Preparation of MCM-41-supported chiral Salen Mn （Ⅲ） catalysts and their catalytic properties in the asymmetric epoxidation of olefins

A secondary amino-modified mesoporous molecular sieve MCM-41 was obtained by reaction of bis(3-(triethoxysilyl)propyl)amine with MCM-41. The chiral Salen-Mn (III) complex was anchored onto the modified MCM-41 by a multi-step grafting method and two heterogenized catalysts with different Mn contents were obtained. The catalysts were characterized by XRD, N2 adsorption, ICP, FT-IR and DR UV-Vis. Their catalysis on asymmetric epoxidation of several olefins was studied with NaClO and m-CPBA as oxidants respectively. It was found that both the activity and enantioselectivity of the cata- lysts decreased after the homogeneous catalyst was heterogenized. The reasons resulting in the de- crease of catalytic performance were discussed.     

Mechanism of the interaction between Au nanoparticles and polymerase in nanoparticle PCR

Nanoparticle PCR is a novel method to optimize DNA amplification. It performs well in improving specificity, enhancing sensitivity and speed. Several mechanisms were proposed in previous studies: one was based on the interaction between gold nanoparticles (AuNPs) and DNA while the other was attributed to the heat transfer property of AuNPs. In this paper, we propose that the interaction between AuNPs and DNA polymerase can significantly influence PCR. First, the addition of DNA polymerase can eliminate the inhibitory effects of excess AuNPs. Second, the addition of AuNPs will increase yield of the desired PCR product and make the optimum concentration of DNA polymerase move to higher value. Third, while excess polymerase might inhibit amplification efficiency, AuNPs can reverse this process and the yield of PCR amplification. Based on these results we propose a possible mechanism that AuNPs might modulate the activity of polymerase and improve PCR amplification.     

中国居民生活方式和能耗关系的研究

近年来，随着经济的快速发展和人民生活水平的不断改善，中国居民的生活能耗持续增长．由发达国家和地区的先进经验可知，居住建筑的特点和居民的日常生活方式都对居住建筑能耗有影响．为了清楚了解居住建筑能耗与生活方式之间的关系，开找出4常生活甲有利于节能的措施，笔者在2006／2007平4个孕节中各选择一周，对杭州地区100户家庭进行了能耗和生活方式的调查．经过统计分析，发现居民日常生活方式与能耗有密切联系，并找到了一些日常生活中有利于节能的合理措施；而且通过在调查中对居民进行节能教育后，发现居民的节能意识和行为都有一定的改善，并伴随能耗的降低．     

抗粘、耐酸汽车钢化玻璃油墨的制备与性能

采取自制的调墨油、耐酸钢化颜料黑(低熔点玻璃粉和高温陶瓷黑色素的混合物)和助剂制备了抗粘、耐酸的汽车钢化玻璃油墨,进行了同步热分析,并采用SEM和XRD研究了烧结温度和时间对油墨釉层表面析晶、表面形貌及其对釉层光泽度和耐酸性的影响,确定了油墨的最佳烧结温度和时间.结果显示:低熔点玻璃粉的软化点为512℃,与调墨油树脂的最终分解温度(470℃)较接近,从而在600～700℃的烧结温度范围内可以充分熔融流动并代替树脂作为连结料;钢化颜料黑在579.4℃开始析晶,起到了降低油墨烧结温度和抗粘的作用;采用SEM和XRD研究了烧结温度和时间对油墨釉层表面析晶、表面形貌及对釉层光泽度和耐酸性的影响,确定了油墨的最佳烧结温度和时间分别为660℃和4 min;所制备的油墨具有良好的抗粘性、耐酸性以及较好的光泽度.     

A new estimator of covariance matrix via partial Iwasawa coordinates

This paper is concerned with the problem of improving the estimator of covariance matrix under Stein’s loss. By the partial Iwasawa coordinates of covariance matrix, the corresponding risk can be split into three parts. One can use the information in the weighted matrix of weighted quadratic loss to improve one part of risk. However, this paper indirectly takes advantage of the information in the sample mean and reuses Iwasawa coordinates to improve the rest of risk. It is worth mentioning that the process above can be repeated. Finally, a Monte Carlo simulation study is carried out to verify the theoretical results.     

Ruin probabilities with pairwise quasi-asymptotically independent and dominatedly-varying tailed claims

This paper considers the nonstandard renewal risk model in which a part of surplus is invested into a Black-Scholes market whose price process is modelled by a geometric Brownian motion, claim sizes form a sequence of not necessarily identically distributed and pairwise quasi-asymptotically independent random variables with dominatedly-varying tails.The authors obtain a weakly asymptotic formula for the finite-time and infinite-time ruin probabilities.In particular,if the claims are identically distributed and consistently-varying tailed,then an asymptotic formula is presented.     

浅谈高速公路电子监控系统应用

随着社会经济的发展,高速公路运输需求日益增长,交通拥挤严重,安全事故频频发生.这一问题己成为长期困扰人们的难题.高速公路电子监控系统作为智能交通运输系统的一部分,对该问题的解决给出了可行的方案.     

Characterization of microbe cementitious materials

A new generation of cement, microbe cement, has been developed in response to the ever increasing awareness of environmental protection. Microbe cement is a new strengthening material based on microbiologically induced precipitation of calcium carbonate. This paper confirms the feasibility of binding loose sand particles using microbe cement and details the cementation mechanism of microbe cement. We have also prepared microbe cementitious materials (biosandstones). The compressive strength of the bio-sandstone, which depends on the content of calcium carbonate produced by microbially induced precipitation and the bio-mediated calcite crystal size, could be up to 12 MPa at an age of 20 days. By increasing the precipitated calcite content, the compressive strength and microstructure of bio-sandstone could be improved.     

Initializing K-means Batch Clustering: A Critical Evaluation of Several Techniques

K-means clustering is arguably the most popular technique for partitioning data. Unfortunately, K-means suffers from the well-known problem of locally optimal solutions. Furthermore, the final partition is dependent upon the initial configuration, making the choice of starting partitions all the more important. This paper evaluates 12 procedures proposed in the literature and provides recommendations for best practices.     

云南省边境县域产业结构空间差异分析

利用偏离一份额分析模型对云南省边境县域GDP及第一、二、三产业数据进行分析，结果表明：云南省边境县域产业结构模式相同的在空间分布上趋于相对集中；第一产业对边境县域经济增长起到主要推动作用的有勐腊县；第二产业对边境县域经济增长起到阻碍作用的有贡山县、盈江县、江城县、勐海县、绿春县、金平县；第三产业对边境县域经济增长起到主要推动作用的有腾冲县、瑞丽市、潞西市、景洪市、勐海县、富宁县；根据增长分量、产业结构分量、总偏离量将边境县城经济发展类型划分为发展优势区、发展平衡区、发展劣势区3种类型．