Thermal degradation of BaAl2Si2O8：Eu2＋ phosphor excited by near ultraviolet light

Eu2+ doped BaAl2Si2O8 phosphor was synthesized by one-step calcination of precursors that were prepared by chemical co-precipitation.The thermal degradation properties of BaAl2Si2O8:Eu2+ were investigated by photoluminescence,lifetime and chromaticity coordinate measurements.BaAl2Si2O8:Eu2+ is efficiently excited by incident light of 250-400 nm,which matches the emission of near ultraviolet LED chips well.BaAl2Si2O8:Eu2+ exhibits broad blue emission at 470 nm because of the 4f65d1-4f7(8S7/2) transition of Eu2+ ions,and the emission band shows an unusual blue shift with bandwidth broadening and emission intensity decreasing as the annealing temperature is increased.The luminescence decay and CIE chromaticity coordinates of BaAl2Si2O8:Eu2+ were determined to investigate its application in white LEDs.     

基于混合差分法的运动目标检测

为了提高背景重建速度和目标检测精度,提出了基于混合差分的运动目标检测方法.采用一种基于统计模型的区域像素级背景重建方法.结合帧差分法对于环境的适应性和背景差分法目标检测的准确性.首先用帧差分法得到目标最大的可能区域,在该区域进行像素级背景重建.然后用背景差分精确提取目标区域.既克服了单纯帧差分对于目标运动速度的限制,又缩小了背景差分的区域,使运动目标检测的时间复杂度迅速降低.通过实验,验证了该方法在检测精度和速度上的优势,可以应用于视频监控和目标跟踪领域.     

大采高综采破碎顶板液压支架压架致损机理分析

针对大采高综采工作面破碎顶板条件下液压支架破损情况,对液压支架破损的原因进行了探讨.在已有的两柱掩护式支架受力力学模型的基础上,建立了支架耳座、掩护梁的受力模型.分析结果表明,在大采高顶板破碎条件下,平衡千斤顶受到支架位态的影响处于受拉状态,导致耳座与掩护梁焊接处开裂;掩护梁在上覆岩层产生的压应力作用下产生弯曲应力,弯曲应力最大位置处布设的管孔易产生应力集中,导致掩护梁产生裂纹并贯通.     

[（n-Bu）4N]2[X2Mo4O10（OCH3）2]的合成与表征

本文选用醌类配体菲醌和酚类配体1，2-二羟基萘，合成了具有相似结构、通式为[(n-Bu)4N]2[X2Mo4O10(OCH3)2](X=OC10H6O和OC14H8O)的二种四聚钼多酸配合物，进行了元素分析、核磁共振、红外光谱和热重分析等表征．并对菲醌与钼多酸配合时由醌式状态向酚式结构的还原进行了研究和探讨．     

弯曲圆管中矿浆湍流场的三维数值模拟及分析

采用三维、定常、不可压缩,时均Ｎ－Ｓ方程和混合长湍流模型,建立了弯曲圆管中矿浆流动的控制方程和模型,使用有限元法对计算区域进行了离散,并对流动方程进行了求解,为减小用有限元法计算三维湍流场的计算量而采用了加罚有限元法。     

[(HOCH2)3CNH3]6[V10O28]的合成、晶体结构及性质研究

合成了一种新的有机一无机盐[(HOCH2)3,CNH3]6[V10O28],用IR、UV-Vis光谱及循环伏安法对其进行了表征,测定了化合物的晶体结构.该晶体属单斜晶系,P2(1)/n空间群,化学式为C24H72N6O46V10,分子量为1 690.28,晶胞参数:α=1.042 8(3)nm,b=1.639 8(5)nm,c=1.607 9(5)nm,α=90°,β=91.094(5)°,γ=90°,V=2.749 0(14)nm3,Z=2,残差因子R1=0.041 7,wR2=0.084 8.该化合物基于[V10O28]6-同多阴离子,通过与[(HOCH2)3CNH3] 之间的离子间相互作用以及氢键相互作用形成了以[(HOCH2)3CNH3] 为桥联的十钒酸根的有机/无机三维阵列结构.化合物溶液的光色性研究表明从有机分子到钒多酸阴离子之间发生电荷转移;电化学性质表明,该化合物在2.0mol/L H2SO4溶液中随着扫速的增加,还原和氧化的峰电位差距增加.     

基于结构元的模糊净现值研究

为了解决具有模糊年值和模糊折现率的净现值问题,采用模糊结构元方法对该问题进行分析推演,首先对模糊结构元理论进行简要的介绍,利用模糊结构元相关定理,推导了模糊净现值求解通式和模糊净现值的极限,得到了模糊净现值解析表达形式。最后,通过算例可知,结构元理论解析表达的模糊净现值,对其求解简单便捷。     

Effect of Mn cluster on the formation of superoxide radicals in photoinhibition of photosystem Ⅱ

To further realize the action of superoxide radicals (O₂^{− .}) in photoinhibition of photosystem Ⅱ (PSⅡ), we employed 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap, associated with EPR spectroscopy, to study the effect of illumination time on O₂^{− .} formation during high light photoinhibition in PSⅡ membranes and Mn-depleted PSⅡ membranes. Results indicated that the removal of Mn cluster from PS
membranes has a strong influence on the dynamics of superoxide formation. The relative mechanism was also discussed. These novel findings may further promote the studies of the structure and function of PSⅡ and the mechanism of photoinhibition.     

工程造价案例教学研究

文章分析了工程造价专业实施案例教学的必要性,设计出了工程造价案例的教学内容,并详细阐述了实施过程和实施后的总结评价,对工程造价专业实施案例教学具有很好的参考价值。     

Superresolution measurement on the minute fluctuation of cell membrane

A wide variety of the physical properties of cell membrane reflect life-cycle processes, including me- tabolism, respiration, photosynthesis, signal transduc- tion, transmembrane transport, and so on. So it is sig- nificant to investigate the elastic prop…