PDA加氢合成CHDA的工艺

1,4-环己二胺存在反式和顺式两种异构体.文中研究了对苯二胺在Ru/C催化下加氢合成trans-1,4-环己二胺的工艺体系,考察了反应压力、温度、催化剂用量以及催化剂制备方法对加氢体系的影响,并初步考察了催化剂的循环套用情况.结果表明,高温活化和碱处理可以大大提高催化性能,使产品中trans-1,4-环己二胺的含量明显增加.最佳工艺条件为:采用经500℃活化和碱处理的5%Ru/C,加氢反应温度为140℃,压力为8MPa;此条件下对苯二胺的转化率接近100%,1,4-环己二胺的选择性达90%以上,反顺比接近80∶20.     

氯化铁催化合成α-萘乙酸甲酯的研究

本文报道了以氯化铁为催化剂，以α-萘乙酸和甲醇为原料直接酯化合成α-萘乙酸甲酯的方法及最佳反应条件。     

Triazolotriazine-based thermally activated delayed fluorescence materials for highly efficient fluorescent organic light-emitting diodes (TSF-OLEDs)

Thermally activated delayed fluorescence (TADF) sensitized fluorescent organic light-emitting diodes (TSF-OLEDs) have shown great potential for the realization ...     

大化肥合成氨MODICON PLC系统故障分析及升级改造

分析了MODICON984 PLC的系统构成,热备功能及系统故障情况,介绍采用QUANTUM PLC在MODICONPLC升级改造应用及改造后系统的运行情况。     

聚己内酯/淀粉共混材料的非等温结晶动力学

以异氰酸酯（MDI）为相容剂,采用共混挤出技术制备不同含量的聚己内酯与淀粉的共混产物（SPCL）,通过X射线衍射及DSC研究SPCL的结晶性质和非等温结晶行为,分别用Ozawa法和Mo法对所得数据进行处理．结果表明：随着淀粉含量的增加,SPCL的结晶程度降低;淀粉在SPCL中起到了成核剂的作用,加快了聚己内酯（PCL）的结晶速度,但对PCL的结晶程度起抑制作用．建模结果表明,Ozawa法适于处理纯PCL的非等温结晶行为,但不适于处理SPCL共混物,而Mo法对PCL和SPCL共混物均适用．     

Detailed analysis of the plasma extracellular vesicle proteome after separation from lipoproteins

The isolation of extracellular vesicles (EVs) from blood is of great importance to understand the biological role of circulating EVs and to develop EVs as biomarkers of disease. Due to the concurrent presence of lipoprotein particles, however, blood is one of the most difficult body fluids to isolate EVs from. The aim of this study was to develop a robust method to isolate and characterise EVs from blood with minimal contamination by plasma proteins and lipoprotein particles. Plasma and serum were collected from healthy subjects, and EVs were isolated by size-exclusion chromatography (SEC), with most particles being present in fractions 8–12, while the bulk of the plasma proteins was present in fractions 11–28. Vesicle markers peaked in fractions 7–11; however, the same fractions also contained lipoprotein particles. The purity of EVs was improved by combining a density cushion with SEC to further separate lipoprotein particles from the vesicles, which reduced the contamination of lipoprotein particles by 100-fold. Using this novel isolation procedure, a total of 1187 proteins were identified in plasma EVs by mass spectrometry, of which several proteins are known as EV-associated proteins but have hitherto not been identified in the previous proteomic studies of plasma EVs. This study shows that SEC alone is unable to completely separate plasma EVs from lipoprotein particles. However, combining SEC with a density cushion significantly improved the separation of EVs from lipoproteins and allowed for a detailed analysis of the proteome of plasma EVs, thus making blood a viable source for EV biomarker discovery.     

AC发泡剂新工艺研究-Ⅱ.氯酸盐氧化法

在一定量的催化剂ＰＣ—６存在下，通过控制Ｂｒ－离子浓度、盐酸浓度和温度等因素．使氯酸钠与联二脲反应生成偶氮二甲酰胺，获得纯度为９９．９％，得率在９７．５％以上的产品． 此法不仅在产品得率方面。同时还在设备操作的简便性，母液的循环使用及减轻污染等方面均较目前国内采用的氯气法优越．     

三相电弧炉电气系统模型的探讨

本文为进行电弧炉系统谐波分析的仿真研究,在理论上作了初步探讨。首先建立交流电弧的等效数学模型,并根据电弧炉电弧工作的实际情况加以修正,得到不同工作状态下的电弧模型,在此基础上导出了电弧炉系统的状态方程。     

E~n中的一个三角不等式

本文直立了Ｅｎ中的Ｎ（Ｎ＞ｎ≥２）个定向超平面两两之间夹角的正弦不等式．     

关于随机变量一致完全收敛性的若干定理

本文定义了随机变量的一致完全收敛性,并获得了相应的若干收敛性定理。