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931.
932.
933.
934.
935.
936.
Conclusion The results of pulse radiolytical research on the · OH radical-induced oxidation of NDM in aqueous solution demonstrate that
pH value has a great influence on the radiolytical mechanism of NDM. At low pH value, the product is mainly stabilization
of the oxidizing sulfur centre in the three-electron-bonded cation radical NDM2 ·+ [S]; with the increase of pH value, NDM2 ·+ [S] gradually decays to become the reducing α-amino radical which was verified by the chemical method and whose yield was
also calculated. Compared with Met2 ·+ [S] produced by the · OH radical-induced oxidation in aqueous solution [1], the stability of NDM2·+ [S] increases and the yield of α-amino radical decreases. This suggests that the introduction of phosphoryl group has a coordinating
effect on the radioprotection of methionine to biological systems, and provides the essentially theoretical foundation for
the thorough clarification of the reversible phosphorylation of proteins. 相似文献
937.
It is proposed that a segment of Er-doped fiber with a couple of fiber gratings on the ends may be used as a novel optical
bistability device with low power and high speed. Operation and bistability threshold of device are analysed in accordance
with the distributed feedback couple-mode theory and the nonlinear characteristic of Er-doped fiber. It is shown that a nanoseconds
microwatts bistable operation of a centimeter device is realizable under nowaday technological condition.
Supported by the National Natural Science Foundation of China
Zhang Yuancheng: born in Aug. 1938. Professor 相似文献
938.
On abiogenic natural gas 总被引:4,自引:0,他引:4
Xianbin Wang Chunyuan Li Jianfa Chen Xinyu Xia Zhanqian Guo Hongsen Xie 《科学通报(英文版)》1997,42(16):1327-1327
939.
Zhou Xiaohai Deng Lizhi Wu Xuye Zhang Shaohui Liu Shengquan Huang Suqiu Qu Songsheng 《武汉大学学报:自然科学英文版》1997,2(4):484-488
Thermodynamic data were determined for the reversible binding of O2 to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge
(abbreviated to Co2PP8 and Co2PP4) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P
1/2) and hill coefficient (n) at 298 K were determined as follows:P
1/2=54.2 kPa,n=2.0 for Co2PP8 andP
1/2=6.8 kPa,n=1.8 for Co2PP4, respectively. The rate equations of reversible oxygen binding by Co2PP8 were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there
exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes
formed in the solutions are of superoxo (Co-O
2
−
) type.
Supported by the Research Foundation of the State Education Commission of China
Zhou Xiaohai: born in 1962, Ph.D. Associate professor 相似文献
940.
Wang Tianzhi Li Weiping Wu Dingquan Wan Hongwen Yang Feng Qu Songsheng 《武汉大学学报:自然科学英文版》1997,2(4):511-513
The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ
r
H
m
, ΔG
o
, ΔG
T
≠
and kinetic parameters (K
m
,k
2) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state
theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate
complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state
interactions are by nature inhibitory and only waste catalytic power.
Supported by the National Natural Science Foundation of China
Wang Tianzhi: born in 1968. Ph D 相似文献