3D打印金属材料研究进展

3D打印技术是快速原型制造技术的一种,也被称为增材制造技术,被誉为"第三次工业革命"的核心技术,其中金属3D打印被认为是将来制造业的主导方向.金属粉末材料是金属打印的物质基础,同时也是3D打印技术发展的突破点.综述了3D打印金属粉体材料的研究现状,重点介绍了钛合金、铝合金、不锈钢、高温合金和镁合金等5种金属粉体材料在3D打印技术中的应用,并对金属粉体材料的运用进行总结和展望.     

离子交换色谱柱上橙皮苷分离与配位反应的一体化

提出并实现了橙皮苷分离及其与Cu2 配位反应一体化的新设想,并借助离子交换色谱、紫外可见光谱、X-射线衍射、傅立叶红外光谱和核磁共振等分析手段探讨其作用机理.结果表明,在离子交换色谱柱上能有效实现配体分离与配位反应的一体化,制备高生物活性中药配合物新药.其反应机理在于树脂相中软碱橙皮苷与溶液相中交界酸Cu2 间存在库仑力,容易发生配位反应,配体的分子状态和疏水状态因Cu2 对橙皮素的"集中效应"和芸香二糖对橙皮素的"包埋效应"而改变,故再生剂阴离子易穿过能斯特层与橙皮苷交换,并因电子云重叠而排斥橙皮苷至液相中,从而有助于分离、反应一体化.     

建筑构件多功能耐火试验炉的设计

为了适应多种建筑构件耐火试验,并提高试验的可靠性,根据GB/T9978—1999标准的要求,设计了水平建筑构件耐火试验炉和垂直建筑构件耐火试验炉各一座.通过合理布置燃烧器,使炉内的温度更均匀,利用自行设计的控制系统对炉内的温度及压力进行自动控制,克服了传统人工操作的各种缺点,同时也减少了污染,节省了空间,节约了燃料及人工成本.最后介绍了试验炉的使用情况,取得了较好的效果.     

计数标准型水泥搅拌桩质量抽检方案

针对水泥搅拌桩的质检特性,基于数理统计理论,提出了计数标准型水泥搅拌桩抽检方案.利用OC曲线对现有百分比抽检方案和计数标准型抽检方案进行了评价.根据水泥搅拌桩上部结构重要程度提出了3种不同的水泥搅拌桩抽检级别,并给出了不合格率、最大不合格率、生产方风险、使用方风险等抽检参数的取值,构建了水泥搅拌桩抽检流程.结果表明,计...     

番木瓜性别鉴定方法研究

番木瓜雌雄异株,有雄株、雌株和两性株3类植株.雄株不结果,在生产上是无用的,雌株的果实不如两性株的果实市场价值高,因此,从经济效益考虑,对番木瓜植株进行性别鉴定是十分必要的.但番木瓜性别分化和性别表现较迟,这给番木瓜性别早期鉴定带来很大困难.多年来,人们一直在寻求早期鉴定番木瓜性别的方法.目前已经产生了一些番木瓜性别鉴定方法,本文系统研究分析番木瓜性别鉴定方法及其进展.     

Effects of mechanical strain amplitude on the isothermal fatigue behavior of H13

Isothermal fatigue (IF) tests were performed on H13 tool steel subjected to three different mechanical strain amplitudes at a constant temperature to determine the effects of mechanical strain amplitude on the microstructure of the steel samples. The samples' extent of damage after IF tests was compared by observation of their cracks and calculation of their damage parameters. Optical microscopy (OM) and scanning electron microscopy (SEM) were used to observe the microstructure of the samples. Cracks were observed to initiate at the surface because the strains and stresses there were the largest during thermal cycling. Mechanical strain accelerated the damage and softening of the steel. A larger mechanical strain caused greater deformation of the steel, which made the precipitated carbides easier to gather and grow along the deformation direction, possibly resulting in softening of the material or the initiation of cracks.     

CASIO编程计算器在公路工程施工测量放样中的应用

CASIO编程计算器系列(4500p、4800以及4850型号)以其实用的编程功能,在各个领域得以广泛应用,尤其在公路工程使用领域,在设计、监理、施工、试验和管理方面得到了广大科技工作者的认可,文章以CASIO编程计算器在公路工程施工测量放样中的应用进行阐述.     

超细五氧化二锑的制备

以三氧化三锑和双氧水为原料，其量比为1：1．8，在90℃下回流反应60min，在稳定体系中制得水系五氧化二锑胶体；用喷雾干燥方法制备了平均粒径为0．5μm的五氧化二锑粉末，测试了其物化性能；加入5％的该产品在PVC中，其氧指数为39。     

Ostrowski-Reich定理在GETOR方法中的应用

定义广义ETOR（记为GETOR）方法，同时对GETOR方法建立了Ostrowski-Reich型定理，扩充了巳有的结果。     

Effect of protein molecules on the photoluminescence properties and stability of water-soluble CdSe/ZnS core-shell quantum dots

The fact that the photoluminescence properties of quantum dots are always strongly influenced by the environment limits the scope of further progress in the field of QD’ bio-applications. In this paper, the effects of immunoglobulin G (IgG) on the photo-luminescence properties and stability of water-soluble CdSe/ZnS core-shell quantum dots coated with amphiphilic poly (acrylic acid) (PAA) are studied. Photoluminescence (PL) spectra, UV-vis spectra and excited state lifetime measurements are used to characterize the influence of different protein molecules, such as IgG (goat anti-human IgG, rabbit anti-human IgG, human IgG, and goat anti-human IgG-human IgG conjugates), avidin and bovine serum albumin (BSA) on the PL properties of QDs. The PL intensity and stability of CdSe/ZnS are largely enhanced compared to that of pure CdSe/ZnS QDs when the IgG molecules are added into the QD solution. The PL intensity increases with increasing the IgG concentration, but there appears no influence on the PL peak and a full width at half maximum (FWHM). The PL evolution of QDs as a function of different protein molecules depends on the structure of protein molecules, which is used as a sensor to recognize human IgG. It is inferred that the interaction between PAA coating layer and IgG molecules results in the enhancement of PL intensity. The study of the effect of pH and ion strength on optical properties of QD-IgG mixed solution, compared with the pure QD solution, suggests that pH value and ion strength do not destroy the interaction between the PAA coating layer and IgG. Excited state lifetime analysis indicates that the PL enhancement comes from the passivation of surface of the QDs with the PAA coating layer. IgG molecules have no effects on the properties of the biological system but can increase the stability and PL intensity of CdSe/ZnS QDs, which will enlarge the application of QDs in biomedicine and other fields.