外电场下SDB基本单元的氢氚取代的热力学研究

采用密度泛函B3P86方法在6-311G基组水平上对聚苯乙烯-二乙烯基苯(Polystyrene-Divinylbenzene SDB)单元结构分子在外场下的结构进行优化。根据热力学原理,研究了外场下SDB分子的氢氚取代反应的热力学性质,计算得到外场下SDB单元结构氢氚取代反应在不同温度下的标准生成自由能函变、反应平衡常数及氢氚反应的平衡压力比。表明T_2(g)+SDB_((H2))(s)→H_2(g)+SDB_((T2))(s)氢氚取代反应随外场的增加,在反应热力学上有利于正向反应的进行。     

福州温泉区地下热水有限元数值模拟研究

福州温泉区蕴藏着丰富的地下热水,然而长时间的过量开采,已造成地热水位下降,热水资源逐渐枯竭.针对这一状况,在对福州市温泉区复杂的地质概况及水文地质条件进行概化的基础上,对热田区热水动态进行三维有限元数值模拟,对其允许开采量进行了现状评估与预测分析     

Super-plasticity of Zr<Subscript>64.80</Subscript>Cu<Subscript>14.85</Subscript>Ni<Subscript>10.35</Subscript>Al<Subscript>10</Subscript> bulk metallic glass at room temperature

Generally, bulk metallic glasses （BMGs） exhibit a very limited plastic deformation under a compression load at room temperature, often less than 2% before fracturing. In this letter, through an appropriate choice of BMGs＇ composition, an amorphous rod of Zr64.80Cu14.85Ni10.35Al10 with a diameter of 2 mm was prepared by using copper mold suction casting. X-ray diffraction and differential scanning calorimetry were utilized to determine its structure and thermal stability, and the uniaxial compression test was adopted to study its plastic deformation behavior at room temperature simultaneously. The results showed that the glass transition temperature and onset temperature of the exothermic reaction of the amorphous rod were 646 and 750 K, respectively, and its micro-hardness was 594.7 Hv. During compression, when the engineering strain and engineering stress arrived at 9.05% and 1732 MPa, respectively, i.e., the true strain and true stress reached 9.42% and 1560 MPa, respectively, the amorphous rod started to yield. After yielding, with the increase of load, the strain increased and the glass rod ulti- mately were compressed into flake-like form. Although the maximum engineering strain was larger than 70%, i.e., the maximum true strain exceeded by 120%, the amorphous specimen was not fractured, indicating that it has super-plasticity at room temperature. Through the appropriate choice of composition and optimization of the technological process, flexible BMG with super-plasticity at room temperature could be produced.     

论设立统一规范公平的死亡赔偿金制度

结合多年的司法实践,笔者提出了我国死亡赔偿金立法存在的问题,并讨论了设立统一死亡赔偿金制度的必要性及可行性,对此制度的设立提出了自己的建议。     

浅谈旧关隧道建设中的质量管理措施

隧道工程质量控制是建设管理工作中的重中之重。文章从项目建设管理者角度出发,通过国道307线旧关隧道建设过程中的实际管理经验,对隧道建设中的质量管理措施进行了较为详细的阐述。     

连续的数据库数字水印检测算法

数据库数字水印的检测是数据库数字水印方案的关键环节之一,优良的检测方案可以增强水印的检测效率及性能.提出了一种连续的数据库数字水印检测算法,在保证检测准确度的情况下,可以较大幅度地提高数据库中水印检测的时间效率;对于数据库数字水印的子集替换和子集删除攻击具有较强的免疫性.通过实验对该算法进行了验证和比对分析,证明该算法具有比较理想的效果.     

Nd_3Fe_(29-x)Ti_x(x=1.3～2.0)化合物的成相范围及其温度特性(英文)

用热磁测量和X -光衍射谱研究了Nd3Fe2 9-xTix 化合物的成相范围及其温度特性 .研究发现 ,x =1.3～ 2 .0范围内的所有化合物都成单相 ,其晶体结构具有A2 /m空间群的单斜结构 .随着Ti含量的增加 ,晶格参数a ,b ,c几乎不变 ,而晶胞体积V略微增加 .每个样品都出现了自旋重取向现象 ,但自旋重取向温度Tsr和居里温度TC 几乎不随Ti的含量而改变 .