环境对单分子体系荧光光子统计性质的影响

利用近年所发展的产生函数（Generating Function）理论方法,研究了激光场和射频场共同驱动下单分子二能级体系发射荧光光子的统计性质.对在激光脉冲和射频脉冲场作用下单分子二能级体系的荧光光子发射特性进行了理论研究,并讨论了单分子二能级体系发射光子的控制等有关问题.     

单分子发射光子的统计性质: 考虑系间穿越影响

用产生函数(generating function)方法研究了单分子存在系间穿越过程的发射光子的统计性质, 并给出了长时间极限下的发射光子的平均值以及对应的Mandel Q 参数的表达式.研究结果表明, 在系间穿越过程存在的情况下, 单分子发射光子的平均发射光子数和对应的Mandel Q参数随时间都呈线性关系, 并且Mandel Q参数对跃迁速率k₂₃ 在长时间尺度上非常敏感.     

V型三能级量子点体系中的类相干粒子数囚禁现象

采用产生函数（Generating Function）方法讨论了V型三能级量子点体系在泵浦场和探测场作用下的发射光子的统计特性.研究表明：在强泵浦场作用下,跃迁偶极矩垂直的V型三能级体系表现出Autler-Townes分裂现象;而在跃迁偶极矩平行的V型三能级系统表现出类似于相干粒子数囚禁的现象.通过所施加的探测场,我们可以调节量子点系统发射光子的开关状态.     

Shiga toxin-producing Escherichia coli O104:H4: An emerging 0important pathogen in food safety

In 2011, Shiga toxin-producing Escherichia coli O104 : H4 resulted in a large outbreak of bloody diarrhea and hemolytic uremic syndrome (HUS) in Germany and 15 other countries in Europe and North America. This event raised a serious public health crisis and caused more than two billion US dollars in economic losses. In this review, we describe the classification of E. coli, the Germany outbreak, and the characteristics and epidemical source-tracing of the causative agent. We also discuss the genomics analysis of the outbreak organism and propose an open-source genomics analysis as a new strategy in combating the emerging infectious diseases.     

船用核动力装置自然循环载热能力的分析与计算

给出了考虑倾斜和匀加速上浮或下沉的船用压水反应堆核动力装置—回路自然循环的热工水力特性模型及数学描述；用标准ＦＯＲＴＲＡＮ－７７语言编制了计算、分析各种不同运行方式下，稳态自然循环载热能力的计算机程序ＳＮＣＮＲ－０１．并分别在考虑和不考虑倾斜和匀加速上浮、下沉的情况下，计算了四种不同运行方式下稳态自然循环能力的大小及与相应参数间的关系。     

Efficient photo-assisted Fenton oxidation treatment of multi-walled carbon nanotubes

In this paper,a new and efficient way to oxidize and functionalize the multi-walled carbon nanotubes (MWNTs) has been developed by using a combination of ultraviolet (UV) irradiation and Fenton oxida-tion process,namely UV/Fenton oxidation treatment. Comparing with conventionally individual Fenton oxidation treatment of MWNTs,UV/Fenton combined treatment improved the etching rates and effi-ciencies and hence reduced the time for surface modification of MWNTs,which was proved to be an effective method in etching and functionalizing CNTs. The formation of new functional groups,struc-tural changes and thermal stability during oxidation period were characterized by Fourier transform infrared spectroscopy (FTIR),Raman spectroscopy and could be clarified by thermogravimetric analy-sis (TGA),which showed that it was under UV irradiation conditions that MWNTs could be rapidly functionalized with hydroxyl,carbonyl and carboxyl groups in the presence of Fenton reagents,origi-nating from the increase in the gross HO· concentration and the existent synergetic effect when using UV irradiation combing with Fenton oxidation process. Introduction of such new oxygen-containing functional groups was attributed to attacks of HO· on defect sites and unsaturated bonds of C=C in the MWNTs sample,which should play an important role in accounting for the FTIR and Raman spectral changes.     

The synthesis and characterization of a Co-N/C composite catalyst for the oxygen reduction reaction in acidic solution

A non-precious metal Co-N/C catalyst for the oxygen reduction reaction (ORR) was synthesized by heating a mechanical mixture of cobalt chloride, urea and acetylene black under a nitrogen atmosphere. The catalyst was characterized by XRD and XPS. The electrocatalytic activity in the ORR was evaluated by linear sweep voltammetry in 0.5 mol L⁻¹ H₂SO₄ solution. The results show that the Co-N/C catalyst aids the reduction of oxygen. The presence of elemental cobalt in the precursor allows nitrogen atoms to embed themselves in the graphite matrix to form pyridinic and graphitic type C-N structures as the ORR active sites. The effect of heat-treating temperature on the catalytic activity was also investigated. The results also show that the Co-N/C catalyst is most active when pyrolyzed at 600°C. The obtained Co-N/C catalyst loses some activity after initial exposure to the H₂SO₄ solution because of leaching, but is then stable for up to 20 h immersion. The catalyst is also stable when charged, which is supported by the cyclic voltammetry results.     

再生式液体炮研究中异常燃烧的分析

该文根据国内外有关液体炮（LPG）研究段笔者多年的实验研究中取得的异常燃烧现象的大量资料，将常见的异常燃烧现象归纳概括为2大娄：回火和压缩点火；把在研究中发现的并称之为“爆燃”现象列为第3类异常燃烧现象．并进行了分析。在对正常发射过程与异常燃烧过程进行比较的基础上，深入分析了各种异常燃烧现象的特征、危害及产生的原因，并介绍了防止异常燃烧的各种技术途径。     

泵浦探测场下单分子体系荧光光子的统计性质

本文利用最近所发展的产生函数（Generating Function）理论方法,研究了泵浦和探测场共同驱动下单分子二能级体系发射荧光光子的统计性质.给出了泵浦探测场对体系发射光子线型、MandelQ参数以及光子发射几率等统计量的影响.理论计算的单分子发射平均光子数与已有实验结果符合得很好.     

基于变结构MRAS观测器的PMSM无速度传感器矢量控制

为改善传统模型参考自适应系统(Model Reference Adaptive System, MRAS)速度观测器对电机参数和负载变化敏感的缺点,针对永磁同步电机,基于变结构技术,提出一种变结构MRAS速度观测器。该方法利用滑模变结构代替MRAS中的自适应律,利用连续的双曲正切函数Sigmoid代替符号切换函数,可以降低滑模模态的抖动。理论分析和仿真结果表明,基于变结构MRAS观测器的PMSM无速度传感器矢量控制系统具有较好的动静态性能,且具有较强的鲁棒性。