Thermodynamics and kinetics of extracting zinc from zinc oxide ore by the ammonium sulfate roasting method

Thermodynamic analyses and kinetic studies were performed on zinc oxide ore treatment by (NH₄)₂SO₄ roasting technology. The results show that it is theoretically feasible to realize a roasting reaction between the zinc oxide ore and (NH₄)₂SO₄ in a temperature range of 573-723 K. The effects of reaction temperature and particle size on the extraction rate of zinc were also examined. It is found that a surface chemical reaction is the rate-controlling step in roasting kinetics. The calculated activation energy of this process is about 45.57 kJ/mol, and the kinetic model can be expressed as follows:1-(1-α)1/3=30.85 exp(-45.57/RT)·t. An extraction ratio of zinc as high as 92% could be achieved under the optimum conditions.     

精细控压钻井溢流检测及模拟研究

针对现有钻井过程中溢流检测方法无法检测微溢流量,对深井和复杂井井控提出挑战,展开了精细控压钻井 溢流检测及模拟研究。研究中通过对比出入口微流量变化,提出了精细控压钻井溢流检测和分析方法;根据气液两相 流理论,建立了井筒气侵期间流动计算模型。将该检测方法应用于塔中某井进行试验,结果表明：精细控压钻井系统 溢流检测方法可以准确检测溢流的发生和累积溢流量;根据气液两相流模型,可以模拟精细控压钻井不同回压时井筒 流动参数的变化;该检测方法在现场试验中检测结果和模拟结果一致。精细控压钻井系统溢流检测方法能够准确检 测溢流发生,该检测方法具有可行性和可靠性,可对控压钻井发现和控制溢流提供了理论支持。     

围垦工程群对杭州湾南岸累积水动力影响分析

以杭州湾南岸为研究对象,分别建立1997年、2007年和2015年杭州湾海域二维水动力数值模型,计算并对比各年份水动力场。从高潮位、漫滩流和流速大小三个角度来分析杭州湾大范围、累积的围垦工程对杭州湾南岸的影响。结果显示,特征点高潮位均有不同程度的抬升,自西往东呈降低趋势;围垦工程导致杭州湾南岸漫滩流特性有所减弱;大部分南岸近岸海域涨、落急流速均有不同程度的降低,并且南岸近岸海域涨急流速有较为明显的累积效应。     

利用运行状态信息的机床刀具可靠性预测方法

针对数控机床类退化失效型设备,提出了一种基于设备运行状态信息的可靠性预测方法,主要包括状态特征指标选取、瞬时可靠度计算以及神经网络预测模型的建立和应用.其中,瞬时可靠度计算是准确预测的关键,结合Bayes方法和KM估计器思想提出的基于状态特征指标比例关联关系的瞬时可靠度算法简单高效.针对刀具加工过程中的磨损量时变数据,以可靠度为评价标准,正确预测出了刀具的失效时间,该过程表明设备状态信息用于可靠性预测的可行性和有效性,是未来可靠性发展的一个重要方向.     

外部治理机制对上市公司应计质量影响的实证研究

以2002～2004年深沪两市所有A股上市公司为基础,检验了外部治理机制对上市公司应计质量影响.研究发现:市场中介发育程度越高、法律制度环境越好,上市公司应计质量越好;市场化进程越快,上市公司应计质量越高.     

大直径盾构负环管片拆除及隧道换装技术

通过对北京铁路地下直径线2标工程的研究,确定在刀盘改造期间进行负环管片拆除的一系列工作,重点如部分反力架的拆除方法、负环管片的详细拆除方法以及拆除反力架后临时支撑的架设方法,同时就泥水盾构隧道的换装技术进行了叙述,最终在7 d之内成功拆除了7环负环管片,节约了工期,保证了后继施工的材料运输速度。     

低渗透油藏加密井评价与加密技术界限计算方法——以鄂尔多斯盆地盘古梁长6油藏为例

目前中国低渗透油藏加密井及更新井产量在油藏总产量中占有重大比例,但同一井区内加密井生产效果差别巨大,亟需开展加密井单井评价及加密技术界限研究,指导低渗透油藏井网加密调整.分析盘古梁长6油藏历年投产加密井的实际生产动态数据,给出加密井生产动态模式划分标准以评价加密井单井开发效果.利用数值模拟方法定量研究了加密井网和加密时机对低渗透油藏加密效果的影响.结果 表明:加密井网井排距对加密效果影响最大,其次是加密井类型,最后是加密时机.利用油藏工程方法给出了低渗透油藏加密极限井距和加密时机的计算方法,对低渗透油藏井网加密调整具有指导意义.     

银行卡POS交换系统的设计与实现

本文从总体上介绍了银行卡ＰＯＳ交换系统的网络架结构和交换中心应用软件的结构,对交换系统中的信息流程也作了分析,并针对系统的安全问题分析了可行的安全策略。     

Analysis of chemical composition of melt inclusion of beryl in pegmatite and discovery of zinc-spinel by electronic probe

The compositions of daughter mineral of melt inclusion in beryls, which are from pegmatite of Keketuhai in Xinjiang and Mufushan in Hunan, have been analyzed by electronic probe. Ten kinds of mineral, such as beryl, zinc-spinel, mica, quartz, magnetite, etc., which consist of different mineral associations have been identified. The zinc-spinel existing in two different forms was first discovered in the melt inclusion in China and abroad. This study provides that there exist the local magmatic differentiation and the immiscibility and heterogeneity of magma. It is very useful for the current research of magmatic rocks, pyrolite, meteorolite.     

Apoptosis of carrot nuclei inin vitro system induced by cytochrome c

The apoptosis of carrot nuclei induced in cytosol of carrot cells by cytochrome c is reported. This kind of cell-free apoptosis system of plant, CS-100, is an efficient In vitro inducing system. Several typical characteristics of apoptosis including chromatin condensation, margina-tion and apoptotic bodies could be detected, and the degradation of genome in carrot nuclei into nucleosomal fragments could be detected. TUNEL assay shows the specific breakage of 3'-OH ends of DNA strand. The results indicate that CS-100 is an efficient and easily-operated in vitro system to study the apoptotic mechanism in plant and the apoptosis in plant cells may share similar pathways to apoptosis in animal cells.