新型掺Er3+碲酸盐玻璃光谱性质与Judd-Ofelt理论分析

采用高温熔融法制备了掺Er3 :TeO2-SiO2-Na2O系列玻璃样品.测试了样品中Er3 的发射光谱和吸收光谱.利用Judd-Ofelt理论计算了Judd-Ofelt强度参数Ωλ(λ=2,4,6)、Er3 各能级间跃迁的振子强度、跃迁几率、荧光分支比和辐射寿命等参数.利用测得的发射光谱计算了Er3 :4I13/2→4I15/2的荧光半高全宽(FWHM)值,其数值最大为63 nm.讨论了强度参数Ω6值与FWHM的关系及SiO2的含量对碲酸盐玻璃的光谱参数和光谱特性影响.结果表明,可以通过调整基质玻璃的组分来增加Ω6值,进而增强Er3 的1.5μm处的发射带宽.适量的SiO2的引入,提高了玻璃基质中Er-O键的共价性和玻璃刚性,使Er3 :4I13/2的辐射寿命最大值达到3.1 ms,同时还改善了Er3 的光谱性质,使得其玻璃基质更适合作为实现宽带放大和高增益放大的基质材料.     

纳米ZnO去除CH3 SH性能的研究

在常温、常压条件下,考察了平均粒径分别为14.3 nm,21.2 nm,24.1 nm,35.3 nm的ZnO和商品ZnO(约200 nm)对CH3SH的去除性能,通过FTIR和XPS等技术对脱硫反应后的试样进行了表征.结果表明,CH3SH主要以分子形式吸附于纳米ZnO表面,并随纳米ZnO粒径的减小,吸附在纳米ZnO表面上CH3SH的FTIR特征峰和硫物种XPS特征峰逐渐增强,CH3SH在纳米ZnO表面进一步脱质子,反应活性逐渐增大,脱硫性能逐渐提高.说明纳米ZnO的表面结构是影响脱硫性能的主要因素.     

Spatial prisoner’s dilemma games with increasing size of the interaction neighborhood on regular lattices

We studied the evolution of cooperation in the prisoner’s dilemma game on a square lattice where the size of the interaction neighborhood is considered. Firstly, the effects of noise and the cost-to-benefit ratio on the maintenance of cooperation were investigated. The results indicate that the cooperation frequency depends on the noise and cost-to-benefit ratio: cooperation reaches a climax as noise increases, but it monotonously decreases and even vanishes with the ratio increasing. Furthermore, we investigated how the size of the interaction neighborhood affects the emergence of cooperation in detail. Our study demonstrates that cooperation is remarkably enhanced by an increase in the size of the interaction neighborhood. However, cooperation died out when the size of the interaction neighborhood became too large since the system was similar to the mean-field system. On this basis, a cluster-forming mechanism acting among cooperators was also explored, and it showed that the moderate range of the neighborhood size is beneficial for forming larger cooperative clusters. Finally, large-scale Monte Carlo simulations were carried out to visualize and interpret these phenomena explicitly.     

公交服务可靠性研究

借鉴系统效能模型建立公交服务可靠性评价体系,确定公交服务质量的评价指标、计算公式和评价标准,建立评价模型,并采用层次分析法对公交服务可靠性进行综合评价。利用该模型对哈尔滨市具有代表性的102路公交的服务可靠性进行评价。结果表明,102路公交服务系统效能为0.585,公交服务可靠性较差。     

杭州市服务外包人才培训模式对高职教育发展的启示

杭州市服务外包人才培训在培训内容、模式创新、就业导向以及培训合作等方面具有鲜明特点,基本实现了学员培训与就业的无缝对接．对当前我国高等职业教育发展具有较强的借鉴和指导意义。本文在探讨杭州市服务外包人才培训的基础上重点从职业导向、专业设置、学生实训改革等方面分析了高职院校的发展问题与基本思路。以期有助于进一步提高我国高职教育的职业针对性。     

高硫天然气净化处理技术的集成开发与工业应用

针对高含硫天然气具有易燃、易爆、易腐蚀、易泄漏等特性,充分考虑了四川当地的自然条件,从净化处理的工艺过程入手,分析与比较了工艺路线、能源利用与节能以及安全环保措施等,确立了高含硫天然气净化处理的技术集成与工程化实施方案,该方案得到了成功的工业应用。     

Study on control strategy of CAN bus network based on event triggered mode

In order to reduce the load rate of CAN bus and improve the real-time performance of control system, CAN bus control system of a pure electric vehicle is studied. Communication messages of each node are optimized and redefined by sorting the message into three types: control message, status message and alarm message. Event triggered mode is added to the communication way of CAN bus, and the communication control strategy of the vehicle is made. It is proved that CAN bus load rate of control system is reduced after optimization, and the real-time performance of communication is improved effectively.     

鲁西地区铁矿类型特征及成矿谱系

山东省是中国的铁矿资源大省,其中鲁西地区铁矿成矿地质条件优越,铁矿类型有沉积变质型、接触交代型、热液交代充填-风化淋滤型、沉积型、岩浆型等多个成矿类型;其中尤以沉积变质型铁矿、接触交代型铁矿最为重要,是山东省的主要铁矿石来源。在梳理鲁西地区各种类型铁矿时空分布特点、分析典型铁矿床特征、控矿要素及矿床成因的基础上,以地质演化史为轴线,建立了鲁西地区各类型铁矿的成矿谱系。研究表明,在地质演化过程中,鲁西地区铁矿的形成是在海底火山喷发、地层沉积、岩浆侵入、区域变质、构造运动、风化淋滤等地质及成矿作用的高度耦合下形成的一系列地质产物;即在新太古代时期形成了沉积变质型铁矿(如韩旺式、苍峄式、杨庄式和济宁式铁矿)和岩浆型铁矿(如肖家沟式铁矿),在晚石炭世时期形成了沉积型铁矿(如山西式铁矿),在早白垩世时期形成了接触交代型铁矿(如莱芜式、莲子汪式铁矿)和热液交代充填-风化淋滤型铁矿(如朱崖式铁矿)。各种类型铁矿床具有地层控矿、岩体控矿、构造控矿和多要素共同控矿的特点。在铁矿勘查过程中,应按其成因类型和控矿要素进行有针对性的勘查部署,以此促进鲁西地区的铁矿勘查及研究工作整体水平得以提升。     

钢铁行业ERP产品编码分析

本文介绍了物料编码的基本规则、重要性,及钢铁行业产品编码一般采取的方法,及各种方法的之间的区别。     

s-p-d-f杂化轨道(Ⅰ)

Ⅰ引言现代的化学键理论,在处理分子结构问题上,已取得了很多成就。目前,电子配对法和分子轨道法是处理分子结构问题常用的两种方法,其中电子配对法的假定与化学家所熟知的价键概念相一致,所以用的比较普遍。在解释分子的几何构型和共价键的方向性方面,电子配对法的杂化轨道理论,显德更为重要。Pculing。首先造出「等性键函数」,后来,Slater。Hultgren、Eimball、Kuhn、Duffey、Torkington 等人做了很多的补充与推广。我国化学家唐敖庆教授,在这方面亦有特殊的贡献。