球状飞射物对屋面瓦片冲击效应的数值模拟

选取典型的球状混凝土飞射物,研究其对一种典型屋面陶土瓦片的冲击破坏作用.基于ANSYS/LS-DYNA平台,参考落球冲击试验方法建立冲击碰撞的有限元计算模型.选取Johnson-Holmquist-Ceramic本构模型模拟陶土瓦片材料,引入单元应变失效准则模拟瓦片破坏情况,采用显式动力学方法研究落球冲击试验中瓦片应力、应变、变形的时变机理.对冲击速度、球块质量、瓦片倾角进行参数分析,结果表明,瓦片最大等效应力与冲击速率及球块质量大致成正比,与瓦片倾角相关性不大.冲击过程是一个能量显著转移的过程,根据损伤方程计算出陶土瓦片能承受不超过34.35m·s~(-1)的来流风速下球状混凝土飞射物的冲击破坏作用.     

学龄前和学龄期儿童希氏束以上心动过速性心肌病高危因素分析

目的探讨学龄前和学龄期儿童希氏束以上的心动过速(室上性心动过速)与心动过速性心肌病的相关性及高危因素.方法选取室上性心动过速患儿179例,根据心动过速时心功能状态分为心肌病组23例,非心肌病组156例.分析患儿性别、年龄、发作类型、发作频率、持续时间、心室率与心功能损伤的关系和相关高危因素.结果 179例患儿中心动过速性心肌病23例,其中房室折返性、房室结折返性、无明确分类的心肌病分别为7例、10例、6例.房速所致心动过速性心肌病发生率为25.00%(8/32),明显高于阵发性室上性心动过速所致的心肌病发生率10.20%(15/147),差异具有统计学意义(P0.05).心肌病组患儿中房速所占比例、发作持续时间明显高于非心肌病组患儿,发作频率明显低于非心肌病组患儿,差异均具有统计学意义(P0.05).二元Logistic回归分析显示:发作持续时间是心动过速性心肌病的独立影响因素.结论学龄前和学龄期儿童室上性心动过速所致心动过速性心肌病的发生率为12.85%,其中房速所致的心肌病发生率明显高于阵发性室上性心动过速,发作持续时间是唯一高危因素.     

石墨烯-碳量子点复合材料的电化学性能研究

采用Hummers法和水热法,制备石墨烯和碳量子点溶液作为前驱体,然后通过一步煅烧法制得石墨烯-碳量子点复合材料。借助SEM、UV-Vis、FTIR等手段,对样品的形貌和结构进行表征;利用循环伏安法(CV)、差分脉冲伏安法(DPV)及恒流充放电循环测试等,重点考察了样品的电化学性能。结果表明,在石墨烯表面负载碳量子点可增加材料的比表面积并改善其机械性能,由于活性位点的增加,所制石墨烯-碳量子点复合电极具有较好的可逆性及电化学活性;在检测不同浓度双氧水时,复合电极的灵敏度为纯石墨烯电极的1.4倍左右;石墨烯-碳量子点复合材料作为锂离子电池负极使用时,与纯石墨烯材料相比具有更好的循环稳定性,且容量保持率提高了1.67倍。     

Preparation and performance of a cold gas dynamic sprayed high-aluminum bronze coating

By mixing preheated high-aluminum bronze powders with different amounts of Al₂O₃ powder, a low-pressure cold-sprayed coating was prepared and sprayed onto a Cr12MoV steel substrate. The hardness of the coating and the bonding strength between the coating and the substrate were tested with a HV-1000 microhardness tester and a mechanical universal testing machine. The surface microstructure, cross-section and tensile fracture surface of the coating were observed with a scanning electron microscope (SEM). Correspondingly, the influences of the preheat treatment temperature of the bronze powder and the Al₂O₃ content on the coating performance were investigated. The results indicate that the hardness of bronze powders decreased and the coating deposition rate increased after the preheating treatment of the bronze powder. The Al₂O₃ content in the mixed powders contributed to the deformation of bronze powders during the spraying process. This trend resulted in varied performance of the coating.     

辫状河储层内部建筑结构及剩余油分布研究

储层内部建筑结构是影响开发效果的决定性因素,对剩余油分布具有控制作用。基于河流相建筑结构分析理论,在辫状河沉积模式指导下,采用层次分析法,从开发角度对砂体内部结构进行精细解剖,识别和确定出辫状河道、心滩坝、废弃河道和落淤层等结构要素,弄清各级次、各期次结构要素的接触关系,完成辫状河储层内部结构的精细表征;基于内部结构表征成果,结合不同时期水淹层测井解释结果和生产动态资料,恢复不同开发调整时期的水淹特征,动态表征辫状河储层内部结构控制下的水淹过程,并依据小井距密闭取芯井精细水洗结果验证,总结不同储层结构控制下的剩余油分布模式。结果表明,辫状河储层整体以高含水为主,水淹呈不均匀立体式、随机式特征,不具有分段水淹的特点,未水淹部位分布非常零散,局部物性变差部位、落淤层和低渗屏障遮挡部位直接控制了剩余油的分布。     

智慧城市支撑下的“多规合一”技术框架与实现途径探讨

 云计算中心、基础地理信息数据库、"互联网+"政务服务等智慧城市建设的内容,为"多规合一"工作开展提供重要的技术支撑。本文从智慧城市技术支撑的角度出发,针对各市县部门规划中存在的矛盾、不协调问题,探讨了智慧城市对"多规合一"的支撑作用,提出了以数据、业务和平台3个层面构建的"多规合一"技术框架;从"多规合一"的数据体系、规划编制与管理协同及信息平台功能建设3方面分析了"多规合一"的实现途径,为市县"多规合一"的规划编制与管理及"多规合一"信息平台建设提供技术指导。     

Nanoengineering of amino - functionalized mesoporous silica nanospheres as nanoreactors

Selective functionalization of mesoporous silica nanospheres (MSNs) is crucial for nanoengineering of MSNs. Herein, we have combined “surface-protected etching strategy” and “cationic surfactant assisted etching strategy” to prepare functionalized MSNs with externally attached amino groups. The externally attached NH2 groups endow the catalysts with excellent catalytic performance for nitroaldol reaction between nitromethane and benzaldehyde. In addition, those NH2-MSNs can also be used to support gold nanoparticles, which display very good catalytic performance for reduction of 4-nitrophenol. It can be envisioned that the synthesis protocol developed in this work could also be extended to nanoengineered MSNs, which provides opportunities for nanoreactors design.     

Coupling effects of tungsten and molybdenum on microstructure and stressrupture properties of a nickel-base cast superalloy

In order to comprehensively understand the forming mechanism of abnormal phases solidified in a nickel-base cast superalloy with additives of tungsten and molybdenum, the coupling effects of W and Mo on the microstructure and stress-rupture properties were investigated in this paper. The results indicated that the precipitation of primary α-(W, Mo) phase depended tremendously on the amount of W and Mo addition. When the total amount of W and Mo was greater than 5.79 at%, α-(W, Mo) phase became easily precipitated in the alloy.With increasing of Mo/W ratio, the dendrite-like α-(W, Mo) phases were apt to convert into small bars or blockylike phases at the vicinities of γ′/γ eutectic. The morphological changes of α-(W, Mo) phase can be interpreted as the non-equilibrium solidification of W and Mo in the alloy. Since the large sized α-(W, Mo) phase has detrimental effects on stress-rupture properties in as-cast conditions, secondary cracks may mainly initiate at and then propagate along the interfaces of brittle phases and soft matrix. During exposing at 1100 ℃ for 1000 h, the α-(W, Mo) phases transformed gradually into bigger and harder M_6C carbide, which results in decreasing of stress-rupture properties of the alloy. Finally, the alloy with an addition of 14W-1Mo(wt%) maintained the longest stress lives at high temperatures and therefore it revealed the best microstructure stability after 1100 ℃/1000 h thermal exposure.     

头孢孟多酯钠的波谱学特征和结构确证

建立了利用分析仪器确证头孢孟多酯钠化学结构的方法。通过元素分析仪分析头孢孟多酯钠的元素组成,并利用核磁共振（NMR）、质谱（MS）、红外光谱（IR）、紫外光谱（UV）对头孢孟多酯钠进行结构分析。通过解析确证,头孢孟多酯钠的结构为7-D-( 2-甲酰氧苯乙酰胺)-3-［(1-甲基-1H-四唑-5-基)巯甲基］-8-氧代-5-硫杂-1-氮杂双环[4.2.0]辛-2-烯-2-甲酸盐。该方法准确可行,可为头孢孟多酯钠的结构鉴定提供依据。     

结构混凝土抗压强度预测RBF-ANN模型

为了达到对C20~C40范围内的结构混凝土抗压强度快速准确预测的目的,基于RBF-ANN模型基本原理及应用特点,在钻芯法、回弹法、超声波法及回弹-超声波综合法等大量室内和现场无损检测试验基础上,进一步应用Matlab2012b神经网络工具箱,建立了混凝土抗压强度RBF-ANN预测模型。该模型经充分训练后,应用于山西省重点建设工程项目的结构混凝土质量控制。工程实践表明,构建的RBF-ANN模型预测精度为4.4%,满足工程实际需要,具有较好的便捷性、经济性和准确性。