聚苯硫醚交联反应机理的量子化学计算研究

用量子化学从头计算方法,利用静态理论对聚苯硫醚（ＰＰＳ）的交联机理进行了研究,通过对ＰＰＳ分子模型和可能产生的自由基模型的量子化学计算,探讨了ＰＰＳ的热交联反应趋势和交联结构,证实了氧在交联中所起的重要作用。     

Frobenius范数意义下矩阵的Young不等式

研究Young不等式的一些新的形式,给出在Frobenius范数意义下矩阵的Young不等式,表明更精确的上下界以及在新不等式中故有的充要条件依然成立．     

Deposition of bio-mimicking graphene sheets with lotus leaf-like and cell-like structures on the nickel substrate

Bio-mimicking graphene films,deposited on textured nickel substrates,were synthesized by the following method:replicating the surface textures of the lotus leaf by polymer duplication,fabricating textured nickel substrates by electroplating on the polymer coated with a Au film,preparing bio-mimicking graphene oxide films on the nickel substrates by vacuum filtration,and electrochemical reduction.By controlling the vacuum filtration,this replica method can not only replicate the lotus leaf structure by a graphene film,but also can achieve a novel cell-like graphene film.     

Preparation, characterization and photodegradation of methylene blue based on TiO2 microparticles modified with thiophene substituents

The new microparticles,2-formylthiophene(FT)/TiO2 and(E)-1,2-bis(5-formyl-2-thienyl) ethylene(EBFTE)/TiO2 were synthesized with a silane coupling agent.The prepared TiO2 composites were characterized using Ultraviolet-Vis absorption(UV-Vis),X-ray diffraction(XRD),scanning electron microscope(SEM) and thermogravimetric analyzer(TGA).Methylene blue was used as a model material to examine the photocatalytic activities of the prepared catalysts under both Ultraviolet-Vis(UV) and visible(Vis) light.The enhanced photocatalytic activities were observed in the presence of(FT)/TiO2 and EBFTE/TiO2 under Vis light.It suggests that FT or EBFTE plays a block or active role in the photodegradation mechanisms under UV and Vis light irradiation,respectively.     

Ionic liquids containing the urea moiety for recognition of halides and complex anions

A series of novel imidazolium based ionic liquids containing the urea moiety were designed and synthesized for anion recognition. 1-Ethylurea-3-methylimidazolium acetate ([Eumim]OAc) was used as the receptor for the halides and complex anions (BF4-, PF6-, BPh4-). 1H NMR spectra showed that the urea protons and imidazolium C(2) proton of the receptor ([Eumim]OAc) moved upfield on addition of various anions. A Job plot showed that the [Eumim]OAc receptor formed a 1:1 complex with BPh4-. X-ray diffraction analysis and the molecular modeling study revealed that the conformations of [Eumim]OAc and [Eumim]BPh4 were different. The conformational change of the cation was caused by anion exchange, and may provide an alternative to current methods for recognition of anions.     

罗非鱼鳞胶原蛋白提取工艺研究

研究用胃蛋白酶从罗非鱼鳞中提取胶原蛋白的工艺。根据测定水解液中羟脯氨酸(HYP)的含量计算胶原蛋白提取率,采用单因素和正交试验确定胃蛋白酶水解鱼鳞制备胶原蛋白的适宜酶解条件。结果表明,采用底物质量分数7%,胃蛋白酶酶解罗非鱼鳞制备胶原蛋白的适宜温度、pH、加酶量、时间分别为65℃、2.0、2%、2 h。在适宜工艺条件下,胶原蛋白提取率可达94.24%。     

公交服务可靠性研究

借鉴系统效能模型建立公交服务可靠性评价体系,确定公交服务质量的评价指标、计算公式和评价标准,建立评价模型,并采用层次分析法对公交服务可靠性进行综合评价。利用该模型对哈尔滨市具有代表性的102路公交的服务可靠性进行评价。结果表明,102路公交服务系统效能为0.585,公交服务可靠性较差。     

福州市鼓楼区小学教育资源空间可达性分析与评价

划片入学是教育部门缓解教育资源空间布局不均衡问题的重要解决办法。文章以福州市鼓楼区为例,运用改进的多级半径高斯两步移动搜寻法(MC2SFCA),对比划片入学前后小学资源空间可达性,分析划片入学政策是否改善了小学教育资源空间分布均衡性。结果显示:(1)福州市鼓楼区教育资源可达性东南区高、西北区低,城镇两极分化明显;街道内部可达性由中心向四周衰减,划片入学政策下的模型评价结果显示中心区高可达性区域面积大大减少,城镇间的可达性差距减小;(2)划片入学政策避免了大面积学区房炒作、优质教育资源供不应求以及教育资源冗余等问题,一定程度上改善了教育资源分布不均衡的现状。研究结果可为合理布局规划小学教育资源、制定划片入学政策提供参考。     

聚合膜的摩擦磨损性能

通过在四球摩擦磨损试验机和ＭＨＫ５００环块摩擦磨损机上的试验表明,在不同的润滑油中加入可聚合单体,可以有效降低金属表面的摩擦磨损,使润滑油的抗极压和抗疲劳性能都有显著提高·通过付立叶红外光谱仪分析表明,由于摩擦表面生成原位聚合膜,使摩擦系数和磨损量显著降低·     

力学谱技术在聚合物流体结构转变过程中的研究进展

介绍了近年来利用力学谱技术研究聚合物流体(聚合物熔体和高分子浓溶液)结构转变过程的进展,分析了分子质量和共混物质量浓度对单分散聚合物熔体液/液转变过程的影响及其液/液转变机制,并介绍了嵌段共聚物聚氧乙烯/聚氧丙烯/聚氧乙烯(PEO PPO PEO)浓溶液的相转变过程随温度、聚合物质量浓度和NaCl等因素变化的关系,指出了今后力学谱技术在软凝聚态领域有待于进一步研究的方向.