Petrogenesis of Aoyougou high-silica adakite in the North Qilian orogen, NW China: Evidence for decompression melting of oceanic slab

A trondhjemitic body occurs in the Aoyougou area,the western part of the North Qilian orogen.It is geochemically characterized by high SiO 2,Na 2 O (high Na/K),elevated Sr/Y and (La/Yb) N,positive Sr anomaly,relatively enriched large ion lithophile elements (LILEs) and light rare earth elements (LREEs),and depleted Nb,Ta,Ti,resembling the high-silica adakite.Zircon U-Pb SHRIMP dating yields a weighted mean age of 438±3 Ma.This age is significantly younger than eclogitization ages of 460-490 Ma in the North Qilian orogen,suggesting that formation of the adakite postdates the subduction of oceanic crust in association with closure of the ancient Qilian Ocean.Whole-rock Sr and Nd isotopic analyses give initial ratios of I Sr =0.7044 0.7047 and Nd (t)=3.0 4.1,indicating that they are derived from partial melting of the juvenile oceanic crust.In view of the tectonic evolution of the North Qilian orogen,the high-silica adakite was probably derived from decompression melting of the exhumed eclogite at the depth of ～60 km.     

Leptomeningeal metastasis from central nervous system tumors: A study of classification and stage in the spinal canal of 58 patients

Leptomeningeal metastasis (LM) is caused by the spread of malignant tumor cells into the subarachnoid space.However,classification and staging of LM in the spinal canal is rare in the literature.The authors reviewed the records of 58 Chinese patients with LM for clinical features,neuroimaging,and treatments.Gadolinium-enhanced magnetic resonance imaging (MRI) of brain and spinal cord were performed in all patients.Removal of intracranial tumors was performed in all patients and diagnoses were confirmed by histology.The study group consisted of 58 patients,with 29 cases presenting with intraspinal symptoms.Of the 58,8 patients underwent intraspinal tumor removal,8 received radiotherapy alone,9 received chemotherapy alone,and 34 patients received combined radiochemotherapy.We classified LM into 3 types:type L or leptomeninges LM,is subdivided into 2 subtypes (subtype LI and LII (a,b)),type N or nerve root LM is subdivided into 2 subtypes (subtype NI and NII (a,b)),and type M or mixed-type LM.We also divided LM into stages of I-IV according to the symptoms and the volume of the tumor based on spinal axial MRI.Type LI LM often occurs in patients with intracranial and intraspinal tumors found simultaneously.Patients who receive surgery for intracranial tumors may present with type N LM.Surgery is suitable for patients with NI LM and LIIb LM in stages III-IV,presenting with severe spinal symptoms.The prognosis is better for type N LM than type L LM.     

Ce-doped LiNi1/3Co（1/3-x/3）Mn1/3Cex/3O2 cathode materials for use in lithium ion batteries

LiNi1/3Co1/3Mn1/3O2 and Ce-doped LiNi1/3Co1/3Mn1/3O2 cathode materials were synthesized by a co-precipitation method and solid phase synthesis and characterized using X-ray diffraction(XRD) and scanning electron microscopy(SEM).The results indicated that the resultant cathode materials with different Ce content all had a good layer structure and high crystallinity.Electrochemical performance testing of the cathode materials showed that the discharge capacity increased with increasing Ce content while the initial reversible capacity attenuation decreased with Ce doping.When the Ce content of the cathode materials is x=0.2,and the current charge and discharge rate is a constant 0.2 C,the discharge capacity maintained 91% of its initial capacity after cycling 50 times.     

黑社会组织形成及其社会控制方式——基于成本-效益的“袍哥文化”分析

“袍哥文化”是我国长江中上游地区特有的社会文化,其初期组织形式以反清复明的民间组织为主．但由于人们对其文化内涵认识产生偏差以及对利益的盲目追求,导致“袍哥文化”下形成危害社会的黑社会组织。本文从文化视角分析“袍哥文化”对黑社会组织形成的作用,并建立成本一效益经济模型,探讨其社会控制方式。     

CseNaYC16：Sm3＋晶体的光学与磁学性质研究

掺杂三价稀土离子（Re3＋的Cs3NaYC16晶体,因具有优良的光学和磁学性质而得到了高度的重视。本文利用晶体场理论和自旋哈密顿理论分别对Cs2NaYCl6：Sm3＋晶体的光谱和电子顺磁共振谱（EPR）进行分析和计算。在叠加模型的基础上,通过对角化24x24能量矩阵研究cs2NaYCl6：Sm3＋时的能级、电子顺磁共振参数和超精细结构常数。计算结果与观测值能够较好的吻合并对结果进行讨论。     

切换系统超稳定的充分条件

研究了切换系统的超稳定问题．利用子系统交互能量的撅念,将子系统所获得的能量分为从系统输入获得的能量和从其他子系统获得的能量两部分．通过改变Popov积分不等式的积分限,对子系统所获得的能量进行限制．在每个子系统所获得的总能量有限的情况下,基于切换系统的耗散理论,分析了切换系统运动的超稳定和渐近超稳定性;利用正实引理和K...     

稀土元素掺杂TiO2光催化剂的改性及其性能和结构的研究

采用溶胶-凝胶法制备了稀土铽掺杂的纳米TiO2陶瓷光催化剂.研究了不同掺杂比例的铽（0.025%、0.05%、0.1%、0.15%、0.2%、0.25%、0.3%、0.35%）对二氧化钛催化活性的影响.污染水样的COD测试结果表明,掺杂铽的比例为0.15%时,TiO2的催化剂性能最好,COD去除率达90.9%.XRD结果表明铽掺杂纳米二氧化钛的主要晶型为锐钛矿.BET结果表明其催化活性与比表面积成正相关.     

分子生物计算在逻辑演算中的应用

DNA计算是一种基于生化反应机理的新型信息处理模式,与基于图灵机思想的电子计算机原理截然不同。近年来,DNA分子生物计算理论、实验技术的快速发展为DNA计算机的实现技术提供了一种新的理论和手段。文章首次尝试了DNA计算在逻辑演算中的应用,拓宽了DNA计算的应用领域。模型的最大优点是反应物可以在溶液中充分混合接触而进行生化反应,充分体现了DNA计算巨大并行性的优点,另外编码数和操作数都是线性增加的。     

化学信息学双语教学的探讨

素质教育背景下的双语教学体现了时代发展的需求,是实现国际化人才培养目标的有效途径。本文从化学信息学研究内容、学科应用、重要意义、发展前景等方面阐述开展化学信息学双语教学的重要性。明确化学信息学双语教学的目标与内容,并探讨进行双语教学的可行方式。针对化学信息学双语教学中的教材建设、教学方法、教学手段等关键问题,作了深入细致的思考及探讨。     

SO4^2--La2O3-TiO2固体超强酸催化水杨酸的酯化反应

首次以SO42--La2O3-TiO2为非均相催化剂,以水杨酸为原料,合成了水杨酸甲酯和乙酰水杨酸。考察了影响反应的条件,获得优化实验条件:n水杨酸:n甲醇为1:12,催化剂用量40 g/mol酸,反应5 h时,水杨酸甲酯的收率可达86%;n水杨酸:n乙酸酐为1:4,催化剂用量6 g/mol酸时,乙酰水杨酸的收率可达87%,同时催化剂回收再生容易,重复使用4次催化活性无明显降低,是一种环境友好的催化剂。