^`H—NMR测定氰戊菊酯的立体结构与含量

本文运用核磁共振氢谱法并借助位移试剂Eu(fod)_3测定了氰戊菊酯四种旋光异构体的立体结构及其总含量,并对其R醇与S醇之比进行计算。同时,讨论了对上述结果的影响因素。     

Abnormal cerebellar development and axonal decussation due to mutations in AHI1 in Joubert syndrome

Joubert syndrome is a congenital brain malformation of the cerebellar vermis and brainstem with abnormalities of axonal decussation (crossing in the brain) affecting the corticospinal tract and superior cerebellar peduncles. Individuals with Joubert syndrome have motor and behavioral abnormalities, including an inability to walk due to severe clumsiness and 'mirror' movements, and cognitive and behavioral disturbances. Here we identified a locus associated with Joubert syndrome, JBTS3, on chromosome 6q23.2-q23.3 and found three deleterious mutations in AHI1, the first gene to be associated with Joubert syndrome. AHI1 is most highly expressed in brain, particularly in neurons that give rise to the crossing axons of the corticospinal tract and superior cerebellar peduncles. Comparative genetic analysis of AHI1 indicates that it has undergone positive evolutionary selection along the human lineage. Therefore, changes in AHI1 may have been important in the evolution of human-specific motor behaviors.     

Two-dimensional simulation of Poiseuille-Rayleigh-Bénard flows in binary fluids with Soret effect

Poiseuille-Rayleigh-Bénard flows in binary fluids with Soret effect are directly simulated by a mixed finite element method. A temperature perturbation is used as an initial disturbed source for the basic parallel flows. The whole spatio-temporal evolution of the binary fluid flows is exhibited: initially only the disturbed mode with the wavenumber k=π is amplified while others are damped, and continuously the amplified mode grows further and the nonlinear effect becomes important; after a nonlinear evolution transition the flow system evolves finally into a periodic right traveling wave.     

稀土对轧辊钢中非金属夹杂物的影响

研究了Ce对ZG75CrM0钢中非金属夹杂物的影响．结果表明，Ce可显著减少钢中夹杂物的含量、提高钢的洁净度、并使其些夹杂物性态改变；钢的室温塑韧性、抗热疲劳性、高温抗氧性均有明显提高．     

Ag(Ⅰ)-phen-TPPS_4荧光体系的研究及痕量银的测定

研究了Ag(I)-phen-TPPS_4荧光体系,建立了痕量银的荧光测定新方法。在碱性介质中,Ag(phen)_2~ 络阳离子与TPPS_4 的阴离子形成三元离子对缔合物(Ag:Phen:TPPS_4=1:2:1),导致TPPS_4 的荧光(λex=413 nm,λem=638 nm)猝灭而定量测定银。也可直接测定缔合物的荧光(λex=438 nm,λem=648 nm)而定量测定银。两种测定方法在Ag(I)浓度为0～3 μg/25 ml范周内,工作曲线呈良好线性关系,方法的检出限前者为0.88 PPb,后者为5.2 PPb。用于废水中微量银的测定,变异系数6％,标准加入量的回收率 92～107％。     

集聚效应对中国风电产业发展差异影响的实证研究

风电产业的发展是清洁能源发展的热点之一。本文从产业集聚效应的角度出发,深入研究了我国风电产业链的发展情况,利用地区集中度LQ指标对2009~2012年华北、东北、西北和江苏沿海风电产业集聚情况进行了实证研究,得出我国四大区域确实存在风电产业集聚现象。同时利用产业地区集中度cR指标测度各地的市场集中度,深入分析了我国典型地区的风电产业集聚特征,得出受集聚效应和各地经济资源禀赋不同的影响,我国风电产业发展存在差异且缺少地区间的产业联动发展,并提出相应的对策建议。     

植物基因克隆的方法和策略

芬子生物学的迅速发展对克隆植物基因起了积极的推作用，本篇旨在介绍植物基因克的策略及研究进展。     

基于STL-Informer-BiLSTM-XGB模型的供热负荷预测

供热负荷预测是指导供热系统调控的重要手段。提高供热负荷预测精度十分重要,针对机器学习中输出目标的分解预测,提出了一种基于季节和趋势分解(Seasonal and Trend decomposition using Loess, STL)的供热负荷预测方法,构建了适用于供热负荷预测的输出目标。首先利用STL算法将供热负荷时间序列数据分解为趋势分量、周期分量和残差分量,分别训练Informer、BiLSTM和XGB三个模型,将构建好的三个分量预测模型的输出叠加作为初步预测结果,分析误差序列,以BiLSTM预测误差提高模型精度,构建出STL-Informer-BiLSTM-XGB预测模型。将上述模型与常用预测模型进行对比,结果表明所构建的STL-Informer-BiLSTM-XGB 模型的MAPE、MAE和MSE,分别为0.871%、96.18和13202.2,预测效果最优,验证了所提出的方法具有较高的供热负荷预测精度。