五台山滹沱群SHRIMP锆石U-Pb年龄: 华北克拉通早元古代拼合新证据

采自五台山台怀镇南8 km处滹沱群变质火山-沉积岩层中的长英质凝灰岩样品含有两组锆石, 所记录的SHRIMP锆石方法²⁰⁷Pb/²⁰⁶Pb年龄分别为2180±5 Ma和2087±9 Ma. 在误差范围内, 较老的一组年龄与五台山大洼梁花岗岩年龄相当, 表明它们来自相似的地壳岩浆源; 而较年轻的一组锆石年龄与相邻地区阜平杂岩湾子表壳岩中变沉积岩和变火山岩及南营花岗片麻岩年龄相当, 因而被解释为滹沱群火山作用年龄. 这两组年龄的存在表明: (1) 滹沱群形成于早元古代而非太古宙; (2) 早元古代火山-沉积作用在五台和阜平地区同时间发生. 这样, 早元古代沉积作用在该区是广泛的, 它们代表了华北克拉通东部陆块西侧大陆边缘相沉积. 滹沱群火山作用年龄的确定也表明该群所经历的变质-变形事件发生在2087±9 Ma 之后, 这进一步佐证我们最近根据其他方面研究结果所得出的吕梁造山事件(约1.8 Ga)是该区主要构造事件的结论: 该事件导致华北克拉通东部陆块和西部陆块的最终拼合, 并成为全球早-中元古代超级大陆组成部分之一.     

近红外光谱技术鉴别海面溢油

近红外光谱技术分析速度快、效率高、成本低、重现性好,典型的无损分析;主要用于样品类别鉴定和纯度检验.近红外光谱技术结合模式识别方法,在纯品油种类的鉴别中已得到成功应用[1,2],本实验室也初步建立了纯品油近红外谱图数据库[3],但该法在实际海面溢油样品的鉴别中应用仍甚少.     

一类带有奇异项的临界椭圆方程正解的存在性

研究了一类带有负指数项和Sobolev-Hardy临界项的半线性椭圆方程，运用变分法证明了正解的存在性。     

正常赖默—悌曼反应研究:超声波辐射与相转移催化合成方法

系统研究了正常及反常赖政－悌曼反应（NormalorAbnormalReliner－TiemannReavction，NRYorART）；研究了相转移住化方法和超声波辐射技术及其在正常Reliner—Tiemann（NRT）反应中的应用，从而使反应条件温和，效率增加，对邻比大，时间缩短，取得较好收效。     

卟吩质子化过程结构变化的理论研究

用ＡＭ１ＭＯ方法计算了质子化卟吩的构型，并通过结构分析、电荷布局分析和前线轨道分析，讨论了其质子化过程的构型变化及Ｒａｍａｎ光谱变化的原因。     

Two classes of metabolites fromTheonella swinhoei are localized in distinct populations of bacterial symbionts

The marine spongeTheonella swinhoei (lithistid Family Theonellidae, Order Astrophorida) has yielded many important, bioactive natural products, most of which share structural features with bacterial natural products. The presence of microbial symbionts inT. swinhoei has been reported, and it was originally suggested that the cytotoxic macrolide swinholide A and many of the bioactive cyclic peptides fromT. swinhoei were all produced by symbiotic cyanobacteria. By transmission electron microscopy, we found four distinct cell populations to be consistently present inT. swinhoei: eukaryotic sponge cells, unicellular heterotrophic bacteria, unicellular cyanobacteria and filamentous heterotrophic bacteria. Purification and chemical analyses of each cell type showed the macrolide swinholide A to be limited to the mixed population of unicellular heterotrophic bacteria, and an anti-fungal cyclic peptide occurred only in the filamentous heterotrophic bacteria. Contrary to prior speculation, no major metabolites were located in the cyanobacteria or sponge cells.     

Induction of autotomy in the American bird grasshopperSchistocerca americana (Drury) by the ecdysone agonist RH-5849 and investigation of its mode of action

The non-steroidal ecdysone agonist RH-5849 (1,2-dibenzoyl-l-tert-butylhydrazine) was found to be an effective neurotoxicant on injection into the American bird grasshopper,Schistocerca americana (Drury). Treated grasshoppers became immediately hyperactive, followed by loss of coordination, paralysis and eventually death. We also discovered that this compound induced bilateral autotomy of the metathoracic legs during the early stages of intoxication. However, no evidence of ecdysonergic or morphogenetic activities was observed. Synergism studies with neurotoxins of known mode of action suggested that RH-5849 has a mechanism of action similar to that of 4-amino pyridine, which blocks potassium channels.