PI/TiO2纳米复合膜的H2/CH4和H2/N2分离性能

以可溶性聚酰亚胺为基质 ,经乙酸修饰后的钛酸丁酯为TiO2 溶胶前体 ,NMP为共溶剂 ,采用溶胶凝胶法可制得PI/TiO2 纳米复合膜。采用XPS、TEM和气体透气性能测试等手段 ,对复合膜的结构和H2 分离性能进行了表征。结果表明 ,复合膜中钛酸丁酯已转化为TiO2 ,PI与TiO2 两相结合完好。TiO2 以颗粒状均匀分布在PI基质中 ,其颗粒粒径约为 1 0nm。复合膜的H2 ,N2 和CH4 透气系数随着TiO2 含量的增加而明显增加。当TiO2 含量为2 2 3 %时 ,对H2 的透气系数为 1 4 .1Barrer,对H2 /N2 和H2 /CH4 的分离系数分别为 1 87.5和 1 4 3 .2 ,因此 ,该复合膜是一种较为理想的H2 分离和回收膜材料     

HV/CVD Grown Relaxed SiGe Buffer Layers for SiGe HMOSFETs

High-vacuum/chemical-vapor deposition (HV/CVD) system was used to grow relaxed SiGe buffer layers on Si substrates. Several methods were then used to analyze the quality of the SiGe films. X-ray diffraction and Raman spectroscopy showed that the upper layer was almost fully relaxed. Second ion mass spectroscopy showed that the Ge compositions were step-graded. Transmission electron microscopy showed that the misfit dislocations were restrained to the graded SiGe layers. Tests of the electrical properties of tensile-strained Si on relaxed SiGe buffer layers showed that their transconductances were higher than that of Si devices. These results verify the high quality of the relaxed SiGe buffer layer. The calculated critical layer thicknesses of the graded Si1-xGex layer on Si substrate and a Si layer on the relaxed SiGe buffer layer agree well with experimental results.     

2-氨基-3-氰基-4-(2’,4’-二氯苯基)-4H-萘并[1,2-b]吡喃的合成和晶体结构

标题化合物C22H17Cl2NO3的晶体由α-乙氧羰基-2,4-二氯肉桂腈、β-萘酚在TEBA存在下合成并经DMF与水的混合溶剂重结晶而得.其结构通过元素分析、IR和1HNMR进行了表征,用X射线单晶衍射法测定了该化合物的晶体结构.结果表明,晶体属于单斜晶系,P21/n空间群。a=1.450 5(2)nm,b=0.903 7(1)nm,c=1.491 3(2)nm,α=90°,β=101.21(1)°,γ=90°,Mr=414.27,V=1.917 5(4)nm3,Dc=1.435 g·cm-3,Z=4,μ(MoKα)=0.362 mm-1,F(000)=856.晶体结构用直接法解出,经全矩阵最小二乘法修正,最终偏离因子R=0.044 44,Rw=0.117 7.化合物分子中,原子C(1),C(2),C(3),C(4),C(5)和O(1)形成一个六元环,该六元环中C(1)-C(2)键长为0.134 6(3)nm,表明为双键.此六元环为船式构象.     

卫星闪电定位校正

从卫星资料处理出发，分析了雷暴云在多通道卫星云图上的基本特征，提出了利用多通道数字化卫星云图判识雷暴云的方法。在判识出雷暴云的基础上，对其中心进行定位，并利用其定位结果，对闪电定位仪测得的闪电资料进行校正，以提高闪电定位仪的定位精度及卫星资料判别雷暴云的正确率。初步分析表明，利用卫星定位对闪电定位进行校正，对闪电资料的定位精主工有较大的提高，得到了较好的结果。     

中国西部绿化对东亚季风气候影响的数值模拟

中国西部大开发战略中的生态环境建设将在西部地区引起显著的地表覆盖变化。根据最新的全球地表特征数据库资料和21世纪初中国西部生态环境三大重点建设工程的具体规划，得出两种植被，即现实植被和虚拟植被。并利用RIEMS—TEA模式，通过一次敏感性试验，发现西部地区绿化明显影响东亚的季风系统和中国东部季风区气候。模拟试验显示，中国西部绿化会明显增强东亚夏季风，这将会加强中国东部由南向北的水汽输送，并有利于输送邻近海洋的水汽到大陆，使得中国大陆东部季风区整体出现降温、增湿和降水增加。而且，温度、湿度、气压和风速受影响的程度在垂直方向上都已超出了边界层之外。     

Structural Changes of Polyethylene Terephthalate Fibers Grafted by Acrylamide

A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed.     

The Effect of Strain Rate on Tensile Properties of Cotton Yarns

The effect of strain rate on tensile properties of cotton yarns is analyzed using the standard linear solid model. The tensile curve, breaking strength and work of rupture of the yarns under different strain rate are calculated. A good correlation exists between the experiment results and theoretical anticipations.     

鄂尔多斯盆地低渗透油田注水开发的调整与优化

根据鄂尔多斯盆地成功开发的主要特低渗油田——安塞、靖安、华池油田长6、长3油层的储层特征及开发实践,提出了改善特低渗油田注水开发效果的注采参数、注水方式优化及调整技术,从而达到提高单井产量及最终采收率,降低开发投资和生产成本,以提高整体开发效益的目的.     

双向偏压剪反复扭构件抗震性能试验研究

通过对 8根承受双向偏压力、剪力作用的钢筋混凝土柱在低周反复扭矩作用下的抗震性能试验 ,对钢筋混凝土复合受扭构件的破坏形态、滞回曲线、延性及耗能、承载力、刚度及滞回阻尼等特性以及轴压比、相对偏心距对它们的影响进行了分析 .并通过空间变角桁架理论推导出扭矩、轴压力、双向弯矩和双向剪力间的承载力相关公式 ,最后通过相关公式和试验结果拟合出极限扭矩实用计算公式 .分析表明公式计算值与试验值符合较好     

抗菌剂及抗菌材料的发展和应用

综述了近年来抗菌剂在国内外的研究开发及抗菌材料的应用发展状况，探讨了抗菌剂在今后几年内的发展方向，指出国内抗菌剂在发展中需要注意的问题。