25Hz微电子交流计数站内电码化调试存在问题分析

分析了微电子交流计数站内电码化在车出清区段后不能自动复原的问题,探讨了解决问题的方案,并提出了在受端发码时受端发码电源的调试范围。     

Heterogeneity,nonlinearity and endogenous market volatility

This paper aims to contribute to the literature on the explanatory power of behavior models with heterogeneous agents. The authors present a new nonlinear structural stock market model which is a nonlinear deterministic process buffeted by dynamic noise. An exogenous noise is introduced to the model with the assumption of IID normal innovations of the fundamental value in order to investigate how noisy dynamics interacts with deterministic process. The market is composed of two typical trader types: the rational fundamentalists and the boundedly rational traders governed by greed and fear. The interaction between noise and deterministic element determines the evolution process of the system as key parameters are changed. The authors find the model is able to generate time series that exhibit dynamical and statistical properties closely resembling those of the S&P500 index, such as volatility clustering, fat tails (leptokurtosis), autocorrelation in square and absolute return, larger amplitude, crashes and bubbles. The authors also investigate the nonlinear dependence structure in our data. The results indicate that the GARCH-type model cannot completely account for all nonlinearity in our simulated market, which is thus consistent with the results from real markets. It seems that the nonlinear structural model is more powerful to give a satisfied explanation to market behavior than the traditional stochastic approach.     

基于不确定理论的短期风险模型

在保险实务中,给定时间内的理赔总量是一个非常重要的数据,而针对该数据的模型更是保险风险分析中的基础模型.本文通过对给定时间内发生索赔的保单的研究分析,以不确定理论为工具,给出了两个带有限制条件的基于不确定理论的短期风险模型的分布,及其期望的一个性质.     

利用ETC技术的小区内无线车位锁设计

针对居住小区内的专用车位被随意占用现象,提出了基于ETC技术的自动控制车位锁系统。该系统通过无线自动控制装置,免去了每次都需要车主手动开锁车位或者利用无线控制器的情况。经过实验,该设计可以智能化地解决专属车位的随意占用现象。     

人参皂苷粉、银杏叶提取物对鸡胚绒毛尿囊膜血管新生的作用

为探讨人参皂苷粉和银杏叶提取物对鸡胚绒毛尿囊膜血管新生的影响,取孵育9天的种蛋,通过暴露鸡胚绒毛尿囊膜来建立模型,28只存活的鸡胚随机分为4组,包含两组空白载体的对照,一组加人参皂苷粉水溶液,一组加含银杏叶提取物药膜,作用3天后,观察分析鸡胚绒毛尿囊膜上血管生长的变化.结果显示:人参皂苷粉组,血管数量明显增多,但血管直径变细,颜色变淡;银杏叶提取物组,血管数量显著增多,血管颜色加深.研究发现:人参皂苷粉既能促进血管生成,又能抑制血管生成,总体表现为抑制;银杏叶提取物能够明显的促进血管的新生.     

基于金刚石结构碳的多孔材料设计及储氢性能研究

基于金刚石结构的碳设计了多孔材料,利用GCMC方法对其在温度为298 K,压强为0~100 bar的条件下的储氢量、氢分子分布和等量吸附热进行了讨论.考虑孔内壁以化学吸附的氢在内,PCM-2和PCM-3两种多孔材料的重量储氢量达到了相关机构规定的实际储氢应用的最低标准.氢分子密度分布图表明氢分子在孔道中的分布距离孔道边缘有一定的距离,此距离是因氢分子具有一定的动力学直径所致.等量吸附热表明多孔材料对氢分子的吸附属于物理吸附.     

考虑气流影响的直通穿孔管消声器声学性能

为了研究气流对消声器传递损失的影响,采用有限元法(finite element method,FEM)和计算流体力学法(computational fluid dynamics,CFD)相结合的方法来解决这种流声耦合问题.以直通穿孔管消声器为例,计算出它们存在气流时的传递损失,并与文献中的实验数据和预测结果进行对比,以验证计算结果的准确性.研究结果表明:当忽略消声器内部气流引起的湍流噪声时,随着气流速度的增加,除了共振峰值处的传递损失显著减小外,多数频率处的传递损失有所增加,尤其是在较高频段内变化较为明显;随着气流温度的增加,传递损失曲线向高频方向移动.     

一种新型荧光分子的密度泛函方法研究

采用密度泛函理论(DFT)中的B3LYP、B3P86、B3PW91、B1B95、O3LYP、M05、M06、MPW3PBE和B1LYP等不同方法对一种新型荧光材料进行了理论研究.在6-31+G*基组水平上对该荧光材料的结构进行了优化,用前线轨道(HOMO、LOMO)理论分析了分子的轨道间相互作用;用AIM 2000程序包计算了所有化合物的电荷密度,进行了成键临界点(BCP)电荷密度分析.实验比较了不同方法下各物质的零点能、吉布斯自由能、荧光光谱最大吸收峰波长大小.发现密度泛函理论中的O3LYP方法计算得出的荧光光谱的最大吸收峰波长大小约为370.35 nm,与实测值380 nm最为接近.     

Effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of La1−xMgxNi3.5 (x=0.20, 0.23, 0.25 at%) alloys

The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry.     

[bmim]Zn_2Cl_5/NH_3溶液的比热容和过量焓

测定了离子液体[bmim]Zn_2Cl_5在T=(323.15~1 173.15)K范围内的热重曲线,结果显示[bmim]Zn_2Cl_5在T637.15 K时具有很高的热稳定性。通过DSC测试得到[bmim]Zn_2Cl_5的比热容数据,在T=(251.15~383.15)K范围内可以用一个圆锥曲线很好地拟合。实验测定了[bmim]Zn_2Cl_5(2)+NH3(1)二元体系溶液的摩尔过量焓,其中氨的摩尔分数x1=(0.60~0.95),温度值为T=288.15 K,303.15 K,318.15 K,333.15 K。采用NRTL模型对过量焓数据进行拟合,得出二元可调参数和非随机参数。过量焓数据的测量误差和最大拟合偏差分别小于4.8%和4.3%。在[bmim]Zn_2Cl_5比热容和[bmim]Zn_2Cl_5/NH3过量焓数据的基础上,计算了氨质量分数w1=(0~1)、温度范围T=(273.15~343.15)K条件下[bmim]Zn_2Cl_5/NH3溶液的焓,所得焓浓图对于研究[bmim]Zn_2Cl_5/NH3吸收式制冷系统性能至关重要。