转换的必要性，然后采取有效的策略逐步地、系统地推进转换，才能取得较好的效果。     

整机老炼条件的优化设计

本文通过工程实例，阐述如何利用现有信息来设计产品的老炼条件，以使它在保证产品达到规定可靠性的前提下尽量节省成本     

The behavior of the homozygous and heterozygous sub-types of rats which are genetically-selected for diabetes insipidus: A comparison with Long Evans and Wistar stocks

Several aspects of spontaneous and conditioned behavior (food and water intake, locomotion and emotionality, passive and active avoidance acquisition and retention) of standard (albino and pigmented) rats, and rats heterozygous (HEDI) and homozygous (HODI) for diabetes insipidus, are reviewed. As would be expected, HODI rats have been repeatedly found to consume far more fluid than either HEDI or control rats. Pigmented rats appear to be more active than albinos. HODI rats exhibit less marked emotional responses than do control rats, among which the pigmented ones exhibit the highest emotionality. Light aversion is more evident in albino than in pigmented rats. No differences are found among HEDI, HODI and normal Long Evans rats. It is quite difficult to provide a clear-cut statement concerning inter-strain differences in passive avoidance behavior, possibly because of the variety of techniques employed. In any case, HODI rats do not perform worse than normal controls do. In one-way active avoidance paradigms, pigmented rats perform better than albinos, and the performance of HODI rats does not differ from that of controls. In two-way avoidance paradigms, albinos appear to outperform pigmented rats. Once again, there are no obvious differences between HODI and control animals.In addition to indicating that HODI rats may actually be less emotional than the other groups of rats reviewed here, the studies described once again fail to confirm the previously alleged functions of vasopressin in memory consolidation.     

粘合衬对服装舒适性影响的研究

探讨了粘合衬与粘合工艺对服装透气性、透湿性及透水性影响的规律。得出服装的舒适性虽由面料决定,但辅料(粘合衬)的影响也不可忽视。粘合衬的涂胶种类,粘合衬本身的透气性与透湿性,以及非织造粘合衬底布的单位重量,机织粘合衬底布的覆盖系数等,均对服装舒适性有影响,从而为衬料的选择,以及粘合工艺参数的设定,提供了依据。     

乙烷—丙烷混合裂解模型及产率预计

本文研究了乙烷和丙烷的混合裂解,并与乙烷、丙烷单独裂解进行了比较。解决了微分方程组的刚性问题,提出了混合裂解反应动力学模型。明确了三种选择性的概念,即;真实选择性、迭加选择性和总选择性,从而澄清了国际上对于选择性有正偏差和负偏差的不同观点。为乙烯生产提供了有效利用乙烷和丙烷的分析评价方法。