Experimental investigation and thermodynamic assessment of the yttriumhydrogen binary system

A coupled experimental investigation and thermodynamic study of the yttrium-hydrogen(Y-H) binary system were carried out to provide more comprehensive and quantitative insights into the key thermodynamic properties of this system. Y-H system in the full range of H/Y = 0–3.0 was investigated by accurate pressure composition isotherm(PCI) measurement to provide credible phase equilibria information and thermodynamic data.The phase boundaries obtained were in agreement with previous experimental data but with improved accuracy.With the guide of the crystal structures, all the solid phases were modelled using the three sublattice model. The Y-H phase diagram and thermodynamic parameters were calculated and assessed with the CALPHAD technique.The obtained results are in very good agreement with our experimental data and the published data reported in literature. The obtained thermodynamic database of Y-H system can be used to predict the hydrogenation behavior and decomposition temperatures of hydrides.     

Grey hematite photoanodes decrease the onset potential in photoelectrochemical water oxidation

Photoelectrochemical (PEC) water splitting for solar energy conversion into chemical fuels has attracted intense research attention.The semiconductor hematite (...     

基于动态矩阵的永磁同步直线电机速度控制

为了改善直线电机的动态响应性能,提高电机控制系统的鲁棒性,使电机稳定运行,基于预测控制理论,设计了适用于直线电机速度环控制的动态矩阵控制器,将传统的直线电机三闭环控制系统中的速度环PID控制器替换为动态矩阵控制器,并分别搭建基于PID速度控制器和动态矩阵速度控制器的永磁同步直线电机三闭环仿真模型,在此基础上给控制系统施加阶跃信号,并进行突加负载和突减负载的仿真,将2种控制器控制下的系统响应结果进行对比。仿真结果表明,当速度环采用动态矩阵控制后电机的响应速度更快,超调更小,使电机速度更快达到稳定。改进后的速度环控制器提高了直线电机控制系统的鲁棒性,改善了直线电机的动态响应性能,提高了控制系统的抗扰动能力,有利于电机在负载变化较大的情况下运行。     

最小代数的同调和上同调

计算出了域上的最小代数的同调和上同调,并作为应用发现了比∧代数还要简单的DGA与Steen- rod代数具有相同的上同调．     

Shape recovery using high dynamic range images

An effective method for object shape recovery using HDRIs (high dynamic range images) is proposed. The radiance values of each point on the reference sphere and target object are firstly calculated, thus the set of candidate normals of each target point are found by comparing its radiance to that of each reference sphere point. In single-image shape recovery, a smoothness operation is applied to the target normals to obtain a stable and reasonable result; while in photometric stereo, radiance vectors of reference and target objects formed due to illuminations under different light source directions are directly compared to get the most suitable target normals. Finally, the height values can be recovered from the resulting normal field. Because diffuse and specular reflection are handled in an unified framework with radiance, our approach eliminates the limitation presented in most recovery strategies, i.e., only Lambertian model can be used. The experiment results from the real and synthesized images show the performance of our approach.     

双环网络G(N;1,s)等价生成树

提出研究双环网络G(N;1,s)的抽象模型--等价生成树,并对其性质进行了研究,给出了双环网络G(N;1,s)等价生成树的构造方法.提出基于等价生成树G(N;1,s)的直径d(N;1,s)的求解算法,并给出了其显式公式,利用C语言编程对等价生成树的结构模型进行了仿真.结果表明:算法不仅可在有限时间内求出G(N;1,s)的所有直径,而且可方便地得到源结点到所有其他结点的最短路径.算法的复杂度为O(N).     

基于自适应谱段分组的超光谱图像压缩算法

针对庞大的超光谱数据与有限的卫星信道容量间存在的巨大矛盾,提出了一种新的基于自适应谱段分组的超光谱图像压缩算法.为了充分挖掘图像的谱间相关性,运用该算法对超光谱图像进行了预处理,通过谱段的自适应分组和预测参考帧的选取提高了压缩算法的编码性能,并结合谱间预测和位平面编码分别消除了超光谱图像的谱间和空间冗余.实验结果表明:与传统方法相比,在保证图像质量和较低计算复杂度的前提下,其压缩编码的平均峰值信噪比提高了约2.0～4.5 dB.     

基于光栅扫描的NAM优化策略

借助于Packing问题的优化思想,提出了一种基于光栅扫描的NAM优化策略.以矩形子模式的NAM表示方法为研究对象,进行了理论分析与实验验证.NAM优化策略的最终目标是不断地逼近模式的最优化表示,NAM优化问题在降低存储空间、提高传输速度、加快处理过程、模式匹配等方面具有较高的理论参考和实际应用价值.结果表明:基于光栅扫描的NAM优化策略是行之有效的,对NAM的优化具有一定的指导意义.     

二氧化硅增强增韧不饱和聚酯

采用二氧化硅对不饱和聚酯树脂进行增强增韧,发现在所采取的试验条件下,SiO2的添加量对材料性能有显著影响,添加量为8%(质量分数)时拉伸断裂能达最大值,添加量为8%～12%时所得复合材料有较低的固化收缩率.用红外光谱法研究复合材料中分子特征基团的变化及氢键对材料性能的影响,发现在SiO2添加量低于10%时,随添加量增加,不饱和双键和羟基的吸收峰显著增强.     

多级泵轴断裂分析

针对某化工企业引进的国外多级高压烃泵主轴发生断裂事故,结合该轴材料和断口形貌,运用机械可靠性设计原理和方法进行了计算和分析,以探寻其断裂的主要原因.计算分析结果与实际运行表明,该泵选型扬程过高,使泵轴的综合工作应力大,又存在局部应力集中,加之氯离子的腐蚀,因而轴的可靠性较低,导致发生疲劳失效而断裂.据此,文中提出了相应的改进措施.