有机二氟化磷双核铜(Ⅰ)配合物的合成和表征

合成了三个新型的有机二氟化磷双核铜(Ⅰ)配合物[Cu_2Cl_2(2.5-Me_2PhPF_2)_2]、[Cu_2Cl_2(Ne_2NPF_2)_2]和[Cu_2Cl_2(F_2POCH_2CH_2OPF_2)_2]。通过元素分析、分子量测定、红外光谱和~(31)P-NMR光谱对这些配合物进行了表征。研究发现,在这些配合物的结构中,Cl~(-1)桥联两个Cu(Ⅰ)使其具有桥式结构,配体中的两个P原子分别与两个Cu(Ⅰ),P—Cu(Ⅰ)反馈π键的强度随着和P相联原子的电负性的增大而增强。     

Application and realization of hierarchical network planning based on Web

Making use of Microsoft Visual Studio. NET platform, hierarchical network planning is realized in working procedure time-optimization of the construction by TBM. and hierarchical network graph of the construction by TBM is drawn based on browser. Then the theory of system realization is discussed, six components of system that can be reused are explained emphatically. The realization of hierarchical network panning in Internet provides available guarantee for controlling rate of progress in large-scale or middle-sized projects.     

Discussion on the new space of strategic development and function of Hengsha,Shanghai

Integrating various resource advantages including location, land, coastline and waterway, Heng- sha, Shanghai will be the new space of strategic development in the future （especially after 2020）. Inspired by marine economic development and continual establishment for new strategic space of coastal cities, in this pa- per we will take the strategic development direction of Hengsha new space into consideration when enlarging on the positioning of the new development space in Hengsha, which includes international logistic center （free har- bor and logistic transshipment center）, modem port industry, high-end services, tourism, leisure, and recre- ation and ecological village in downtown area.     

麦草碱木质素的氧化和磺甲基化改性

针对麦草碱木质素水溶性差、相对分子质量低的问题,以Fenton试剂为氧化剂、亚硫酸钠为磺化剂对麦草浆碱木质素进行氧化和磺甲基化改性.采用分子轨道理论对碱木质素和羟甲基化碱木质素分子单元进行了电荷密度计算,发现愈创木基单元中苯环上的C-5位最容易进行磺甲基反应.将麦草碱木质素经氧化后进行磺甲基化反应,得到磺甲基化碱木质素,红外光谱测试表明产物中具有磺酸基的特征吸收峰,电导滴定法测得其磺化度为0.96mmol/g,Zeisel法测得甲氧基含量为5.41%,凝胶渗透色谱测得其重均相对分子质量M-w达6 653.当溶液质量浓度为30 g/L时,溶液表面张力达45.3mN/m.水泥净浆流动度测试表明,产物对水泥净浆的分散性能与木质素磺酸钙相近.     

A_r~+激光诱导氯气刻蚀硅

本文通过被局域刻蚀硅表面形貌的精确测量,考察了刻蚀速率对于激光功率、波长、反应室气压的依赖关系,讨论了在不同光斑尺寸和刻蚀深度下反应机理的变化,给出了衬底晶向和表面氧化层对刻蚀效果影响的一些新的结果。     

杜氏藻Dunaliellapeircei超微结构研究

两类糖蛋白纤维构成了Dunaliella peirces的细胞外被,鞭毛和基本分别为“9+2”和“9+0”结构,首次发现的中心粒由9个三联体组成,高尔基体1～2个,眼点位于细胞质中,由二排椭圆形小球构成,内质网丰富,线粒体形状多样,在“杯形”叶绿体中发现了雏形的基粒及“杯”上的小孔,叶绿体前端凹凸不平,后端具大型淀粉核一个,细胞核位于“杯形”叶绿体的凹窝中。     

Effects of calcineurin on LTP of rats <Emphasis Type="Italic">in vivo</Emphasis>

Calcineurin (CN) is thought to play a role in the synaptic plastivity and long-term potentiation (LTP) in the hippocampus. Based on two LTP models in vivo, a specific inhibitor cyclosporin A (CsA) of CN was observed, which affected LTP in the hippocampal dentate gyrus of the rats. The results indicated that CsA blocked LTP induced by high frequency stimulation (HFS) partly, but it had no effect on the decrease of the onset and peak latency of population spikes (PS) except that it reduced the increase of the amplitude after HFS. On the other hand, CsA blocked LTP induced by ginsenosides (GSS) completely. It suppressed the GSS-enhanced amplitude of PS reversibly and blocked the decrease of the peak latency of PS induced by the GSS. These results suggest that the postsynaptic CN plays a role in the induction of LTP in the hippocampus of the rats.     

基于AT89C52与MFC的电阻率分布监测系统

文中研究了一种基于AT89C52与MFC( Microsoft Foundation Classes)的电阻率分布监测系统,它可以实时地监测16个电极两两之间的电阻.文中讨论了系统的结构和工作原理,并重点讨论了以AT89C52微处理器为核心的下位机监测仪表的结构和工作原理、硬件电路、软件设计和以MFC编写的上位机软件.     

花鲈种质资源的研究进展

中、日、韩三国学者对花鲈分类、人工繁殖和养殖技术作了研究,日本学者提出中日花鲈为两种,有待分子水平上的进一步研究确认。花鲈种质问题亟待解决,可通过现代生物技术予以解决。该问题的解决可为花鲈资源保护和持续利用提供理论依据。     

浅谈地下水过量开采的危害及防治

地下水是社会发展的重要资源,长期的过度开采已形成诸多环境地质问题,造成了巨大的经济损失并带来一些社会问题.本文参考多个地区水文地质状况、地下水开采情况及治理措施,总结了地下水超采的危害,并对地下水的开采管理提出了一些建议.