Structure and properties of samarium overlayer and Sm/Rh surface alloy on Rh(100)

The structure and properties of Sm overlayer and Sm/Rh surface alloy have been investigated with Auger electron spectroscopy (AES), low energy electron diffraction (LEED), X-ray photoelectron spectroscopy (XPS), and temperature programmed desorption spectroscopy (TDS). The growth of Sm on Rh(100) at room temperature (RT) appears following the Stranski-Krastanov growth mode and only the trivalent state Sm is observed from XPS results. Thermal treatment of the Sm film at 900 K leads to the formation of ordered surface alloy which shows the c(5√2 × √2)R45° and c(2×2) LEED patterns. Annealing the Sm film at temperature above 400 K makes the binding energy (B.E.) of Sm 3d_5/2 shift to higher energy by 0.7 eV, which indicates charge transfer from Sm to Rh(100) substrate, causing the increase of CO desorption temperature.     

有限状态多期模型下的最小κ熵等价鞅测度期权定价

本文用一个纯跳的随机过程来描述标的资产价格的动态性,称为有限状态多期模型。考虑只有一个标的资产的期权定价模型,给出其最小κ熵等价鞅测度,在此基础上采用Monte Carlo模拟欧式期权定价MCMEM(κ)方法,分别以虚拟Black-Scholes世界中欧式期权价格和现实金融市场中的麦当劳股票期权价格为例,对MCMEM(κ)和Black-Scholes公式等其他定价方法进行比较,验证了MCMEM(κ)的可行性。     

改进bang bang控制的微网VSG自适应虚拟惯量控制策略

研究并网逆变器虚拟同步机(virtual synchronous generator, VSG)控制策略在有新能源接入的电力系统中的频率稳定性问题.利用虚拟惯量的可变性,减少频率超调量并加快频率响应速度,提出一种基于改进bang-bang控制的微网VSG自适应虚拟惯量控制策略.首先,在bang-bang控制的基础上,设定一个频率稳态区间与稳态惯量.然后,通过建立微网孤岛运行模式下的VSG小信号模型,对虚拟惯量进行稳定性分析,确定虚拟惯量的取值范围及稳态惯量.最后,用Matlab/Simulink进行仿真实验,对比多种虚拟惯量控制策略,验证了所提策略的有效性.     

4,5-双(5-氯-2-甲基噻吩-3-基)-1,2-二苯基-1H-咪唑的光致变色性能

 设计合成了4,5-双(5-氯-2-甲基噻吩-3-基)-1,2-二苯基-1H-咪唑化合物L,通过1HNMR、13CNMR 和元素分析对其分子结构进行表征,并研究了酸效应对其吸收光谱、荧光光谱和热稳定性的影响。结果表明,酸效应对化合物L 吸收光谱的影响很小,但通过酸效应能够对化合物L 的荧光光谱和热稳定性进行有效的调节。另外,化合物L 在质子化前后均表现出良好的光致变色性能,并显示出与众不同的“on to on”荧光特性。     

槲皮素锡的合成及其生物活性研究

槲皮素在碱性甲醇溶液中与三氯化锡反应生成槲皮素锡金属配合物.用紫外光谱、红外光谱、差热分析对该配合物进行了表征,用二苯基苦基肼(DPPH)法测定了槲皮素锡清除自由基的活性.结果表明,在60℃和pH 8～9合成条件下,槲皮素锡最高收率达63%;槲皮素锡清除自由基的活性较槲皮素有所降低.     

基于互信息的热点词发现和突发性话题检测研究

针对舆情监测中现存的热点词提取方法精度不高、速度不快的问题,文章采用互信息作为热点词突发性的度量手段,并使用类间离散度作为调节因子来构建热点词的突发性度量公式.在此基础上,构造了改进后的动态突发性向量空间模型,并用于网络中突发性热点话题的发现与追踪.实例验证结果表明,文章提出的改进方法能够获得很好的准确度P、召回率R和F度量.     

几种非晶态合金的交流磁性研究

本文研究了四种非晶态合金的磁性参数随频率ｆ及磁感应强度Ｂ的变化规律，得出非晶态合金的磁化过程符合晶态金属磁畴理论的技术磁化规律；在中强场内交流损耗符合晶态金属磁损耗分离关系，找出了Ｐ／ｆ与频率ｆ关系曲线包含两条直线规律，求得直线转折所对应的频率约为２０ｋＨｚ；不同铁磁性非晶态合金在最大磁导率μｍａｘ值相差较大的情况下，磁损耗分离满足相同的规律。     

Thermodynamic properties and microstructural characteristics of binary Ag-Sn alloys

The liquidus and solidus temperatures and enthalpy of fusion for Ag-Sn alloys are systematically measured within the whole composition range by differential scanning calorimetry (DSC). The measured enthalpy of fusion is related to Sn content by polynomial functions, which exhibit one maximum value at 52 wt%Sn and two minimum values around 21 wt%Sn and 96.5 wt%Sn, respectively. The liquidus slope, the solidification temperature interval, the solute partition coefficient and the entropy of fusion are calculated on the basis of the measured results. The undercoolability of those liquid Ag-Sn alloys solidifying with primary (Ag) solid solution phase is stronger than the other alloys with the preferential nucleation of ζ and ε intermetallic compounds. Morphological observations reveal that peritectic reactions can rarely be completed, and the peritectic microstructures are always composed of both primary and peritectic phases.     

Optical mapping of a rice BAC clone using restriction endonuclease and imaging with fluorescent microscopy at single molecule level

A method of constructing restriction map by optical mapping and single molecule fluorescent microscopy is described. DNA molecules were aligned and adsorbed on a glass coverslip surface by a modified “molecular combing” technique, and then the surface-immobilized DNAs were cleaved in situ with a restriction endonuclease. Individual DNA molecules digested by the endonuclease EcoRⅠ were observable with fluorescent microscopy. Using optical mapping, a physical map of a rice bacterial artificial chromosome clone was constructed. This method will facilitate genomic mapping and tracing the dynamic process in real time at a single molecule level with fluorescence microscopy.     

碳酸盐矿物随埋深增加的溶蚀响应机制及其储层意义

以化学热力学为基础,利用数值模拟方法,研究不同埋深情况下碳酸盐矿物方解石(CaCO3)和白云石(CaMg(CO3)2)在含CO2流体及含H2S流体中的溶蚀响应机制。模拟结果表明,在流体系统不发生改变的前提下,随着埋深的增加,相同条件下方解石的溶蚀量始终大于白云石。同时,除温度、压力、酸性气体分压、流体成分之外,封闭在溶蚀体系中的气体总量是影响碳酸盐矿物溶蚀的另一重要因素。当封闭气体总量相对较高时,随着深度的增加,这两种矿物的溶蚀量表现为先增大后减少,此时白云石中溶蚀孔隙比方解石更为发育;当气体总量较低时,两种矿物的溶蚀量曲线单调性减少。