Synthesis and phase behavior of ω-(cholesteroxycarbonyloxy)-alkyl 3,3,5,5-tetramethyl-3,5-disila-4-oxacyclohexyl-carboxylate

Four new organosilane compounds containing cholesteryl group were synthesized by esterification of 3,3,5,5-tetramethyl-3,5-disila-4-oxa-cyclohexane-1-carboxylic acid and ω-hydroxyalkyl, cholesteryl carbonate in the presence of DCC and DMAP. Their structures were characterized by¹H-NMR, IR and elemental analysis. Their phase behaviors were investigated by differential scanning calorimetry (DSC) and polarized microscopy. Results showed that these four organosilane compounds were all liquid crystalline and longer spacer was advantageous to orientation of organosilane heterocycle and cholesteryl group. Biography: TANG Hong-Ding (1972-), male, Ph. D candidate, Research direction: orgenosilicon materials     

扶沟至西华高速公路路基路面排水设计

根据平原区实际状况,结合扶沟至西华高速公路的实际特点,详细阐述了本条高速公路路基、路面及分隔带排水设计要点及思路,为平原区高速公路排水设计积累了经验.     

口服胰岛素载体的研究进展

对于糖尿病病人而言,胰岛素给药的传统途径是通过皮下注射给药.多次反复的注射会给糖尿病病人带来巨大的痛苦.而胰岛素的口服给药具有巨大的优越性,可以极大的降低患者的注射痛苦.胰岛素作为蛋白质的一种,若口服给药将被人体蛋白酶分解.因此,选择装载胰岛素的载体的材料将非常重要.本文将从多聚糖,高分子纳米材料,脂质体和囊泡,凝胶等四种载体简单概述当前胰岛素药物载体的研究现状.     

低pH值下DACMC的制备、结构及热性能

在低pH值条件下采用NaIO4氧化羧甲基纤维素(CMC),制备了二醛羧甲基纤维素(DACMC),通过FT-IR、13C NMR、XRD和AFM等研究了pH值对NaIO4氧化CMC程度的影响,以及pH值对DACMC结晶结构、形貌结构、热稳定性的影响.结果表明:pH值对NaIO4氧化CMC的程度有显著的影响,但缺乏规律性,当pH值为1.5时其氧化程度最高(醛基含量最大为54.35%);FT-IR和13C NMR结果证实了在CMC分子链上有羰基产生;DACMC的结晶度均大于CMC,且随反应体系pH值的增加而增大;由于失水葡萄糖环的断裂,DACMC的分子链更加柔软,相互缠结得更加紧凑、规整,表面Z向尺寸随着醛基含量的增大而降低;DACMC的热稳定性差于CMC,pH=1.5的条件下制备的DACMC的热稳定性最差.     

选择性保护的萘烷酮的合成

报道了从1,3环己二酮出发,通过硅胶辅助与丁烯酮进行Michael共轭加成生成2(3氧)丁基1,3环己二酮,该化合物在苯中于回流温度下与苄胺缩合并环化生成了6苄氨基3,4,7,8六氢萘1(2H)酮,再用5%的盐酸水溶液于室温下水解,水解产物与乙二醇在对甲苯磺酸催化下反应得到萜类化合物合成的中间体选择性保护的萘烷酮,总收率约18%.     

Constrained oscillation of a bubble subjected to shock wave in microvessel

A three-phase coupled model of the gas–liquid–solid oscillation system is established to analyze the oscillation characteristics of a bubble inside a micro blood vessel with various radii and its shape changes with different interface boundaries. The results show that unlike the spherical symmetric oscillation in an unbounded fluid, the oscillating bubble has significant asymmetric characteristics under the constraint of a flexible microvessel, especially while its radius reduces to the same order of magnitude as that of the bubble. Moreover, the variation of microbubble motion, whether the geometric shape or oscillation feature, exhibits obvious differences in the micro blood vessel compared with the rigid wall. The reasons behind these phenomena are analyzed in this paper. The conclusions have significant importance in the understanding of the mechanism of microvessel injury in ultrasound therapy.     

深冷处理对高速钢高低温力学性能的影响研究

研究了深冷处理和未深冷处理的试样在室温及高温下的力学性能 .结果表明 ,深冷处理试样的力学性能明显提高 ;深冷处理和未深冷处理试样的磨损表面形貌和垂直截面形貌有显著差异 ,说明它们有不同的磨损规律 ;通过X 射线衍射还发现 ,深冷处理可使马氏体轴比和碳含量下降 ,促使新相碳化物MC析出 .     

青海野生大黄茶营养的成分分析

对青海野生大黄茶营养成分进行了分析，结果表明：野生大黄茶中含有蛋白质、脂肪、维生素C、胡萝卜素等营养物质，其中维生素C和胡萝卜素含量丰富，分别达到47.97mg/100g和0.41mg/kg，且氨基酸种类较多。青海野生大黄茶保持了大黄的有效药用成份-大黄素，是一种饮用方便的新型保健品。     

企业内部异构型网络的互联

通过对深圳市滨河污水处理厂污不处理集散控制系统和办公自动化管理信息系统的分析,将先后建成的生产型和管理型两套系统,组成一个完整的统一网络,实现了异构型双网互联     

HZY型振动运输机的激振方式与振动规律

建立了ＨＺＹ型振动运输机力学模型，运用相对运动原理对其振动规律进行了分析，探索了产生扭转振动的原因，推导出了稳定同步振动的运动方程，并提出了实现稳定同步运转的判据及相应的技术措施．这对采用双电机进行自同步振动机的设计具有指导意义．