SO4^2--La2O3-TiO2固体超强酸催化水杨酸的酯化反应

首次以SO42--La2O3-TiO2为非均相催化剂,以水杨酸为原料,合成了水杨酸甲酯和乙酰水杨酸。考察了影响反应的条件,获得优化实验条件:n水杨酸:n甲醇为1:12,催化剂用量40 g/mol酸,反应5 h时,水杨酸甲酯的收率可达86%;n水杨酸:n乙酸酐为1:4,催化剂用量6 g/mol酸时,乙酰水杨酸的收率可达87%,同时催化剂回收再生容易,重复使用4次催化活性无明显降低,是一种环境友好的催化剂。     

毕节烟叶中性致香成分和潜香物质分析

利用HPLC、GC-MS对毕节地区5个典型植烟区考烟的中性挥发性香味及潜香成分进行了分析。结果表明:HPLC检测烟草多酚类物质总含量均在30 mg/g以上,不同产地的含量依次为赫章>毕节>金沙>大方>威宁。GC-MS检测出34种重要中性挥发性香味成分,其中新植二烯含量高,占总香味成分的85%-90.5%.毕节市烟区样的苯丙氨酸类物质总量、棕色化产物总量、类西柏烷类总量都显著高于其他烟区;大方烟区的香气物质总量,类胡萝卜降解产物总量、大马酮、香叶基丙酮、巨豆三烯酮B、D均显著高于其他烟区。     

差压浓度法测量气/固两相流质量流量

提出了一种通过使用文丘里管和电容传感器测量气／ 固两相混合物的差压和固相浓度来推导固相速度和质量流量的新方法,分别建立了均相流模型和分相流模型,使文丘里管既适用于稀相,也适用于浓相流动情况,扩大了其适用范围·不需测量气体单独流经文丘里管时产生的差压,适于工业上在线实时应用·     

Isolation and identification of a novel STR (D17S2204) in the vicinity of NF1 locus

Using a synthetic oligonucleotide (dA-dC)15 as a probe to screen a probe pool made by microdissected human chromosome band 17q11-q12, a DNA fragment containing (CA)16 was isolated, which is a novel short tandem repeat (STR) determined by searching in the GenBank and GDB. It has 8 allelic types with a PIC value of 0.61. The novel STR is conformed with Mendelian segregation according to the linkage analysis of a three-generation neurofibromatosis type Ⅰ (NF1) pedigree. The STR was localized at chromosome band 17q11-q12 in the vicinity of NF1 gene by FISH analysis. The accession number of the STR in GenBank and GDB is G32112 and D17S2204 respectively.     

基于AVS音频编码的信息隐藏方法

提出了一种基于AVS音频编码的信息隐藏方法.该方法基于AVS独特的量化与位平面编码模块,使用位平面嵌入与比例因子修改技术,可以有效降低编码器码率控制对信息隐藏效果的不利影响,而且不使数据载体音质受到破坏.在量化过程中实施信息的嵌入,嵌入过程中主动修改比例因子以降低量化噪声.将隐藏信息进行矢量分组与位平面处理,进而在量化过程中将其嵌入到量化频谱中.仿真结果证明：该方法可以有效降低编码器码率控制对信息隐藏效果的不利影响,且嵌入隐藏信息后AVS音质也无明显损失.     

三角代数上导子的两个结论

设R是有单位元的交换环,A,B都是R上的酉代数,M是非零(A,B)-酉双模,且作为左A-模和右B-模都是忠实的.记T=(A M0B)为由A,B,M构成的三角代数,D为T的导子.给出T满足[D(X),D(Y)]=0的导子的结构,并证明了三角代数T的导子都不是强保交换的.     

Retrieval of column-averaged volume mixing ratio of CO2 with ground-based high spectral resolution solar absorption

The total column-averaged volume mixing ratio of atmospheric carbon dioxide （Xco2） has been retrieved with high spectral resolution solar absorption data obtained from ground-based Fourier transform spectrometer （FTS） measurements at Xichong, a coastal site in the district of Shenzhen in southern China. Based on differential optical absorption spectroscopy （DOAS） theory, the Xco2 was retrieved by finding the best match of observed high spectral resolution solar absorption data and monochromatic radia- tion transfer model calculations. The averaged Xco2 in the whole observation period was about 394.9 ppm. The uncertainty of the retrieval was estimated to be 2.0 ppm （0.51%） by comparing retrievals at two bands. The preliminary results show that Xc% retrieved by this method can be used to validate satellite remote sensing of Xco2.     

基于多种群蚁群算法的变压器故障检测次序寻优方法研究

针对传统变压器故障检测次序的不足,在研究变压器故障树分析方法的基础上,提出了一种基于多种群蚁群算法的变压器故障检测次序寻优方法.首先给出了多种群蚁群算法的原理和模型;然后利用蚁群算法的全局优化和启发式寻优的特点,对变压器故障检测次序进行优化;最后,以分接开关故障树为例验证了多种群蚁群算法在变压器故障检测次序寻优中的可行性和有效性.     

Petrogenesis of Aoyougou high-silica adakite in the North Qilian orogen, NW China: Evidence for decompression melting of oceanic slab

A trondhjemitic body occurs in the Aoyougou area,the western part of the North Qilian orogen.It is geochemically characterized by high SiO 2,Na 2 O (high Na/K),elevated Sr/Y and (La/Yb) N,positive Sr anomaly,relatively enriched large ion lithophile elements (LILEs) and light rare earth elements (LREEs),and depleted Nb,Ta,Ti,resembling the high-silica adakite.Zircon U-Pb SHRIMP dating yields a weighted mean age of 438±3 Ma.This age is significantly younger than eclogitization ages of 460-490 Ma in the North Qilian orogen,suggesting that formation of the adakite postdates the subduction of oceanic crust in association with closure of the ancient Qilian Ocean.Whole-rock Sr and Nd isotopic analyses give initial ratios of I Sr =0.7044 0.7047 and Nd (t)=3.0 4.1,indicating that they are derived from partial melting of the juvenile oceanic crust.In view of the tectonic evolution of the North Qilian orogen,the high-silica adakite was probably derived from decompression melting of the exhumed eclogite at the depth of ～60 km.     

新型一维草酸钴化合物的水热合成和晶体结构

在水热条件下,成功合成出1例1D的新型草酸钴化合物—[Co(C2O4)0.5(H2O)]n(1).X-射线单晶衍射的分析表明,化合物(1)属于单斜晶系,C2/c空间群,晶胞参数为a=1.178 5(6)nm,b=0.542 5(3)nm,c=0.966 5(5)nm,β=126.371(5)°,Z=8.在化合物中,Co2+离子与草酸基团沿b轴交替连接而形成一个1D直链结构,这些链状结构之间又通过氢键作用而形成一个3D的超分子化合物.