Effects of baria on propane oxidation activity of Pd/Al2O3 catalyst: Pd–BaO interactio n and reaction routes

The BaO-modified Pd/Al2O3exhibits much better catalytic activity than Pd/Al2O3for C3H8 oxidation both before and after the hydrothermal aging treatment. Further studies ascribe its good activity to the influence of BaO species on the physicochemical characteristics of the catalyst and the reaction routes. Firstly, the BaO species inhibits the phase transformation of alumina, resulting in higher surface area of the catalysts and hereby a better dispersion of Pd. Secondly, the basic nature and electron-withdrawing effect of barium oxide maintain palladium at high oxidation state, which leads to a higher PdO content on surface of the BaO-modified catalyst. Finally, the formation/decomposition of carbonate/bicarbonate species can be promoted by the addition of BaO, which provide extra reaction routes and are important for the deep oxidation of C3H8.     

Ⅰ型超导体全离散T-ψ有限元法的误差估计

采用将磁场H进行T-ψ有限元分解的方法来解决Ⅰ型超导的问题,其中带有奇异核的卷积项是误差估计的关键.首先我们要给出T-ψ具体形式,以及变分形式和相关的函数空间;其次,给出全离散格式,并证明其变分问题解的存在唯一性;最后,进行稳定性研究和误差估计.     

A novel GEL-OHA/HAp bone substitute

Self-crosslinked gelatin-oxidized hyaluronic acid/ hydroxyapatite (GEL-OHA/HAp) composite bone substitute was successfully prepared with a novel in situ precipitation method without using any toxic chemical cross-linkers, and its characterizations, including elemental composition, surface morphology, crystallinity, and structure of crystalline phase, were carried out. In order to evaluate its corresponding performances, comparisons with glutaraldehyde crosslinked gelatin/hydroxyapatite (GEL-Glu/ HAp) composite were made in detail. The results indicate that nano-HAp crystallites are homogeneously dispersed in both GEL-OHA/HAp and GEL-Glu/HAp composites, and the HAp crystallites in the former take larger particle size than those in the latter. Mechanical property tests show the acceptable mechanical strength at high strain of GEL-OHA/HAp composite. Study of in vitro degradation and swelling demonstrate that the two composites have similar degradation rate and water absorption capability. By in vitro cell culture, it has been found out that the cells on the GEL-OHA/HAp composite show higher proliferative potential than the cells on the GEL-Glu/HAp composite. Compared with GEL-Glu/HAp composite, GEL-OHA/HAp composite provides an excellent strategy for preparation of non-toxic bone substitute with acceptable corresponding properties.     

酵素和生根壮苗剂对对开蕨组培苗生长的影响

以2 a生对开蕨组培苗为试验材料,0.3%尿素+0.3%磷酸二氢钾为对照,对对开蕨组培苗喷施酵素和生根壮苗剂两种叶面肥,研究两种叶面肥对其生长的影响.结果表明:随着施肥次数的增加,各处理下对开蕨组培苗生长加快,长势增强.与对照相比,叶面施肥后处理6的叶片数量、叶面积增幅最大,差异达显著水平(P0.05),处理3次之;处理5的株高、冠幅净增长量最大,差异显著(P0.05);各处理的新萌发叶片数量和孢子囊叶片数量无明显差异;处理6的比叶重见效最快,施肥后期各处理无显著差异.综合考虑,生根壮苗剂600倍最有利于对开蕨组培苗的生长,其次是1 000倍花粉酵素+700倍光合酵素+10 000倍开根酵素.     

基于多重分形理论的沥青路面集料离析评价方法

对采集的沥青道路表面数字图像进行二值化处理,通过多重测度理论计算得到沥青道路表面集料分布的谱参数,运用多重分形谱参数表征了沥青路面集料各分布状态下的离析程度。结果表明,沥青道路表面集料的分布有多重分形特性,其谱宽Δα能反映集料分布的不均匀程度,Δα越大表明集料分布越不均匀;通过白色像素占总像素的比率ε调整后的谱宽Δα′(Δα′=Δα·ε)能定量表征集料的离析程度;运用多重分形谱评价沥青道路表面集料离析是一种较为准确、高效、低成本的新方法。     

双河油田VII油组油层的灰色关联评价

本文将双河油田Ⅶ油组油层视为-个灰色系统,以各油层的评价参数构造-个标准的最佳油层。由灰色关联分析方法计算各油层与最佳油层间的关联度,根据关联度的大小对各油层进行分类评价。评价结果与实际情况吻合甚好。     

基于活动轮廓模型的DP修正算法

活动轮廓模型（ｓｎａｋｅ）是在现时图像处理和计算机视觉中用于实现对象的边缘检测或轮廓提取的有效工具．本文在讨论用最优化方法——动态规划（ＤＰ）算法求解ｓｎａｋｅ 最小能量的基础上提出了对ＤＰ的修正算法,给出了计算机模拟结果．     

时间分裂空间小波自适应方法在薛定谔方程中的应用

将时间分裂空间小波自适应方法应用于数值求解薛定谔方程(普朗克常数ε很小时). 为了得到稳定且高精度的数值格式, 采用随空间分辨率提高时间步长也自适应的逼近格式, 并给出具体的数值例子.     

基于小波自适应阈值方法的探地雷达去噪

探地雷达在实际使用过程中会被各种噪音信号干扰,针对这一问题,本文提出一种基于小波自适应阈值算法的探地雷达信号处理方法。常规小波阈值算法处理探地雷达B-scan图像时因处理前后的小波系数有所差异,可能导致图像失真。为了使目标信号更加明确,并消除噪音等干扰,通过对小波阈值的选取方式和阈值函数进行改进,使用小波变换的不同层数的子带长度确定阈值,实现阈值自适应准确量化。实验结果表明该方法相对传统小波阈值算法更加适用于探地雷达信号处理,自适应阈值函数拥有更好的良好连续性和稳定性,进一步提高了去除直达波和降噪效果,更好的保存了目标图像的细节。与其他方法对比结果表明,本文提出的算法提高了峰值信噪比,降低了图像熵。可见该方法在探地雷达实际使用情况下有一定的应用价值。     

赣东北地区下寒武统荷塘组页岩气保存条件分析

通过剖面测量等野外地质调查手段和"X"射线衍射分析等室内实验测试方法,分析了赣东北地区下寒武统荷塘组页岩气赋存的物质基础、孔隙特征、演化特征及构造发育特征等地质条件,在确认了下寒武统荷塘组页岩具有良好生烃条件的前提下,重点研究了荷塘组页岩气的保存条件及其差异性。研究结果表明:研究区页岩气保存条件整体良好,下寒武统荷塘组页岩含气量在(1.0~5.0)m3/t之间;受构造和岩浆活动的影响,不同地区页岩气保存条件存在差异;扬子地块、上饶地块及怀玉山区块在断裂、岩浆活动及成岩作用综合影响下,页岩层构造变形程度大,完整度遭到一定破坏,页岩气保存条件相对较差;玉山区块受后期构造运动影响小,岩浆活动弱,褶皱相对宽缓,下寒武统荷塘组页岩埋深和厚度大,页岩气保存条件相对较好。