三种多元复合结构的核壳催化剂研究进展

以核壳结构复合而成的催化剂,在催化反应中常表现出较高的整体活性、大的比表面积、优异的择形催化效果和良好的热稳定性.部分催化载体因具有优异的择形效果和结构稳定性,在多元复合核壳催化剂的设计中也占据了一定的地位.本文主要介绍了几种常用催化剂载体(Al_2O_3、SiO_2、ZSM-5)参与复合的核壳催化剂制备与应用的概况.     

A Generic TC-Based Method to Find the Weakness in Different Phases of Masking Schemes

Masking is one of the most commonly used Side-Channel Attack(SCA) countermeasures and is built on a security framework, such as the ISW framework, and ensures theoretical security through secret sharing.Unfortunately, the theoretical security cannot guarantee practical security, because several possible weaknesses may exist in the actual implementation. These weaknesses likely come from the masking schemes or are introduced by the implementation methods. Finding the possible weakness of the masking scheme is an interesting and important issue for real applications. In this paper, the possible weaknesses for masking schemes in FieldProgrammable Gate Array(FPGA) design are discussed. It was found that the combinational circuit is the key to the security of masking schemes. The Toggle Count(TC) method and its extension are utilized to evaluate the security of masking schemes in the design phase and the implementation phase separately. Comparing different logic-level simulators for the Xilinx FPGA platform, the behavioral and post-translate simulations are considered as the analysis method in the design phase, while the post-map and the post-route simulations are used to find the weakness during the implementation phase. Moreover, a Standard Delay Format(SDF) based improvement scheme is proposed to significantly increase the effectiveness of the TC model.     

Shear-thickening behavior of Fe-ZSM5 zeolite slurry and its removal with alumina/boehmites

A cryogenic scanning electron microscopy (cryo-SEM) technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were found to contain agglomerations, which may break the flow of the pastes and cause shear-thickening behaviors. However, the shear-thickening behaviors can be eliminated by the addition of halloysite and various boehmites because of improved particle packing. Furthermore, compared with pure Fe-ZSM5 zeolite samples and its composite samples with halloysite, the samples with boehmite (Pural SB or Disperal) additions exhibited network structures in their cryo-SEM images; these structures could facilitate the storage and release of flow water, smooth paste flow, and avoid shear-thickening. By contrast, another boehmite (Versal 250) formed agglomerations rather than network structures after being added to the Fe-ZSM5 zeolite paste and resulted in shear-thickening behavior. Consequently, the results suggest that these network structures play key roles in eliminating the shear-thickening behavior.     

Corrosion behavior of high-strength spring steel for high-speed railway

The corrosion resistance and evolution of corrosion products in medium-carbon high-strength spring steels were investigated in a neutral salt spray (5wt% NaCl solution). A formation model of γ-FeOOH and a transformation model describing the conversion of γ-FeOOH to α-FeOOH were constructed. The results indicated that, at the initial corrosion stage, the corrosion resistance was gradually improved with the addition of Cr; however, with the addition of alloying element V, the corrosion resistance decreased. These results were attributed mainly to the initial corrosion stage being closely related to the matrix microstructure parameters such as grain-boundary character and dislocation density. After the rust layer was formed at a later corrosion stage, the corrosion resistance was reinforced with the addition of Cr and V because Cr strongly influenced the composition, structure, and morphology of the corrosion products. The results presented herein show that Cr was conducive to the transformation of γ-FeOOH into α-FeOOH. Moreover, V and Cr exhibited obvious synergy and were enriched in the inner layer of the corrosion products.     

交错立方体上限制容错单播算法的研究

在交错立方体中引入限制故障顶点集的概念,证明了当n≥3时,交错立方体中基于限制故障顶点集的限制连通度为2n-2,这一结果几乎是交错立方体上传统连通度的两倍;然后提出了基于该情形下的时间复杂度为O(「log|F|┐n~3)的容错单播算法,并证明了在最坏情形下,该算法构造出的无故障路径的最长路径长度的上界为5m+n-1,其中m=「log|F|┐;进一步利用上述算法进行仿真.     

Mechanical characterization and strain-rate sensitivity measurement of Ti- 7333 alloy based on nanoindentation and crystal plasticity modeling

The relationship between crystal orientations and meso-mechanical properties of β phase Ti-7333 titanium was investigated through the combination of nanoindentation experiments and simulation. The crystal plasticity finite element(CPFE) model for nanoindentation of single body-centered cubic crystal was established based on the experimental data. And the crystal plasticity constitutive law was implemented to simulate the nanoindentation process, obtaining satisfied results with an acceptable error. From the simulated pileup morphology patterns with different crystal orientations, it was found that the β phase experienced a symmetrical and orientation-related deformation process. Meanwhile, the strain-rate sensitivity(SRS) of β phase was investigated through nanoindentation tests based on continuous stiffness measurement(CSM) under different strain rates,varying between 0.2, 0.05 and 0.01 s~(-1). Two grains with different orientations exhibited similar SRS exponents,m, calculated from the experimental results.     

WO3 nanoflakes decorated with CuO clusters for enhanced photoelectrochemical water splitting

The low quantum efficiency arising from poor charges transfer and insufficient light absorption is one of the critical challenges toward achieving highly efficient water splitting in photoelectrochemical cells. Three dimensions(3D) structures and heterojunctions have received intensive research interests recent years due to their excellent ability to separate photo-generated charges as well as the enhanced light harvesting property. Herein,3 D Cu O/WO_3 structure was fabricated through a facile solvothermal method followed by chemical bath deposition. The loading of Cu O clusters on WO_3 nanoflake arrays results in a much improved photocurrent density compared with that of pristine WO_3 nanoflake arrays, which reaches 1.8 m A/cm2 at 1.23 V vs. the reversible hydrogen electrode. The electrochemical impedance spectroscopy measurement demonstrates that the improved performance of Cu O/WO_3 electrode is attributed to the accelerated charge transfer kinetics as a result of the desirable band alignment in Cu O/WO_3 heterojunction. This work demonstrates a facile strategy to construct superior WO_3 electrode, which will ultimately allow for efficient storage of solar energy into hydrogen.     

新的非线性常微分方程的可积类型

本文给出了文[1]、[2]研究的非线性常微分方程可积类型以统一的形式,提供了可积的充分条件及其通积分,并且推广了文[1]、[2]的有关结论,因而得到了新的非线性常微分方程的可积类型。     

一类数字图像篡改的被动认证

在没有被嵌入水印也没有辅助信息可利用的前提下，针对一类特殊的图像篡改——复制遮盖篡改即遮盖的内容复制自同一幅图像中，提出一种基于小波分解的自相关检测方法，将图像划分为相互重叠的小块，提取每一个小块的小波分解低频子带作为特征向量，采用Pearson相关系数进行块相似性匹配检测，实验结果表明该方法能够抵抗图像复制部位的无缝处理，对一般的高斯噪声、低通滤波、JPEG压缩等噪声攻击具有较好的鲁棒性。     

集中供热热管太阳能集热系统

大面积集中供热已成为节能降耗的新途径 ,也是太阳能热利用发展的趋势。在原有铜铝复合板的基础上 ,试制了一种结合多层建筑的集中供热热管式太阳能供热系统。我们对该集热系统进行了设计 ,并对系统的性能进行了测试。该系统结合建筑 ,利用集热板价格低的特点 ,充分利用楼层的集热面积 ,结构上体现了集中供热的特点 ,热量互为补充 ,能得到足够的热水