改进的EBE预条件矩阵及其在有限元方程组求解中的应用

结构分析中的有限元法一般归结为线性方程组的求解,依据EBE(Element-by-Element)策略,有限元方程组的系数矩阵(即系统的总刚度矩阵)可以表示成低秩的单元级矩阵的和。针对这类形式的线性方程组,本文在EBE策略的基础上给出了改进的预条件矩阵,称其为MEBE预条件矩阵;结合共轭梯度法,可在不显式形成总刚度矩阵的情形下,得出适合于并行计算的MEBE-PCG算法,并在网络机群(COW)并行计算环境下结合实例对算法的效率进行了验证。     

贵州省遵义地区表层土壤中多环芳烃分布特征

调查研究了151个取至贵州省遵义地区12个市(县)的土壤中的多环芳烃(PAHs)的背景含量及与各市(县)总污染物排放量的关系.遵义地区各县(市)表层土壤中PAHs含量介于0.8～251 μg/kg,从单个化合物的检出情况来看,主要以二环、三环和四环PAHs检出率较高,其中四环以苯并(a)蒽,苯并(b)蒽及屈为主,检出率分别为41.7%,38.1%和34.4%.三环PAHs中以菲与蒽的检出率较高分别为37.1%和30.5%,具有两个环化合物以芴与苊为主,检出率分别为41.1%和27.8%.遵义地区各县(市)表层土壤PAHs检出特征虽大体相同,但其含量却有较大差异,其中遵义县∑PAHs的含量最最高,平均为74.5μg/kg,最低为绥阳县为13.74μg/kg,各采样点平均16种PAHs含量从低到高依次为:绥阳县、湄潭县、桐梓县、仁怀、务川县、余庆县、凤冈县、正安县、习水县、赤水县、道真县和遵义县.各县∑PAHs含量的差异与该县市空气与废水排放总量呈显著正相关,相关系数r为0.971,表明贵州土壤中的PAHs主要来自于能源物质的燃烧和PAHs全球范围内的自然迁移,但土壤处于较低污染状态.     

IIS控制器的ASIC设计与实现

介绍了IIS控制器的基本原理与实际应用,详细阐述了在专用集成电路中该控制器的设计思路,其中重点介绍了主控模块和收发模块的架构。在用verilog语言实现整个设计的基础上,运用ModelSim进行了功能仿真,利用SMIC0.13μm工艺库和SYNOPSYS的Design Compiler对其综合。经过FPGA验证,确保该控制器作为一个独立的IP核可嵌入到ASIC系统中。     

基于开发区联系的吉林省产业网络空间格局

开发区作为产业发展的重要载体,在地区产业发展和产业空间组织中发挥着重要作用.在回顾投入产出理论与产业网络研究的基础上,引入以产业强关联关系为纽带的开发区产业关联强度模型,以产业载体间联系视角综合分析了吉林省产业网络格局.结果表明:吉林省三大主导产业为食品加工业、医药化工业和交通运输设备制造业,且省内三大经济区产业发展各...     

基于FPGA的8K点FFT的设计与实现

采用4K点复数FFT实现8K实数点FFT;数据存储单元采用双口乒乓RAM结构;采用级联结构流水线的设计方式,基4蝶形结构完成前6级的运算,双基2蝶形结构完成最后一级运算;使用块浮点溢出检测.实验结果表明,在时钟周期为8.74ns的正常状态下,采用FFT处理器实现8K实数点FFT仅需要35.799μs,达到了高速运算的目的.     

Solvent effects on photophysical properties of copper and zinc porphyrins

The photophysics of Zn（tetraphenylporphyrin,TPP）, Zn（tetra-2,4,6-trimethylphenyl porphyrin, TMP）, Zn （tetra-（o-dichlorophenyl） porphyrin, TPPCI8）, Cu（tetraphenylporphyrin,TPP）, Cu（tetra-2,4,6-trimethyl- phenyl porphyrin,TMP）, and Cu（tetra-（o-dichlorophenyl） porphyrin, TPPCIE, TPPCI8） in several solvents have been investigated on steady state and time-resolved spectroscopy. The Cu（TPPCI8 ） is normal and shows no evidence of CT transition in the visible or near UV regions in nonpolar solvent. However, Cu（TPPCI8）shows a blue shift in the absorption spectrum and intramolecular CT bands at absorption spectra in polar solvent, which shows a fluorescence maximum emission at 650 nm and 8.4 ns lifetime. The reason can be attributed to two points. Firstly, the increase of solvent polarity can enlarge outer reorganisational energy, which is favorable to reduce the activation free energy of charger-transfer transition based on Marcus theory of electron transfer. Moreover, the internal heavy-atom effect on Cu（TPPCIE） is encouraging to stabilize the 2T1 state also, which increases the possibility of population to CT band from 2T1 state. This result is in accord with an earlier estimate of a 10 ns lifetime and CT absorption at 640 nm bands for the CT state of Cu （11） octethylporphyrins. Other possible reasons arousing unusual fluorescence like H-bonding, axial ligands, molecular aggregation are excluded.     

替硝唑缓释微球的制备及高效液相法测定的含量及包封率

目的:建立替硝唑缓释微球的制备方法及微球的含量和包封率的测定方法.方法:采用乳化溶剂扩散法制备替硝唑缓释微球及高效液相色谱法测定替硝唑缓释微球的含量及包封率,色谱条件:色谱柱为迪马C18(250 mm ×4.6 mm,5μm),流动相为甲醇-乙腈-水(20∶10∶70),检测波长为317nm.结果:替硝唑浓度在99.19 μg/mL～148.78 μg/mL范围内线性关系良好,R值为0.999 8.精密度试验RSD为0.94％,回收率为100.3％.结论:该制备和测定方法可用于替硝唑缓释微球的制备及含量和包封率的测定,且方法简便、快捷,准确可靠.     

用亚硫酸氢钠提高不饱和有机烯酸的产率

对合成山梨酸,肉桂酸,2—呋喃丙烯酸的方法进行了改进:在卤仿反应发生后,酸化前用亚硫酸氢钠去除去过量的次氯酸钠,产物的产率比直接酸化分别提高了21.3%,19.74%,27%,重结晶后纯度达99.05%,99.3%,99.1%。经红外,质谱,碳氢数据分析均符合要求。     

《河海大学学报(自然科学版)》1994～2003年引文统计分析及评价

应用文献计量学方法,对《河海大学学报(自然科学版)》1994～2003年间发表的1473篇论文所引用的6356条引文的数量、类型、语种、普赖斯指数、自引比例及引文中的主要中文期刊进行统计分析和定量研究,探索该刊引文的数量特征及其蕴含的情报价值,揭示作者对文献信息的掌握及利用规律．统计结果表明：《河海大学学报(自然科学版)》的年载文量、年引文量和引文率10年间总体呈现上升趋势,平均引文量为4．32条,引文率为94．2％,自引比例为5．5％;引文类型主要是期刊和图书,各占53．71％和34．63％;引文语种主要是汉语和英语,各占65．39％和34．09％;2003年《河海大学学报(自然科学版)》普赖斯指数为59．24％,比前面9年(普赖斯指数介于30％～40％之间)有较大幅度提高;位居《河海大学学报(自然科学版)》所涉及的研究主题贡献较大的核心区刊物有19种．     

Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst.

The photocatalytic splitting of water into hydrogen and oxygen using solar energy is a potentially clean and renewable source for hydrogen fuel. The first photocatalysts suitable for water splitting, or for activating hydrogen production from carbohydrate compounds made by plants from water and carbon dioxide, were developed several decades ago. But these catalysts operate with ultraviolet light, which accounts for only 4% of the incoming solar energy and thus renders the overall process impractical. For this reason, considerable efforts have been invested in developing photocatalysts capable of using the less energetic but more abundant visible light, which accounts for about 43% of the incoming solar energy. However, systems that are sufficiently stable and efficient for practical use have not yet been realized. Here we show that doping of indium-tantalum-oxide with nickel yields a series of photocatalysts, In(1-x)Ni(x)TaO(4) (x = 0-0.2), which induces direct splitting of water into stoichiometric amounts of oxygen and hydrogen under visible light irradiation with a quantum yield of about 0.66%. Our findings suggest that the use of solar energy for photocatalytic water splitting might provide a viable source for 'clean' hydrogen fuel, once the catalytic efficiency of the semiconductor system has been improved by increasing its surface area and suitable modifications of the surface sites.