Acylation of nitriles to β-ketonitriles catalyzed by a heterometallic alkoxide cluster of neodymium and sodium： NdNa8（O^tBu）10（OH）

Catalytic acylation of nitriles with esters in the presence of 10 mol% NdNa8(OtBu)10(OH) is developed.The procedure is suitable for both enolizable and nonenolizable esters and affords β-ketonitriles in moderate to high yields.The heterometallic alkoxide cluster NdNa8(OtBu)10(OH) is structurally characterized by X-ray diffraction,and a mechanism for the production of β-ketonitriles using the cluster is proposed and verified.     

基于结构化模型驱动的稳控装置动作模拟仿真方法

提出了一种基于结构化模型驱动的稳控装置动作模拟仿真方法.通过对稳控装置模型的结构化,将其稳控策略组织为四元表形式(即故障、运行方式、潮流水平和控制策略),并将其控制策略分解为控制方式、控制量、控制量实施原则、控制对象队列和约束5个基本元素,在此基础上归纳出直接型、顺序型、循环型和最优型四种基本的控制策略结构化模型.进一...     

发展公民教育应当注意的两个问题

公民是构成社会的基本要素,公民素养水平的高低直接关系到社会的发展进程和社会的文明程度。在如何开展公民教育,如何提高公民素养的研究过程中,我们遇到很多问题。首先,在观念上厘清＂公民教育＂与＂西方民主＂的关系,是清除思想障碍,在我国顺利开展公民教育的关键;其次,在实施过程中,应尊重社会历史发展的规律,充分利用社会实践和社会各方面力量,做到社会制度的建设与公民素养教育同步进行。     

宜万铁路岩溶隧道施工地质技术

以宜万铁路岩溶隧道的施工地质技术实践为例，介绍了施工地质作为工程勘察阶段工程地质勘探在施工阶段的延续，用以在施工过程中解决勘察阶段所没有或不能解决的工程地质问题。施工地质以超前地质预测预报为主体，以规避大型施工地质灾害为目的，在施工阶段针对可能发生的隧道围岩变更；可能存在的溶腔、断层构造、地下暗河的预测预报；可能引发的水文环境地质问题；工程竣工以后可能存在的隐伏地质病害等，在隧道施工环境条件下为保证施工进度、保证施工安全、保证工程效益、保证工程质量所进行的综合工程地质工作。施工地质包括综合超前地质预报、水文观测和隧道周边及隧底隐伏岩溶探查。     

烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH）的合成及催化性能初探

用定量加入NaOH的方法高产率地合成了烷氧基稀土钠簇合物SmNa8（O^t Bu）10（OH），并对其进行了X射线晶体结构鉴定．此外，将其对芳醛的Tishchenko反应的催化活性进行了初探．     

复合土工膜不同锚固方式的力学特性对比研究

复合土工膜作为一种新型的防渗结构体应用于堆石坝工程，效果突出，但是在土工膜的锚固处容易产生应力集中，出现“端部固定效应”．本文结合国外某工程实例，应用商业软件FLAC3D，采用三维显式有限差分法分别对不同锚固方式情况下复合土工膜的应力、变形进行计算分析．结果表明，采用不同的土工膜锚固方式对其受力有一定的影响，在实际工程中，应采用合适的复合土工膜锚固方式改善土工膜的受力状态，减小“端部固定效应”的影响     

浅述外围护结构的建筑节能技术

外围护结构在建筑节能中起着重要作用,对外围护结构进行合理的设计选择,能极大地降低建筑能耗.文章针对外围护结构,从墙体、屋面、门窗3方面提出了一些提高外围护结构热保温性能的措施,从而改善建筑节能,以供借鉴.     

Facile construction of novel CoMoO4 microplates@CoMoO4 microprisms structures for well-stable supercapacitors

A simple and controllable strategy has been developed to fabricate CoMoO_4 microplates/CoMoO_4 microprisms(CMCMs) structures on Ni foam via a facile, cost-effective, two-step hydrothermal route. The as-grown 3D architecture exhibited excellent areal capacitance of 4.33 F cm~(-2)at a galvanostatic chargedischarge current density of 50 mA cm~(-2)(6 Ag~(-1)) and outstanding cycle performance with only 2.8%degradation over 6500 cycles in the 3 M KOH solution. The asymmetric all-solid-state supercapacitors based on activated carbon(AC) and CMCMs exhibited much better electrochemical performance than the symmetric counterpart, showing an areal capacitance of 95.22 mF cm~(-2)at the current density of 12 m A cm~(-2)and excellent cycling stability with 92.27% of the initial capacitance after 5000 cycles. These results may provide useful guidelines for materials selection and configuration designs for the novel energy storage devices based on Co Mo O4 components and substrates.     

Abrupt onset of a second energy gap at the superconducting transition of underdoped Bi2212

The superconducting gap--an energy scale tied to the superconducting phenomena--opens on the Fermi surface at the superconducting transition temperature (T(c)) in conventional BCS superconductors. In underdoped high-T(c) superconducting copper oxides, a pseudogap (whose relation to the superconducting gap remains a mystery) develops well above T(c) (refs 1, 2). Whether the pseudogap is a distinct phenomenon or the incoherent continuation of the superconducting gap above T(c) is one of the central questions in high-T(c) research. Although some experimental evidence suggests that the two gaps are distinct, this issue is still under intense debate. A crucial piece of evidence to firmly establish this two-gap picture is still missing: a direct and unambiguous observation of a single-particle gap tied to the superconducting transition as function of temperature. Here we report the discovery of such an energy gap in underdoped Bi2Sr2CaCu2O8+delta in the momentum space region overlooked in previous measurements. Near the diagonal of Cu-O bond direction (nodal direction), we found a gap that opens at T(c) and has a canonical (BCS-like) temperature dependence accompanied by the appearance of the so-called Bogoliubov quasi-particles, a classical signature of superconductivity. This is in sharp contrast to the pseudogap near the Cu-O bond direction (antinodal region) measured in earlier experiments.     

关于一类不定方程有解的一般性结论

用模型论的方法证明了一类不定方程a1xr11 a2xr22 ... anxrnn=bys(其中a1,...,an,b为任意整数,r1,...,rn,s为任意正整数)有解.进一步地,我们用相同的方法解决了一个猜想.