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841.
XiaoTao Wang YingKui Yang ZhiFang Yang YongGui Liao Wei Zhang XiaoLin Xie 《科学通报(英文版)》2010,55(30):3441-3447
By means of distillation precipitation polymerization, the silica-hybrid particles with polyazobenzene shell (PAzo@SiO2) micro-spheres were prepared with 6-(4-methoxy-4′-oxy-azobenzene) hexyl methacrylate (Azo-M) as monomer, divinylbenzene (DVB) as cross-linker, and ~250 nm vinylated sol-gel silica particles as template. Hollow polyazobenzene microspheres were further developed after selective removal of the silica cores with HF solution. When the content of DVB related to Azo-M is 20 wt%, the acetonitrile is 200 mL, and the polymerization time is 4.5 h, the hollow PAzo microspheres with about 20 nm shell are successfully fabricated. These hollow PAzo microspheres have excellent reversible photoisomerization, and their first-order rate constant of trans-cis isomerization only decreases 11.8% compared with homopolymer of azobenzene (Homo-PAzo). 相似文献
842.
WANG TengHui WANG LuDe GUO YunXiao LI YanFen FAN GaoChao HUANG ZaiYin 《科学通报(英文版)》2013,58(26):3208-3212
Controllable synthesis of uniform and single-crystalline CdMoO4 nano-octahedra has been successfully realized at large-scale by a facile reverse-microemulsion route at room temperature. The structures, compositions and morphologies of the as-prepared products were characterized in detail by X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), respectively. According to the thermochemical cycle, the relationship between the standard molar enthalpy of formation of nano-CdMoO4 and bulk CdMoO4 was proposed for the first time. In combination with micro-calorimetry, the standard molar enthalpies of formation at 298.15 K of as-ynthesized CdMoO4 nano-octahedra were ob-tained. 相似文献
843.
This research analyzed amino acid sequence similarity between non-self T cell epitopes recognized by mouse antibodies and mouse proteins. Using sequence alignment,we found that only 8 of 1 108 epitopes are highly similar to mouse protein sequences. The result shows that non-self T cell epitopes are not similar or have little similarity to mouse protein sequences. Furthermore,reviewing the related literature,we also found that the eight epitopes would trigger immune responses in some particular environment,which are ignored by T cells in normal condition. The result suggests that no or low-similarity peptide vaccines can reduce the chance of collateral cross-reactions and enhance the antigen-specific immune response to vaccine. 相似文献
844.
In this paper, CdS quantum dots sensitized TiO2 composite powders (QD-CdS/TiO2) were synthesized by impregnating TiO2 powder into CdS sol with different concentrations. X-ray diffraction pattern (XRD) shows the crystal structures of CdS and TiO2 are cubic phase and anatase phase separately in QD- CdS/TiO2 powder samples; the crystal size of CdS in QD- CdS/TiO2 is about 3-7 nm, while TiO2 crystal size is about 20 nm. With increasing CdS content in QD-CdS/TiO2 composite, the UV-Vis absorption spectrum shifted to the longer wavelength lines, exhibiting obvious quantum size effect. The fluorescence intensity of QD-CdS/TiO2 irradiated by blue light is weaker than that of pure CdS. When the molar ratio of CdS and TiO2 is about 1∶2, the QD-CdS/TiO2 powder has the best catalytic properties under visible-light irradiation, and the degradation rate of rhodamine B (RhB) is up to 92.2% within 60 min. 相似文献
845.
Well-crystalline CeO2 nanowires were prepared via a surfactant-assisted hydrothermal process. Reaction temperature and reaction time were changed for the determination of
optimal synthesis parameters. The as-obtained products were characterized by X-ray diffraction (XRD), high-resolution transmission
electron microscopy (HRTEM), and field emission scanning electron microscopy (FESEM). The results show that single crystal
CeO2 nanowires with high yield and good uniformity can be obtained hydrothermally at 180°C for 12 h with the aid of 2.0 g surfactant
(polyvinyl pyrrolidone, PVP). The role of PVP was then discussed and a possible growth mechanism was proposed. Moreover, room
temperature photoluminescence (PL) spectra were obtained for these CeO2 nanowires, which are believed to be related to the abundant defects in these nanostructures. 相似文献
846.
FuWei Yang Yan Liu GuoFang Zuo YuanCheng Zhu BingJian Zhang PingNing Hua 《科学通报(英文版)》2012,57(13):1590-1594
Fluorapatite protective films were prepared on marble substrates using a biomimetic method. By mimicking the mineralization mechanism of enamel, phosphorus and fluorine were introduced on the surface of the marble substrate. In the presence of a biological template, namely collagen, an integrated fluorapatite film was produced and the marble substrate was entirely covered. The prepared fluorapatite films were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX) spectroscopy. The performances of the fluorapatite films were evaluated by color changes, capillary water absorption, and acid resistance tests. The results revealed that the fluorapatite films had good compatibility with the marble substrate; the physical properties such as color and capillary water adsorption of the marble substrates were unchanged. The fluorapatite films also had good acid resistance and were stable even in heavy acid rain. 相似文献
847.
A numerical method to simulate the coupled oscillations of flexible structures in flowing fluids 总被引:1,自引:0,他引:1
A numerical method is developed to simulate the coupled phenomena in a fluid-flexible-structure system. Specifically, a two-dimensional
panel method is used to calculate the hydrodynamic forces and a modal superposition method is adopted to solve the governing
equation of an Eulerian beam. The stability boundary of a single flexible beam in a uniform flow is calculated and compared
with previous results to verify the validity of the code. The flow-induced flapping of a single and two flexible bodies for
S=1.0, U*=7.0 are investigated. For the flow-induced vibration of a single beam, the oscillation frequency is close to the secondary
natural frequency of a cantilever. For two parallel flexible beams, they oscillate in phase when the non-dimensional separating
distance H<0.25. When H>0.25, the out-of-phase mode occurs with a jump in frequency. When H>1, the interaction between the two beams decouples and the frequency and forces of each beam revert to behavior associated
with a single beam in the same flow. Simulations of coupled-flapping of two tandem flexible structures proved that the drag
acting on the upstream body is reduced while for that downstream drag is obviously increased when the structures are closely
arranged. The numerical results obtained in the present work are qualitatively consistent with early experimental results. 相似文献
848.
Oskar Michalski Ewa Bidzińska Michał Borowski Krystyna Dyrek Paweł Olko Liliana Stolarczyk Jan Swakoń Piotr Tomasik Elżbieta Wenda 《科学通报(英文版)》2010,55(31):3556-3561
Cornstarch heated in the range of 230–280°C depolymerized into pyrodextrins characterized by two-component EPR signals of relatively stable free radicals. These thermally generated radicals could serve as efficient scavengers for free radicals generated from pyrodextrins with the 200 Gy dose of γ-radiation. The most efficient traps/scavengers were produced from cornstarch at 250–280°C. IR data indicated incorporation of the OH groups to the pyrodextrins. These groups most probably originated from the OH· radicals formed by the radiolysis of water. EPR spectra provided evidence for trapping free radicals generated by γ-irradiation and for their subsequent annihilation on contact with pyrodextrins. Water affected radical processes occurring in pyrodextrins caused by γ-irradiation. 相似文献
849.
以企业家精神代表创新和创业精神,用1996—2008年的统计数据实证分析了河南省和全国企业家的创新、创业精神与经济增长之间的关系,以及两者的动态趋势,得出创新、创业精神与区域经济增长之间存在很强的正相关关系,河南企业家的创新、创业精神与全国其他省分的企业家表现基本相同.在研究结论的基础上,为河南发展企业家精神提供了几条建议. 相似文献
850.
An approach of three-dimensional seismic ray tracing is presented, which is derived from adopting two-dimensional linear traveltime
interpolation (LTI). By adjusting the forward process using the partition of grid interface, and backward step by considering
more directions, the new approach is suitable for the application of three-dimensional models. The calculation results show
that, with the same accuracy, the improved 3-D method is much faster than the method of traditional LTI directly applied in
the three-dimensional case. 相似文献