Effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of La1−xMgxNi3.5 (x=0.20, 0.23, 0.25 at%) alloys

The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry.     

移动式颗粒床除尘器的设计研究

分析了移动式颗粒床除尘器的特点,并与传统除尘器进行了比较。结合理论计算与实际运行试验,提出了移动式颗粒床除尘器主要结构参数及主要性能参数的设计计算方法,证明了该方法具有较好的实际应用价值。     

农业总产值影响因素分析

文章运用计量学方法分析影响农业总产值的因素,即通过对农产品的播种面积、受灾面积;耕地的灌溉面积、化肥施用量和机械用量的实证分析,运用经济学原理,引入计量经济学模型,得出结论:我国的农业生产由21世纪前的10年到21世纪后的10年取得了长足的发展,但整体农业发展水平还很低.     

浅谈建筑工程招投标现状

文章主要对目前建筑工程招投标现状进行分析,即对当前招标投标工作中存在的问题进行分析,对改进和完善现行建设工程招投标工作进行剖析,深刻说明了建筑工程招标现状,同时也提出了解决这一问题的方法.     

裂解汽油一段加氢催化剂的研究进展

乙烯工业副产物裂解汽油是芳烃抽提的重要原料,加氢精制是处理裂解汽油最有效、最经济的方法.文章主要介绍了裂解汽油一段加氢钯系、镍系催化荆的研究进展,同时指出裂解汽油一段加氢催化剂在工业应用上存在的问题.     

贵州红粘土的工程特性研究

贵州为典型的喀斯特地貌,广泛分布的碳酸盐岩、亚热带的温湿季风气候,为红粘土的形成提供了良好条件,文章结合工程实际描述了贵州红粘土的工程特性以及研究.     

工业设计教育中的教学设计——基于科学的学科分类之“设计教育”设计(一)

改革开放之后,中国设计业得到了快速发展,设计教育也快速成长起来。通过解读工业设计行业、教育和社会发展的变化,探究设计教育的真谛,科学地进行分类,合理地规划设计教学。根据工业设计学科的特点,实验性地提出一些措施,试图在教学形式上做出改变,以适应新时期设计行业和社会发展的需要。     

三种咪唑物质检测技术研究进展

咪唑、2-甲基咪唑及4-甲基咪唑是一类五元杂环小分子化合物,2-甲基咪唑和4-甲基咪唑是同分异构体,常是氨(铵)法生产食品添加剂—焦糖色素的副反应产物,是影响食品添加剂安全性的重要因素.其中4-甲基咪唑会抑制细胞色素P450同功酶,引起人体畸变、癌变等症状,危害人体健康.近年来,有文献先后报道了咪唑及(2-或4-)甲基...     

膜生物反应器处理工业废水的应用研究

介绍了膜生物反应器的类型,并列举了膜生物反应器在不同行业中废水处理中的应用。     

A genome-wide association study in Han Chinese identifies new susceptibility loci for ankylosing spondylitis

To identify susceptibility loci for ankylosing spondylitis, we performed a two-stage genome-wide association study in Han Chinese. In the discovery stage, we analyzed 1,356,350 autosomal SNPs in 1,837 individuals with ankylosing spondylitis and 4,231 controls; in the validation stage, we analyzed 30 suggestive SNPs in an additional 2,100 affected individuals and 3,496 controls. We identified two new susceptibility loci between EDIL3 and HAPLN1 at 5q14.3 (rs4552569; P = 8.77 × 10(-10)) and within ANO6 at 12q12 (rs17095830; P = 1.63 × 10(-8)). We also confirmed previously reported associations in Europeans within the major histocompatibility complex (MHC) region (top SNP, rs13202464; P < 5 × 10(-324)) and at 2p15 (rs10865331; P = 1.98 × 10(-8)). We show that rs13202464 within the MHC region mainly represents the risk effect of HLA-B*27 variants (including HLA-B*2704, HLA-B*2705 and HLA-B*2715) in Chinese. The two newly discovered loci implicate genes related to bone formation and cartilage development, suggesting their potential involvement in the etiology of ankylosing spondylitis.