邻氨基噻唑偶氮类试剂质子化机理的研究

邻氨基噻唑偶氮类试剂［１～３］在不同酸度下呈现不同的颜色,关于其质子化发生的位置以及先后次序至今尚未见文献报道．本文通过量子化学计算,结合分光光度法对这类试剂质子化行为进行了研究．１实验方法１．１吸收光谱测定移取１．０ｍＬ１．０×１０－３ｍｏｌ／ＬＴ...     

A QTL for rice grain width and weight encodes a previously unknown RING-type E3 ubiquitin ligase

Grain weight is one of the most important components of grain yield and is controlled by quantitative trait loci (QTLs) derived from natural variations in crops. However, the molecular roles of QTLs in the regulation of grain weight have not been fully elucidated. Here, we report the cloning and characterization of GW2, a new QTL that controls rice grain width and weight. Our data show that GW2 encodes a previously unknown RING-type protein with E3 ubiquitin ligase activity, which is known to function in the degradation by the ubiquitin-proteasome pathway. Loss of GW2 function increased cell numbers, resulting in a larger (wider) spikelet hull, and it accelerated the grain milk filling rate, resulting in enhanced grain width, weight and yield. Our results suggest that GW2 negatively regulates cell division by targeting its substrate(s) to proteasomes for regulated proteolysis. The functional characterization of GW2 provides insight into the mechanism of seed development and is a potential tool for improving grain yield in crops.     

盾构克泥效浆液成分与渗透扩散研究

克泥效工法常在盾构隧道近接既有建筑物穿越工程中被引进作为控制地层位移的一种辅助工法,克泥效浆液在地层的渗透扩散性对盾壳与地层间环向间隙填充效果有着重要影响,克泥效浆液的流变性能与其微观成分对其流动性有着重要影响。本文基于对克泥效浆液流变性能与微观成分分析,研究了浆液性能变化。进一步结合宾汉姆流体砂土渗流公式与数值计算模型,分析了浆液性能对渗透效果的具体影响,并验证数值模型可靠性与合理性。结果表明:(1)各组克泥效浆液样本在宾汉姆本构下的非线性回归系数均大于0.95,塑性黏度与屈服强度会随着水粉比的减小而增大。(2)克泥效浆液主要成分为石英、斜长石、伊利石、钾长石,随着A液水粉比的增加,克泥效水化产物斜长石增加,而伊利石的含量减小。(3)克泥效浆液会在25s左右占满环向间隙,而后再向地层中发生渗透扩散,地层中浆液体积分数增速随时间而减小,直至增速降为0。(4)随A液水粉比增大、地层渗透系数增加、注浆压力增加,克泥效在地层渗透距离均会增加。理论渗透值与数值模型计算值误差在各工况下的平均误差控制在10%以内。     

基于粒子群算法最优化Verhulst模型的开采残余下沉预测

矿区开采引起的残余下沉稳定时间长、潜在危害大,有必要准确地预测矿区地表的残余下沉。鉴于传统的残余下沉Verhulst模型建模误差大、适用性弱,在建模过程中以数据序列的首个数据保持不变导致预测效果差的缺陷,以直接离散Verhulst模型为基础,引入粒子群算法寻求模型迭代初始值的最优解,建立基于粒子群算法优化的矿区开采残余下沉直接离散Verhulst模型,并以山西阳泉和山东兖州矿区两个时间尺度的地表残余下沉监测数据集进行实例验证,最后利用Matlab App Designer工具实现模型算法的可视化。结果表明：基于粒子群算法优化的直接离散Verhulst模型的矿区开采残余下沉预测精度和稳定性增益明显,所开发的计算工具具有正确性和有效性。     

超深圆形基坑地下连续墙支护结构体系力学性能分析

为了定量研究超深圆形基坑地下连续墙支护结构体系的受力和变形机理,本文通过Midas GTS建立超深圆形基坑施作过程的精细化有限元模型,通过改变地下连续墙局部弱化程度、地下连续墙先行幅和后续幅数量和嵌固深度等参数,对围护结构受力、变形和基坑周边地表沉降等规律进行了分析,分析结果显示:1）本工程的围护结构设计具有一定的优化空间;2）围护结构的水平最大变形和最大应力集中于第8~10道环梁处;3）围护结构的变形随幅间弱化程度和幅数的增加而增加,围护结构应力随幅间弱化程度和幅数增加而减小;基坑周边地表沉降随幅间弱化程度和幅数的增加而增加。分析结果对类似超深圆形基坑的设计和施工具有一定的借鉴意义。     

基于形状记忆合金丝的柔性康复手套设计

针对康复手套穿戴舒适度低、整体结构复杂等问题,研究一种基于形状记忆合金丝驱动的柔性可穿戴康复手套.根据人手生物结构和运动范围分析,设计贴合人手的可穿戴康复手套,并对形状记忆合金驱动器的收缩性能进行动力学和热力学分析.搭建康复手套试验平台,进行连续被动和镜像康复训练试验,结果表明基于形状记忆合金的柔性康复手套可实现手部伸展拉伸等康复训练,验证了该康复手套设计的有效性.     

Research on secure buyer-seller watermarking protocol

A new buyer-seller watermarking protocol is proposed by applying a double encryption method and a novel mechanism of embedding a buyer＇s watermark. The protocol can effectively prevent against collusion attacks and the man in the middle attack if the third party is not trusted. Also, based on the proposed scheme for the first-hand transaction, a new buyer-reseller watermarking protocol and a formal multi-party watermarking protocol are also proposed. The proposed buyer-resell watermarking protocol only needs the original seller to provide transfer certificate and encryption-decryption service to support the second-hand transaction, and the multi-party watermarking protocol with distributed certificate authorities can overcome the difficulty in the combination of multicast mechanism with multiple unique watermarks and allow a seller to multicast the watermarked digital contents and key transaction information to n buyers. Furthermore, the idea of zero knowledge proof is also applied into the proposed scheme to allow the seller to take an effective control on the task performed by the third party.     

基于旋转角度的跑步运动仿真

提出基于旋转角度的方法仿真跑步运动.跑步时人体四肢和躯干都在绕关节做重复旋转运动,基于旋转角度的跑步模型根据各关节的旋转角度计算人体运动时不同部位的位置,进而求解跑步运动行为.根据该模型提出一种跑步运动仿真方法/程序,该方法可以用于跑步运动仿真和提供建模所需的人体部位的位置数据,因而可缩短建模周期.用一个慢跑仿真案例示例了该方法的仿真过程.     

UWB通信系统隐蔽性能仿真分析及系统设计方法

超宽带(UWB)由于其低检测概率(LPD)特性而很有可能成为一种用于战术隐蔽通信的技术.针对两类常用的超宽带无线电信号IR-UWB和MB-OFDM,采用最佳未知信号检测接收机,通过仿真及与直接序列扩频(DSSS)系统比较,评估了超宽带系统的隐蔽性能并提出了提高系统隐蔽性的系统设计方法,剖析了提高IR-UWB通信系统隐蔽性的实现限制.     

Indirect adaptive fuzzy control for a class of nonlinear discrete-time systems

An indirect adaptive fuzzy control scheme is developed for a class of nonlinear discrete-time systems. In this method, two fuzzy logic systems are used to approximate the unknown functions, and the parameters of membership functions in fuzzy logic systems are adjusted according to adaptive laws for the purpose of controlling the plant to track a reference trajectory. It is proved that the scheme can not only guarantee the boundedness of the input and output of the closed-loop system, but also make the tracking error converge to a small neighborhood of the origin. Simulation results indicate the effectiveness of this scheme.