Stability of diatomaceous silica and its geochemical implication

An experiment of stability of diatomaceous silica was performed. The results show that pH value and temperature dominantly influence the stability. The pH value concerning largely dissolving diatomaceous silica is 2-3 higher than that amorphous silica due to the buffer action of coexistent clay minerals. The solubility of diatomaceous silica rises distinctly when temperature is over 40℃, which suggests the cause of distribution of large-scale diatomite deposits in the middle to high latitude areas over the world. There is no close relationship between the solubility of diatomaceous silica and time, which shows that the content of diatomaceous silica in diatomite deposits are determined by the latest environment condition since they formed and bore no relation to the time they experienced.     

海南乡村排球发展的前景及特点

对海南汉区部分乡村排球发展情况进行了调查,探讨海南乡村排球发展的前景及特点,并提出开创单人排球竞技的构想     

石油污染对真鲷幼体中超氧化物歧化酶和过氧化氢酶的毒理效应

研究了在实验生态条件下,不同浓度可溶性０＃柴油的暴露对真鲷幼鱼内脏组织超氧化物歧化酶（ＳＯＤ）和过氧化氢酶（Ｃａｔ）活性的影响．实验结果表明：ＳＯＤ酶活性对于油污染胁迫呈现出明显的剂量－诱导效应关系．在同一剂量溶度作用下,延长暴油时间,能诱导鱼体内ＳＯＤ酶活性,抑制Ｃａｔ酶活性．当污染胁迫解除后,其幼体内脏组织中的ＳＯＤ酶和Ｃａｔ酶活力均得到不同程度的恢复     

随机可变负载下硅塑性行为预测

用有限元法分析了在随机加的圆柱形刻痕器作用下氮化铝的行为,模拟了应力场的整个扩展过程,结果显示,主应力的方向总是处于不停的随机变化之中;而完全卸载时残余张应力的方向最终将趋向于平行于刻痕表面,残余压应力平行于表面,这将易于导致材料的分层断裂;最大塑性应变区并不在整个接触面下。     

载体SiO2表面修饰对钒基催化剂丙烷氧化脱氢催化性能的影响

用ＸＲＤ,Ｒａｍａｎ,ＦＴ－ＩＲ,＾５１Ｖ－ＮＭＲ,Ｐｙ－ＩＲ和ＴＰＲ－ＴＰＯ表征ＳｉＯ２或ＳｉＯ２上预负载ＭｇＯ后负载的钒氧化物催化剂体系。ＳｉＯ２上直接负载钒氧化物,在钒负载量约为５ｗｔ％Ｖ２Ｏ５时出现Ｖ２Ｏ５晶相,而预负载ＭｇＯ在相同钒含量时则没有出现Ｖ２Ｏ５晶相,表面预负载ＭｇＯ促进了钒氧化物在载体表面的分散。     

虚拟专用网络的一般体系结构模型

互联网络的安全问题限制了许多应用的发展．虚拟专用网络技术则可在公用网络环境中向用户提供类似专用网络的信息传输框架．鉴于目前各种虚拟专用网络产品功能的局限性,尤其是在安全特性和互操作性方面的问题,本文在综合了一些主要厂家产品模型的基础上提出了一个通用的虚拟专用网络的体系结构模型．该模型可作为该项技术今后进一步发展和应用的理论指导,有助于技术的规范化     

面向对象Flow-shop调度问题的遗传算法求解

以面向对象的程度设计方法,实现了用遗传算法求解ＦｌｏｗＳｈｏｐ调度问题（ＦＳＳＰ）文中讨论了ＦＳＳＰ的不同存贮方式（ＵＩＳ、ＦＩＳ和ＮＩＳ）,时限问题以及不同的交叉算子对算法的作用     

渤海L油田早期注聚效果评价方法研究

目前对于早期注聚效果的评价没有成熟的方法,增油降水的效果基本依靠动态分析方法评价,由于早期注聚与晚期注聚的很大不同,造成动态分析方法在评价早期注聚效果方面存在很大的局限性。本文引入一种早期注聚效果评价的新方法,运用数值模拟技术对渤海L早期注聚效果进行全面的评价,建立高精度历史拟合的数值模型,并建立假想的水驱模型,使之与实际模型对比,结果表明,通过数值模拟法计算的增油量与动态分析法相比更加精确,原因是数值模拟法排除了各种措施带来的干扰,且考虑了油田的递减规律。另外建立了不同含水时机注聚的模型,通过分析认为,目前渤海L油田实行的早期注聚在各方面相较其他含水时机注聚具有很大优势。     

通风巷道围岩与空气换热的数值模拟

为有效利用巷道内排除的热空气,以大隆矿区矿井通风巷道为例,采用分离求解方法,对巷道围岩一空气换热系统进行三维数值模拟,分析巷道空气出口平均温度71P、巷道围岩与巷道内空气的平均总传热系数K、巷道空气平均出口热流密度q、风速口的变化规律。结果表明：v在0．2～1．0m／s时,耳较大;v越小,砟越接近于围岩初始温度。v在5．0～7．0m／s内,对K影响不大;当v〈5．0m／s时,K呈线性规律降低。v在0．2～5．0m／s时,q呈二次曲线渐变过程。丁随着”的减小、巷道长度的增加而增加。该结果为进一步研究围岩与空气的换热问题奠定了基础。     

Identification of petroleum aromatic fraction by comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry

Comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS) is com-mercially available in the 1990s, with the characteristics of large peak capacity, high resolution, high sensitivity, etc. However, its application to the petroleum and geological analyses is just emerging in China and overseas. In this research, the analytical method for petroleum aromatic fraction using GC×GC-TOFMS is set up, via the choice of the column system and optimization of setting parameters, such as temperature programming, modulation time, hot pulse time, flow rate of carrier gas, data acquisition rate and data processing. The results indicate that different polar compounds of aromatic fraction distribute as bands on structured GC×GC chromatogram. Within each band, homologous compounds appear as a roof-tile structure based on the number of substituent residues. The aromatic compounds are identified and characterized according to the GC×GC chromatogram and mass spectra. According to the polarity and the number of rings, aromatic compounds are spatially present on one chromatogram, which directly reflects the distribution characteristics of complex compounds of aromatic hydrocarbons. In addition, quantitative analysis is favored as some overlapped peaks on traditional GC-MS chromatogram have been separated completely on GC×GC. Some heterocyclic atom aromatic compounds at trace level can be clearly identified using this method, for polarity differences from other interfered aromatic compounds. The development of this method and chromatogram recognition offer petroleum geologists a practical example for the application performance of GC×GC-TOFMS.