Research progress in ZnO single-crystal: growth,scientific understanding,and device applications

Zinc oxide, a wide band-gap semiconductor, has shown extensive potential applications in high-efficiency semiconductor photoelectronic devices, semiconductor photocatalysis, and diluted magnetic semiconductors. Due to the undisputed lattice integrity, ZnO single crystals are essential for the fabrication of high-quality ZnO-based photoelectronic devices, and also believed to be ideal research subjects for understanding the underlying mechanisms of semiconductor photocatalysis and diluted magnetic semiconductors. This review, which is organized in two main parts, introduces the recent progress in growth, basic characterization, and device development of ZnO single crystals, and some related works in our group. The first part begins from the growth of ZnO single crystal, and summarizes the fundamental and applied investigations based on ZnO single crystals. These works are composed of the fabrication of homoepitaxial ZnO-based photoelectronic devices, the research on the photocatalysis mechanism, and dilute magnetic mechanism. The second part describes the fabrication of highly thermostable n-type ZnO with high mobility and high electron concentration through intentional doping. More importantly, in this part, a conceptual approach for fabricating highly thermostable p-type ZnO materials with high mobility through an integrated three-step treatment is proposed on the basis of the preliminary research.     

Dynamic analysis of DNA damage induced miRNAs in colon cancer cells

It is known that microRNAs （miRNAs） expression profile shows substantial changes in cells under DNA damage. Here, we did miRNA microarray and quantitative real-time PCR to comprehensively identify the differentially expressed miRNAs in colon cancer cell lines HCT116 p53＋/＋ and HCT116 p53-/-. Cluster analysis revealed a panel of differentially expressed miRNAs which are regulated by p53 and/or UV-C induced DNA damage. These altered miRNAs tend to be located in chromosomes 13, X and 17. Moreover, pathways enrichment analysis estimated that MAPK pathway, focal adheren pathway, p53 pathway and Wnt pathway were mediated by these miRNAs to exert their functions in DNA damage response. Additionally, we found that miR- 320a, one of the UV-C induced miRNAs, play a role in protecting cells from DNA damage. Taken together, our results show that miRNAs are dynamic regulated in p53- dependent or -independent manners in different cell contexts and different situations following DNA damage.     

Stable silver nanoparticles–aptamer bioconjugates for cellular prion protein imaging

Combining the unique optical properties of metal nanoparticles and the specific recognition of aptamer,aptamer–nanoparticle conjugates have been extensively used in a wide range of applications,particularly multifunctional nanoparticles for cell detection and molecular imaging.Conventional conjugates prepared by chemisorption of monothiol-modified oligonucleotides onto nanoparticle surfaces suffer from a lack of stability when exposed to a variety of small molecules.If silver is used in place of gold,then this lack of stability is even more pronounced.In this study,we reported here the effective and facile strategy of preparing stable silver nanoparticle–aptamer conjugates by in situ generation of strong metal affinity capping ligands,dithiocarbamates modified anti-prion protein aptamer.The conjugates produced are stable and can withstand NaCl concentration at0.25 mol/L.Meanwhile,they could be applied in the cellular prion protein imaging successfully.     

金属离子负载树脂对水中氨氮的吸附特征

研究了金属离子负载树脂对水中氨氮的吸附特征.金属离子负载树脂对氨氮的吸附等温线表明,温度的升高有利于吸附,且吸附等温线都符合Langmuir模型.两种金属离子负载树脂对氨氮的吸附都符合准二级动力学方程.     

广西大瑶山野生绞股蓝六种无机元素的测定

目的：对广西大瑶山野生绞股蓝茎、叶中的六种无机元素进行测定.方法：采用湿法消化法和原子吸收法进行研究.结果：广西大瑶山野生绞股蓝茎、叶中六种元素含量差异较大,叶中的含量明显高于茎中的含量,所测的六种元素的含量依次为：Ca〉Mg〉Fe〉Mn〉Zn〉Cu.结论：广西大瑶山野生绞股蓝六种无机元素的含量较为丰富,可以满足人体的需要,本研究为探讨无机元素与绞股蓝药理作用之间的关系提供了可靠的依据,为绞股蓝药物开发提供了方向.     

乙酰胆碱结构含磷类似物的定量构效关系的最大重叠布居研究

在前文中,我们初步提出了一个涉及农药分子整体结构的新型定量构效关系的抽象表达式。为了具体运用该式,我们首先优化了乙酰胆碱分子的几何构型,并对一些生物活性很好的与乙酰胆碱分子结构特征相似的有机磷酸酯分子进行了构象分析和部分电荷分布计算,从而定性说明了个别分子的抗胆碱酯酶活性。本文运用前文构象分析所得到的分子几何构型,进行全面的最大重叠布居原理的计算,求出各分子中每个原子的净电荷(其中求     

配位场理论的不可约张量方法研究——群与子群的不可约张量算子约化矩阵元间的关系式及其作用

本文运用唐敖庆等引入的群到子群V系数,首先导出了群的不可约张量算子约化矩阵元与其子群的不可约张量算子约化矩阵元间的简单关系式。由此关系式出发,进一步导出了更为一般的广义Wigner-Eckart定理,得到了不同的群到子群V系数间的普遍关系式,从而使不可约张量方法对配位场问题的理论处理更加灵活,方便。     

含有多个配体的杂化与Pauling的成对-缺陷-求和近似<正>

本文报道了对于以前的工作所做的一般化处理,以前的结果仅限于分子ML_k有两个配体(k=2)的情况。现在推广到k>2的情况。假设分子中任意两键M—L_p和M—L_q间的夹角α都相同,我们得到了一些关于对角阵D(λ)酉阵U~T,重迭阵S_1和键强度F的一般公式,还讨论了SS~T的性质,进而由最大重迭法给出了Pauling的成对一缺陷一求和近似的一个理论证明,这表明,Pauling的近似对于键强的估算是很好的。     

稻米粘、糯品质差异及与淀粉酶同工酶关系的初探

本文对我省当前推广的主要粘、糯品种及孝感市农科所近年有成的早籼型粘糯品系作了品质和淀粉酶同工酶的分析。结果表明:(1)粘、糯品质主要表现在直链淀粉含量,米胶稠性、胶化温度、米饭膨胀性不同.(2)直链淀粉、胶化温度在一定范围内与米饭伸延性、发饭率呈正相关;胶稠度在一定范围内与米饭膨胀性呈负相关;总淀粉与蛋白质有互为消长趋势。(3)萌发时胚乳淀粉酶同工酶:Amy—Ⅲ带:粘稻多数品种表现为暗带,而糯稻多数品种表现为窄红带.Amy-Ⅳ带:糯比粘表现较红的颜色。红色的深浅与直链淀粉含量有负相关趋势。     

高强钢的应力腐蚀与高强螺栓的延迟断裂

应用断裂力学的观点和方法缺究和分析了高强螺栓延迟断裂的原因及其规律,并提出了预防的措施和方法。主要内容有：1、应用恒位移缺口试样,模拟标准螺栓联接在服役条件下所产生的峰值应力,对七种强度级别的35CrMnsiA钢在四种介质中(纯水,3.6%NaCl水溶液,新三磺泥浆、老三磺泥浆)的应力腐蚀裂纹萌生规律进行了研究。发现:当强度限 135kg/mm2,缺口根部不会萌生应力腐蚀裂纹。而当 140kg/ mm2 ,缺口处极易产生裂纹。2测试了35CrMnsiA钢在四种介质中的应力腐蚀裂纹扩展速率 与止裂界限应力强度因子KISCC。结果发现:当 135kg/mm2,随强度限的降低,KISCC有明显的升高,而 则大幅度的下降。当 140kg/ mm2,KISCC。及 随强度的改变而变化的规律都不明显。四种介质中的KISCC相差不大。当 140kg/ mm2,纯水中的 比其余三种介质中的要快的多,是盐水中的2～6倍。当 135kg/ mm2,它们的差别逐渐减小,直至全部趋近于零。3、螺栓各不同部位的应力强度因子Kl是不相同的,但Klmax。二则可能发生于二个地方,即螺纹的收尾处及与螺母(桩)相配合且距支承约2/3螺距处。由于拉弯复合作用,前者比后者可能要大。当丝扣根部有0.5mm裂纹,则对中碳低合金高强钢,只有取。 120kg/ mm2才能保证Kl。