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21.
由CoCl(PPh3)3与过量PhNCS在苯溶液中的反应制备出一种流的Co(I)的五配位配合物.根据红外,1H核磁共振、快原子轰击质谱、x电子能谱及元素分析结果确定其分子式为CoCl(CNPh)2(PPh3)2与类似的配合物比较,推断该配合物具有三角双锥结构,其中两个大体积的叔膦基成轴间配位.从d-p户反馈π键度讨论了IR及1HNMR.此外,也对该回合物的溶解性、热稳定性以及对O2的稳定性加以了描述. 相似文献
22.
FROM MANUFACTURING SCHEDULING TO SUPPLY CHAIN COORDINATION:THE CONTROL OF COMPLEXITY AND UNCERTAINTY
Peter B.LUH 《系统科学与系统工程学报(英文版)》2003,12(3):279-297
With time-based competition and rapid technology advancements, effective manufacturingscheduling and supply chain coordination are critical to quickly respond to changing marketconditions. These problems, however, are difficult in view of inherent complexity and variousuncertainties involved. Based on a series of results by the authors, decomposition and coordination byusing Lagrangian relaxation is identified in this paper as an effective way to control complexity anduncertainty.A manufacturing scheduling problem is first formulated within the job shop context withuncertain order arrivals, processing times, due dates, and part priorities as a separable optimizationproblem. A solution methodology that combines Lagrangian relaxation, stochastic dynamicprogramming, and heuristics is developed. Method improvements to effectively solve large problemsare also highlighted. To extend manufacturing scheduling within a factory to coordinate autonomicmembers across chains of suppliers, a decentralized supply chai 相似文献
23.
利用AC=BD的思想,将变系数广义KdV方程约化成常微分方程,求出了KdV方程的Lax对。 相似文献
24.
一 第二届科学技术史名词审定委员会成立的意义
2007年1月15日,在全国科学技术名词审定委员会和中国科学院自然科学史研究所的共同努力下,“第二届科学技术史名词审定委员会”正式成立。自1988年第一届科学技术史名词审定委员会成立以来,海内外学术界关于中国科技史的研究取得了重大的成就,国内外交流空前活跃。2005年7月“第廿二届国际科学史大会”在北京召开,中国科技史的研究进一步走向国外。在全球科学史研究和学术交流日渐频繁的大背景下,如何进一步认识、规范和推广科技史名词术语,建立中国自己的科技史名词体系,便迫切地摆在了中国学者和相关机构的面前。第二届科学技术史名词审定委员会将在第一届委员会工作成就的基础上,改进以往之不足,尽快形成一个稳定、行之有效且高效率的编辑机制和渠道,填补我国科技史名词的空白,展现中国古代辉煌的科学技术。 相似文献
25.
ZAN Ling LIU Zhongshi FA Wenjun PENG TianYou 《武汉大学学报:自然科学英文版》2006,11(2):415-418
A new kind of polymethyl methacrylate (PMMA)-TiO2 nanocomposite was synthesized through polymerization. The thermal and photic stability of this PMMA TiO2 nanocomposites were investigated. The as prepared samples were characterized by scanning electron microscopy (SEM), UV-Vis spectroscopy, differential thermal analysis (DTA) and the photo-induced weight loss, The results show that the photostability of the PMMA-TiO2 nanocomposite is higher than that of the pure PMMA under UV-light irradiation, The weight loss of the pure PMMA reaches 30 % after 300 h UVirradiation, while the composite only 0.3% under the identical experimental condition. The glass transition temperature (TR) of pure PMMA is only 80℃, while the Tg of the composite reaches 258℃. Compared with pure PMMA, the thermal stability of the composite is greatly enhanced. 相似文献
26.
Li XIE Lihua XIE 《系统科学与复杂性》2007,20(2):262-272
We consider the stability of a random Riccati equation with a Markovian binary jump coefficient. More specifically, we are concerned with the boundedness of the solution of a random Riccati difference equation arising from Kalman filtering with measurement losses. A sufficient condition for the peak covariance stability is obtained which has a simpler form and is shown to be less conservative in some cases than a very recent result in existing literature. Furthermore, we show that a known sufficient condition is also necessary when the observability index equals one. 相似文献
27.
Lanju XU 《系统科学与复杂性》2007,20(1):30-40
In the present paper, we focus on constructive spherical codes. By employing algebraic geometry codes, we give an explicit construction of spherical code sequences. By making use of the idea involved in the proof of the Gilbert-Varshamov bound in coding theory, we construct a spherical code sequence in exponential time which meets the best-known asymptotic bound by Shamsiev and Wyner. 相似文献
28.
29.
Rein Vihalemm 《Foundations of Science》2007,12(3):223-234
The philosophical analysis of chemistry has advanced at such a pace during the last dozen years that the existence of philosophy of chemistry as an autonomous discipline cannot be doubted any more. The present paper will attempt to analyse the experience of philosophy of chemistry at the, so to say, meta-level. Philosophers of chemistry have especially stressed that all sciences need not be similar to physics. They have tried to argue for chemistry as its own type of science and for a pluralistic understanding of science in general. However, when stressing the specific character of chemistry, philosophers do not always analyse the question ‘What is science?’ theoretically. It is obvious that a ‘monistic’ understanding of science should not be based simply on physics as the epitome of science, regarding it as a historical accident that physics has obtained this status. The author’s point is that the philosophical and methodological image of science should not be chosen arbitrarily; instead, it should be theoretically elaborated as an idealization (theoretical model) substantiated on the historical practice of science. It is argued that although physics has, in a sense, justifiably obtained the status of a paradigm of science, chemistry, which is not simply a physical science, but a discipline with a dual character, is also relevant for elaborating a theoretical model of science. The theoretical model of science is a good tool for examining various issues in philosophy of chemistry as well as in philosophy of science or science studies generally. 相似文献
30.
Global Optimization in Any Minkowski Metric: A Permutation-Translation Simulated Annealing Algorithm for Multidimensional Scaling 总被引:3,自引:1,他引:2
It is well known that considering a non-Euclidean Minkowski metric in Multidimensional Scaling, either for the distance model
or for the loss function, increases the computational problem of local minima considerably. In this paper, we propose an algorithm
in which both the loss function and the composition rule can be considered in any Minkowski metric, using a multivariate randomly
alternating Simulated Annealing procedure with permutation and translation phases. The algorithm has been implemented in Fortran
and tested over classical and simulated data matrices with sizes up to 200 objects. A study has been carried out with some
of the common loss functions to determine the most suitable values for the main parameters. The experimental results confirm
the theoretical expectation that Simulated Annealing is a suitable strategy to deal by itself with the optimization problems
in Multidimensional Scaling, in particular for City-Block, Euclidean and Infinity metrics. 相似文献