离子液体催化合成阻燃剂3-羟基苯膦酰丙酸

采用两步法合成3-羟基苯膦酰丙酸(CEPPA),即以三氯化磷与苯为原料,在离子液体三乙基苄基氯化铵氯化铝([BnEt3N]Cl-xAlCl3)催化下,合成苯膦二氯(DCPP),再用DCPP与丙烯酸合成3-羟基苯膦酰丙酸(CEPPA).确定第一步最佳反应条件为:n(三氯化磷)∶n(苯)∶n([BnEt3N]Cl-xAlCl3)=3∶1∶0.025,回流温度为72℃～76℃,反应时间为6 h,产率达81.1%;第二步通过改变反应物滴加顺序及调整反应温度,得到最佳反应条件为:n(丙烯酸)∶n(DCPP)=1.30∶1.00;滴加反应阶段,控制在70℃～80℃,反应1.5～2 h后,在90℃保温反应1 h;水解反应阶段,控制在92℃～95℃反应4 h,CEPPA的产率可达91%,并解决了反应中易结块问题.     

关于乘法含幺半环的拟分配格上的半环同余及商半环

定义了乘法含幺半环的拟分配格上的容许同余族,给出了乘法含幺半环的拟分配格上的一个半环同余,得到了关于乘法含幺半环的拟分配格的商半环的一个结果．     

Structural basis of ultraviolet-B perception by UVR8

The Arabidopsis thaliana protein UVR8 is a photoreceptor for ultraviolet-B. Upon ultraviolet-B irradiation, UVR8 undergoes an immediate switch from homodimer to monomer, which triggers a signalling pathway for ultraviolet protection. The mechanism by which UVR8 senses ultraviolet-B remains largely unknown. Here we report the crystal structure of UVR8 at 1.8?? resolution, revealing a symmetric homodimer of seven-bladed β-propeller that is devoid of any external cofactor as the chromophore. Arginine residues that stabilize the homodimeric interface, principally Arg?286 and Arg?338, make elaborate intramolecular cation-π interactions with surrounding tryptophan amino acids. Two of these tryptophans, Trp?285 and Trp?233, collectively serve as the ultraviolet-B chromophore. Our structural and biochemical analyses identify the molecular mechanism for UVR8-mediated ultraviolet-B perception, in which ultraviolet-B radiation results in destabilization of the intramolecular cation-π interactions, causing disruption of the critical intermolecular hydrogen bonds mediated by Arg?286 and Arg?338 and subsequent dissociation of the UVR8 homodimer.     

山西沁河上游河岸植被缓冲带综合评价

在对河岸带特性进行调查的基础上,针对我国北方河岸带的特点,从河流健康状况、岸坡稳定性、河岸带土壤条件、河岸带植被条件等4个方面选取16个指标,运用层次分析法,构建了河岸植被缓冲带综合评价体系,并将河岸带生态系统的状态分为4个等级:理想状态、良好状态、一般自然状态和较差状态。运用该体系对山西省沁河的一级支流赤石桥河和紫红河的河岸植被带现状进行评价,结果显示赤石桥河处于"良好状态",紫红河处于"一般状态"。     

一种低噪声高PSRR的LDO线性稳压器

介绍了 LDO线性稳压器的系统组成原理,分析了系统的电源电压抑制比(PSRR)以及噪声与电路结构的关系,在此基础上,对LDO的核心电路模块进行了设计,并基于0.5μm标准CMOS工艺,运用Cadence平台进行了模拟仿真和验证.测试结果表明:该LDO的PSRR最低约为-45 dB@1 MHz,最高约为-75 dB@217 Hz;输出电压噪声在10 Hz频率以下约为0.78 μV(P-P),在10 Hz至l00 kHz频率范围内约为0.1 μV(RMS),能满足低噪声和高PSRR应用的要求.     

Single atoms in the ring lattice for quantum information processing and quantum simulation

We have demonstrated preparing and rotating single neutral rubidium atoms in an optical ring lattice generated by a spatial light modulator, inserting two atoms into a single microscopic optical potential efficiently by dynamically reshaping the optical dipole trap, trapping single atoms in a blue detuned optical bottle beam trap, and confining single atoms into the Lamb-Dicke regime by combining red and blue detuned optical potentials. In combination with the manipulation of internal states of single atoms, the study is opening a way for research in the field of quantum information processing and quantum simulation. In this paper we review the past works and discuss the prospects.     

Degradation of the antibiotic sulfamonomethoxine sodium in aqueous solution by photo-Fenton oxidation

In this study, photo-Fenton oxidation was applied to degradation of sulfamonomethoxine sodium (SMMS) in aqueous solution. The operation parameters of pH, temperature, and concentrations of H2O2, Fe2+ and SMMS were investigated. The optimum conditions for the photo-Fenton process were determined as follows: [SMMS]=4.53 mg/L, pH 4.0, [H2O2]=0.49 mmol/L, [Fe2+]= 19.51 μmol/L and T=25°C. Under these conditions 98.5% of the SMMS degraded. The kinetics were also studied, and degradation of SMMS by the photo-Fenton process could be described by first-order kinetics. The apparent activation energy was calculated as 23.95 kJ/mol. Mineralization of the process was investigated by measuring the chemical oxygen demand (COD), and the COD decreased by 99% after 120 min. This process could be used as a pretreatment method for wastewater containing sulfamonomethoxine sodium.     

La2O3-Al2O3-SiO2 glass-infiltrated 3Y-TZP all-ceramic composite for the dental restorative application

The 3 mol％ yttria stabilized tetragonal zirconia polycrystals (3Y-TZP) powder had three particle size distributions,while the fine one was lower than 100 nm.The 3Y-TZP compact was prepared by dry-press...     

二阶双曲方程新非协调混合元格式分析

将非协调旋转1rot元应用到二阶双曲方程,建立了一个新的混合元格式.直接利用单元插值的性质,平均值及导数转移技巧,在正方形网格上,分别得到了原始变量及通量的H1-模及L2-模最优误差估计.