Ru基化合物催化制氢的研究进展

氢的存储是车载燃料电池发展的关键环节。甲醇在室温下呈液态并且储氢量达12.6wt%,然而分解甲醇制氢需要较高的温度(超过200℃)和压强(25~50bar)。最近研究者报道了利用单核钌(Ru)基化合物作催化剂,在常温常压条件下可以将甲醇分解成CO_2和H_2;利用双核Ru基化合物作催化剂,可以将多聚甲醛或甲醛与水的混合溶液有选择性地脱氢生成H_2和CO_2,但是关于Ru基化合物微观层次的催化机制还需要进一步研究。本文综述了不同配体构型和不同种类配体对催化剂活性的影响及其脱氢路径,以及催化剂的催化活性和溶液的pH值之间的关系,阐明如何改进现有单核Ru基钳型化合物和双核Ru基化合物催化剂的性能,设计催化活性更优良的新型催化剂。     

结构混凝土抗压强度预测RBF-ANN模型

为了达到对C20~C40范围内的结构混凝土抗压强度快速准确预测的目的,基于RBF-ANN模型基本原理及应用特点,在钻芯法、回弹法、超声波法及回弹-超声波综合法等大量室内和现场无损检测试验基础上,进一步应用Matlab2012b神经网络工具箱,建立了混凝土抗压强度RBF-ANN预测模型。该模型经充分训练后,应用于山西省重点建设工程项目的结构混凝土质量控制。工程实践表明,构建的RBF-ANN模型预测精度为4.4%,满足工程实际需要,具有较好的便捷性、经济性和准确性。     

澳洲大蠊与美洲大蠊总糖含量的比较研究

目的:比较澳洲大蠊与美洲大蠊中总糖含量的差异。方法:采用苯酚-硫酸法测定总糖含量。结果:澳洲大蠊中总糖平均含量为139.6 mg/g,美洲大蠊的为127.6 mg/g,两种蜚蠊的总糖含量差异无统计学意义。结论:两种蜚蠊中总糖含量丰富,且二者的含量比较差异无统计学意义。     

Description of rotational properties of the superheavy nucleus ^256,258,260Rf by projected shell model

Band structure of the Z = 104 nucleus 256Rf has been a recent research focus in nuclear physics. We performed projected shell model calculations for this and some other neighboring Rf isotopes. Specifically, we studied rotational properties of these nuclei and showed that variations in dynamic moment of inertia were sensitive to single-particle structures, which may be useful information for locating the anticipated island of stability. Electromagnetic transition properties were also calculated, and measurable quantities were predicted for further experimental test.     

安徽省分布新纪录——2种有毒植物

报道了安徽省2新分布记录种,分别为大戟科的山靛(Mercurialis leiocarpaSieb.et Zucc.)和齿裂大戟(Euphorbia dentata Michx.).该两种植物均具有一定的毒性,后者原产于美洲,为我国的入侵检疫物种,现在安徽黄山的山岔村、池州的江家冲附近发现有较大面积的分布,应予以关注.     

不同蓄水水位下大华斜坡体稳定性分析

结合坡体的地形地貌、水文地质条件、地层岩性特征,进行了不同水位情况下的斜坡稳定性计算.分析了不同蓄水水位对坡体稳定性的影响及其控制因素.     

沈阳市铁西区工人新村三期园区园林景观评价

从工人新村三期园区的园林景观整体入手,分析了硬质景观和软质景观,认为其充分体现了以人为本的设计理念.整体规划布局合理,园路顺畅,设施齐全、功能完备,植被丰富、四季青新,在绿化和美化了园区环境的同时,给人们的日常生活带来了极大的方便,具有明显的生态效益和社会效益,非常适宜市民居住和生活.但是,在水景景观和常绿树种配植方面略显不足,还有改进空间.     

西藏农村人力资本投资困境分析

农村人口综合素质整体不高,日益成为西藏农村反贫困和可持续发展的重要制约因素之一,加大人力资本投资日益迫切.文章提出没有基于本地化的农村办学思路,师资队伍整体落后与教育质量不高长期并存,教育投资观念偏差根深蒂固,基层卫生服务能力薄弱及健康知识普及严重不足等是当前西藏农村人力资本投资存在的诸多困境,并指出尽快优化教育发展结构、突出师资队伍建设、加强成人培训力度、关注妇女儿童健康是提高农村人口发展能力的重要途径.     

The influence of home environmental factors and life style on children＇s respiratory health in Xi＇an

To assess associations between home indoor air environments and asthma,allergies and pneumonia,children aged 1–8 years were surveyed from 12 kindergartens in the city of Xi’an.2,020 questionnaires were responded with a response rate of 83.5%.The prevalences of doctor diagnosed asthma,hay fever,and pneumonia were 2.9%,3.6%,and 28.3%,respectively.Living close to a highway was a risk factor for current rhinitis(AOR 1.5,95%CI 1.2–1.8),eczema(AOR 1.7,95%CI 1.2–2.5),and diagnosed pneumonia(AOR 1.3,95%CI 1.0–1.6).Dampness problems in the home were associated with 50%–130%increases in the prevalences of asthma and allergy.Airing bed linen under sun-shine was protective,especially against rhinitis.Pet avoidance was consistently and significantly associated with asthma and allergy(AOR 1.3–2.4).Decoration of the home during children’s early life is a risk factor for current rhinitis(AOR 1.9,95%CI 1.3–2.9)and eczema(AOR 1.9,95%CI1.1–3.6).Risk factors for pneumonia were living in an apartment(AOR 1.4,95%CI 1.1–1.8),latex wall paint(AOR 1.3,95%CI 1.0–1.7),dampness(AOR 1.4–1.5),breast feeding\3 months(AOR 1.3,95%CI 1.0–1.7),never airing bed linen in sunshine(AOR 1.3,95%CI1.3–1.6),and cleaning children’s room less frequently than once per day(AOR 1.4,95%CI 1.1–1.7).This study demonstrates that home indoor environmental and life style factors may influence the health of children in Xi’an.