Rapid reductive degradation of azo dyes by a unique structure of amorphous alloys

An Fe-based amorphous alloy was found to significantly enhance the reductive degradation of an azo dye in aqueous solution. The surface-area normalized rate constant was up to 2.0 L m-2 min-1 at room temperature,an order of magnitude larger than any previously reported value. The activation energy of the degradation process was calculated according to the Arrhenius equation,and a much lower value than those previously reported was obtained. Valence band measurement indicated that a depressed valence band maximum and a widened empty band were established in the amorphous ribbon. The unique structure of the amorphous alloy is important-it may reduce the activation energy of the degradation process and enhance the activity of the electrons,thus accelerating the degradation process.     

Preliminary regional estimation of carbon sink flux by carbonate rock corrosion: A case study of the Pearl River Basin

The formation of carbonate rocks has had a dramatic sink effect on atmospheric CO2 throughout geological time.The wide global distribution of carbonate rocks and their strong sensitivity to climate change mean that carbonate rock corrosion consuming air/soil CO2 can play an important role in the global carbon cycle.The carbon sink accounts for 12.00%-35.29% of the missing carbon in the global carbon cycle.Using the Pearl River Basin as a case study,we analyzed comprehensively the factors impacting karstific...     

Multi-threshold second-order phase transition in laser

We present a theory of the multi-threshold second-order phase transition,and experimentally demonstrate the multi-threshold secondorder phase transition phenomenon.With carefully selected parameters,in an external cavity diode laser system,we observe secondorder phase transition with multiple(three or four) thresholds in the measured power-current-temperature three dimensional phase diagram.Such controlled death and revival of second-order phase transition sheds new insight into the nature of ubiquitous secondorder phase transition.Our theory and experiment show that the single threshold second-order phase transition is only a special case of the more general multi-threshold second-order phase transition,which is an even richer phenomenon.     

Highlights of recent advances in functional coordination polymers made in China

Coordination polymers (or metal-organic frameworks, MOFs), as one of the essences of crystal engineering and coordination chemistry, have attracted considerable atten-tion from chemists,     

Rapid growth and sterility of growth hormone gene transgenic triploid carp

Triploid carp (100%) with 150 (3n=150) chromosomes were obtained by crossing the females of improved tetraploid hybrids (♀, 4n=200) of red crucian carp (♀)×common carp (♂) with the males of diploid yellow river carp (♂, 2n=100). The crosses yielded transgenic triploid carp (positive triploid fish, 44.2% of the progeny) and non-transgenic triploid carp (negative triploid fish). Histological examination of the gonads of 24-month-old positive triploid fish suggested they were sterile and the fish were not able to produce mature gametes during the breeding season. Morphologically, both the positive and negative triploid fish were similar. They had a spindle-shaped, laterally compressed, steel grey body with two pairs of barbells. Most of the quantifiable traits of the triploid carp were intermediate between those of the two parents. The positive and negative triploid fish were raised in the same pond for 2 years. The mean body weight of the positive triploid fish was 2.3 times higher than the negative triploid fish. The weight of the largest positive triploid fish was 2.91 times higher than that of the largest negative triploid fish. Thus, we produced fast-growing transgenic triploid carp that have a reduced ecological risk because of their inability to mate and produce progeny.     

基于深腾7000系统的大规模CFD并行计算

从基本流动控制方程及数值离散、多重网格、并行算法等方面详细阐述了混合网格框架下计算流体力学软件的基本原理,提出了采用三重嵌套循环结构在时间推进格式中实现多重网格加速及并行计算技术的主流程设计方案;同时给出了高精度混合网格并行计算软件在深腾7000系统上的大规模并行测试结果以及在某型民用飞机高升力流场数值模拟中的应用.结果表明:此高精度混合网格并行计算软件在采用千万网格点规模的大型飞机高升力复杂流场计算时,不仅计算结果与实验结果符合较好,且在2 048核并行计算时仍具有很好的并行可扩展性,计算效率不低于80%.     

一台慢正电子束实验装置

本文介绍一台磁聚焦传输的慢正电子束装置.在该装置上用Ni+MgO 慢化体产生了慢正电子,测量了慢正电子能谱,并和其他实验组用Au(Pt,不锈钢)+MgO慢化体所得实验结果进行了比较.     

应用功的互等定理推导不连续位移基本解

不连续位移基本解在边界元法中得到了广泛的应用,本文应用功的互等定理推导了该基本解,指出了开尔文解中的某些应力分量就是不连续位移基本解中某些位移分量的一般规律.这种推导方法不但十分简单而且可以推广到各种区域的不连续位移基本解的推求.     

金属有机化合物化学气相淀积含钛硬质涂层的过程研究

在垂直冷壁CVD反应器中进行了文题的探索性研究。以二乙胺基钛(Ti(NEt_2)_4)为源,在不锈钢或硬质合金基体上完成了氮化钛(TiN)和碳氮化钛(Ti(C,N))硬质薄膜低温下的淀积。发现(TiN)和(Ti(C,N))分别在773K和973K下形成;在操作范围内整个反应器流场由自由对流控制;反应过程由表面过程控制;反应活化能为235 kJ/mol;二乙胺基钛反应级数为1级。进行了热力学计算,提出了反应历程假设。结果表明:用二乙胺基钛进行MOCVD淀积含钛硬质薄膜可以降低温度,以扩大基体的选用范围,为获得硬质薄膜提供了一条新的途径。     

新疆雪莲、甘草、大黄的微量元素分析

本文用ICP——AES法测定了新疆雪莲、甘草、大黄的17种微量元素含量,联系临床实际对一些元药理作用进行了分析,以揭示它们与常用同种中药在元素含量和药效上的某些联系和区别。