用光度法研究在3种溶剂中的硫氰酸钼(V)配合物

报道在3种溶剂中硫氨酸钠（V）配合物的生成情况，并以石油亚砜为萃取剂对其进行萃取研究，讨论了萃取剂的影响和有关萃取机理．     

非线性动力系统理论在机械故障诊断中的应用

从非线性动力系统理论的角度出发，对非线性动力系统进行了分析，据此建立了数学模型，并应用于实际的物理系统中．根据对Ｌｉａｐｕｎｏｖ指数的计算，分析了在非线性问题处理中各方法的优劣及其可靠性．作为尝试，文中试图利用非线性方法对故障进行分类，并对系统进行定性预测分析．实际结果表明在一定程度上是较为成功的     

一种改进的程序分频器

对铷频标中的频率合成器内的程序分频器进行了设计，并介绍了改进后的程序分频器。实验结果表明，该程序分频器用于铷频标的频综器中性能指标满足要求。     

The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

Studies on the reaction between Laccase ando-methoxyphenol by microcalorimetry

The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ _r H _m , ΔG _o , ΔG _T ^≠ and kinetic parameters (K _m ,k ₂) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state interactions are by nature inhibitory and only waste catalytic power. Supported by the National Natural Science Foundation of China Wang Tianzhi: born in 1968. Ph D     

全层片组织 TiAl 基合金室温断裂机理的研究

在ＳＥＭ和ＴＥＭ下对Ｔｉ３３Ａｌ３Ｃｒ０．５Ｍｏ合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸，并原位观察了试样中裂纹的形核及扩展过程．发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化；主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行．     

一种ARROW型弯曲波导研究

分别用射线分析法和电磁场分析法，通过保角变换在直角坐标系下研究ＡＲＲＯＷ型弯曲波导特性，导出了其模色散方程（本征模方程）。经优化设计的ＡＲＲＯＷ型弯曲波导结构，使ＴＥ０模的损耗降至为０．０３２９ｃｍ＾－１。     

RESEARCH ON THE STRUCTURE AND THE PROPERTY OF THE HYGROSCOPIC AND PERMEABLE FABRIC FOR SPORTSWEAR

Two structure models for knitting fabric are set up according to the wet-heat transmission principle of the fabric. Four kinds of knitted fabrics for sportswear are designed and produced. The wet-heat property of these fabrics is researched.     

一致凸线性距离空间的最佳联合逼近性

本文证明了一致凸线性距离空间存在唯一的最佳联合逼近元。     

用高阶曲线有限条法分析混凝土曲线梁桥

针对工程中提出的曲线梁桥的新课题，为了有效地进行全桥分析，获取设计所需的纵向、横向内力，文章采用高阶有限条法（ＨｉｇｈｏｒｄｅｒＦｉｎｉｔｅＳｔｒｉｐＭｅｔｈｏｄ）分析等截面曲线梁桥。其形函数用Ｈｅｒｍｉｔ函数法构造，形式简洁、运用能量原理从基于薄板的几何矩阵和基于线弹性的内力矩阵导出了单元刚度矩阵，采用ＦＯＲＴＲＡＮ－７７语言完成了编程工作．经过算例比较．说明了高阶曲线有限条法的简洁性和高精度性。