Effect of protein molecules on the photoluminescence properties and stability of water-soluble CdSe/ZnS core-shell quantum dots

The fact that the photoluminescence properties of quantum dots are always strongly influenced by the environment limits the scope of further progress in the field of QD’ bio-applications. In this paper, the effects of immunoglobulin G (IgG) on the photo-luminescence properties and stability of water-soluble CdSe/ZnS core-shell quantum dots coated with amphiphilic poly (acrylic acid) (PAA) are studied. Photoluminescence (PL) spectra, UV-vis spectra and excited state lifetime measurements are used to characterize the influence of different protein molecules, such as IgG (goat anti-human IgG, rabbit anti-human IgG, human IgG, and goat anti-human IgG-human IgG conjugates), avidin and bovine serum albumin (BSA) on the PL properties of QDs. The PL intensity and stability of CdSe/ZnS are largely enhanced compared to that of pure CdSe/ZnS QDs when the IgG molecules are added into the QD solution. The PL intensity increases with increasing the IgG concentration, but there appears no influence on the PL peak and a full width at half maximum (FWHM). The PL evolution of QDs as a function of different protein molecules depends on the structure of protein molecules, which is used as a sensor to recognize human IgG. It is inferred that the interaction between PAA coating layer and IgG molecules results in the enhancement of PL intensity. The study of the effect of pH and ion strength on optical properties of QD-IgG mixed solution, compared with the pure QD solution, suggests that pH value and ion strength do not destroy the interaction between the PAA coating layer and IgG. Excited state lifetime analysis indicates that the PL enhancement comes from the passivation of surface of the QDs with the PAA coating layer. IgG molecules have no effects on the properties of the biological system but can increase the stability and PL intensity of CdSe/ZnS QDs, which will enlarge the application of QDs in biomedicine and other fields.     

陇南小城镇私立学校6-9岁学生膳食模式研究

通过对陇南市私立学校的学生营养状况进行调查，并经过对研究结果的分析，得出结论：在甘肃省陇南市，6-9岁儿童膳食结构比较合理，但是离平衡膳食有一定差距，也存在一定的问题。需要在增加粮谷类（粗粮）、蔬菜、豆类、水产品、动物内脏的供应，相应减少动物脂肪的供应；加强营养指导，提倡健康生活方式，优化现有饮食结构等方面高度重视。     

Syntheses,structure and photoluminescent properties of lanthanide oxalatosulfocarboxylate coordination polymers

Hydrothermal reactions of oxalic acid(H2ox) and 2-sulfobenzoic acid(H2L) with lanthanide oxide or hydroxide yielded five lanthanide oxalatosulfocarboxylates.They have a general formula [Ln2L2(ox)(H2O)6]n[Ln = La(1),Nd(2),Eu(3),Gd(4),Tb(5)].Their structures were characterized by single crystal X-ray diffraction,powder X-ray diffraction(PXRD),infrared(IR) spectroscopy,elemental analysis(EA),and thermogravimetric analysis(TGA).1-5 are isostructural coordination polymers and feature one-dimensional(1D) chains,which are extended into 3D supramolecular frameworks through inter-chain hydrogen bonds between coordinated H2O donors and oxygen acceptors from carboxylate,sulfonate and oxalate groups.In addition,the solid-state photoluminescence properties of the Nd(2),Eu(3) and Tb(5) derivatives have been measured at room temperature.The Eu and Tb-containing coordination polymers(CPs) exhibit intense red and green luminescence emissions,respectively,with lifetimes in the order of millisecond.     

弹性碰撞的图示分析法

通过引入牵连动量和相对动量等物理量,用图示分析法研究了弹性碰撞.研究结果表明,该方法可以形象而直观地描述弹性碰撞的过程和结果,对弹性碰撞的理论研究和实际应用都有重要的意义.     

Preparation and performance of dye-sensitized solar cells based on ZnO-modified TiO<Subscript>2</Subscript> electrodes

The ZnO-modified TiO₂ electrode was prepared by adding Zn(CH₃COO)₂·2H₂O to the TiO₂ colloid during the sol-gel production process, and was used in dye-sensitized solar cells (DSCs). The open circuit voltage (V _OC) and fill factor (ff) of the cells were improved significantly. The performances of the ZnO-modified TiO₂ electrode such as dark current, transient photocurrent, impedance, absorption spectra, and flat band potential (V _fb) were investigated. It is found that the interface charge recombination impedance increases and V _fb shifts about 200 mV toward the cathodic potential. The effect mechanism of ZnO modification on the performance of DSCs may be that ZnO occupies the surface states of the TiO₂ film.     

中华主流文化与文化软实力的提升

要使我国从文化大国成为文化强国，从经济大国成为经济强国，必须着力构建中华主流文化，提升文化软实力。其途径一是要正确认识中华主流文化在软实力建设中的核心地位，二是要发挥好文化软实力的积极作用。     

二醋酸碘苯促进的水相中酮和酚的直接反应

报道了二醋酸碘苯促进的水相中酮和酚的直接反应,在温和的条件下以中等收率合成了一系列的α-芳氧基酮.     

大跨度预应力框架梁应力测试技术研究

应力监测是预应力结构施工监控中的重要部分,结合工程实例介绍了基于混凝土应变测试预应力测试技术,对弥补预应力结构设计中误差,保证施工质量具有重要意义.     

生存的荒诞——戈尔丁《蝇王》的存在主义解读

英国诺贝尔文学奖获得者威廉·戈尔丁的代表作《蝇王》从存在主义视角对人类生存的荒诞进行了思考,本文试从《蝇王》对人类生存环境的荒诞和人与人存在关系的荒谬来分析它的存在主义特质。     

系数比例自适应算法的研究

系数比例自适应算法是利用系统的稀疏特性而发展起来的一种新的算法。这类算法为每一个滤波器系数引入一个成比例步长参数,使得成比例步长参数与滤波器系数的估计值成正比,保证了大系数获得大步长,缩短了算法的收敛时间。该文首先介绍了系数比例自适应算法的研究背景及研究现状,然后详细描述了典型的系数比例归一化最小均方(PNLMS)算法,最后重点介绍几种改进的PNLMS算法。