影响农村留守儿童心理发展的环境因素

农村留守儿童的数量日益增多,他们出现的心理和行为问题及由此带来的各种不良影响逐渐引起社会和学者的重视。文章提出,家庭、学校、社会三方面是影响农村留守儿童心理发展的重要环境因素,并详细论述了三个因素对留守儿童心理发展带来的影响。     

Primary Sn-rich titianite in the Qitianling granite, Hunan Province, southern China: An important type of tin-bearing mineral and its implications for tin exploration

The Qitianling calc-alkaline granite in Hunan Province (South China) has attracted much attention since the discovery of the Furong super-large tin deposit. The present study provides new mineralogical data to address their implications for exploration of tin deposits. In the Taoxiwo granite in the southeastern part of the Qitianling granite body, Sn-rich titanite was identified as an important type of Sn-bearing mineral. The titanite commonly occurs with biotite as euhedral crystals, exhibiting typical envelope-like shape and sector-zoning texture. These indicate that the titanite most likely crystallized in the magmatic stage. Electron-microprobe analyses show that the titanite is enriched in tin up to 1.12 wt% SnO₂, with an average of 0.43 wt%. With the crystallization of the granite, primary minerals undertook hydrothermal alteration by magma-derived fluids. Subsequently, in the hydrothermal stage, the primary Sn-bearing titanite was altered (at least partially), but still preserved its typical envelope-shaped outline. Micro-scale cassiterite is a representative product of such alteration; other secondary minerals include fluorite, ilmenite, Sn-bearing rutile and quartz. Therefore, the titanite, commonly present in the calcalkaline granites, can be treated as an important Sn-carrying mineral in the Qitianling granite, reflecting the primary magmatic environment with tin enrichment. The hydrothermal alteration of the primary titanite and subsequent crystallization of cassiterite recorded a process of leaching and accumulation of tin in magmatic-hydrothermal evolution of the Sn-bearing granite. Thus, this titanite has important implications for tin exploration. Supported by National Natural Science Foundation of China (Grant Nos. 40730423 and 40221301) and Project of China Geological Survey (Grant No. 1212010632100)     

Variable diffusion boundary layer and diffusion flux at sediment-water interface in response to dynamic forcing over an intertidal mudflat

The diffusion boundary layer (DBL) significantly limits the exchange between sediment and overlying water and therefore becomes a bottleneck of diffusive vertical flux at the sediment-water interface (SWI). Variable DBL thickness and diffusion flux in response to dynamic forcing may influence replenishment of nutrients and secondary pollution in coastal waters. In situ measurements of velocity in the bottom boundary layer (BBL) and oxygen concentration in the DBL were made over an intertidal mudflat, using an acoustic Doppler current and mini profiler. A linear distributed zone in the oxygen profile, the profile slope discontinuity and variance of concentration can be used to derive accurate DBL thickness. Diffusion fluxes calculated from the water column and sediment are identical, and their bias is less than 6%. A numerical model PROFILE is used to simulate the in situ dissolved oxygen profile, and layered dissolved oxygen consumption rates in the sediment are calculated. The DBL thickness (0.10-0.35 mm) and diffusion flux (15.4-53.6 mmol m 2 d 1) vary with a factor of 3.5 during a tidal period. Over an intertidal mudflat, DBL thickness is controlled by flow speed U in the BBL, according to δDBL=1686.1DU 1+0.1 (D is the molecular diffusion coefficient). That is, the DBL thickness δDBL increases with decreasing flow speed U. Changes of diffusion flux at the SWI are caused by variations in the water above the sediment and the turbulent mixing intensity. The diffusion flux is positively related to the turbulent dissipation rate, friction velocity and turbulent energy. Under the influence of dynamics in the BBL, DBL thickness and flux vary significantly.     

硫氰酸钠、钾与4′-溴-5′-硝基苯并-15-冠-5固体配合物的合成及性质

在丙酮溶液中合成了两种未见报道的 4′-溴-5′-硝基苯并-15-冠-5(L)与硫氰酸钠、钾的固体配合物.对它们进行了元素分析、红外光谱、紫外光谱、差热、热重和 X-射线粉末衍射分析及摩尔电导的测定.红外光谱等结果表明—NO_2、—Br 未参与配位,而 SCN~-则以 N 作为配位原子,故可推测配合物中心离子的配位数为6.K~+与L 并非生成常见的夹心配合物,而是生成1:1型非溶剂合、不含水的固体配合物.     

基于硅胶载体表面分子印迹聚合物对牛血清蛋白识别性能

以硅胶作为载体,丙烯酰胺和2-丙烯酰胺基-2-甲基丙磺酸为双功能单体,牛血清蛋白质作为模板分子,制备了牛血清蛋白表面分子印迹聚合物,并对其制备方法、性状和性质进行了检测。结果证明制备的分子印迹聚合物大小在400 nm左右,当功能单体的配比为5∶1时为最优配比,分子印迹聚合物对牛血清蛋白质的结合在60 min时达到平衡,并且在浓度为0. 6mg·m L~(-1)的情况下,结合率达到饱和。特异性检测可知分子印迹聚合物对牛血清蛋白的结合率最高并且其印迹因子(IF)高达1. 58,说明了它对目标蛋白具有良好的选择识别能力,且重复性能好,重复检测后吸附量在80%左右。     

四川省南充市嘉陵区龙头山滑坡发育特征与形成演化

在龙头山滑坡基本发育特征详细调查的基础上,对滑坡的形成条件和演化过程进行了深入分析。滑坡的形成条件包括：（1）浅湖相和半深湖相的沉积建造是龙头山滑坡形成的物质条件;（2）斜坡多面临空的地形提供了良好的空间条件;（3）斜坡存在一组具有一定规模的NNW走向的陡倾导水横张节理系统是龙头山滑坡形成的结构条件,通过分析区域构造形迹和地表构造变形破裂认为,该组张节理是在NNW-SSE向历史构造挤压作用下形成的;（4）NNW走向的陡倾导水横张节理与暗红色泥岩顶面组成了斜坡内部的垂直和水平地下水渗透网络。滑坡的形成经历了成坡阶段、时效变形阶段和平推式滑移阶段。     

基于济宁市污染源现状分析的南四湖流域水质改善对策研究

以济宁市污染源普查数据和南四湖湖区监测结果为基础,对湖区富营养化状态和济宁市各类污染源进行了分析．2011年与2006年相比,湖区COD,氨氮,TP,TN浓度分别下降33％,53％,29％和52％,湖区水质明显改善,主要水质指标中,TP问题仍比较突出．济宁市各类污染源COD,氨氮,TP,TN排放总量分别为15．45万吨,2．59万吨,0．18万吨,3．26万吨．农业面源污染源成为首要污染源,TP,TN占所有污染源排放比例最大;生活污染源c0D排放量最大,占各类污染源COD排放总量的45．76％;工业点源污染得到治理,但对输水水质安全的影响不容忽视．提出了改善水质的合理对策和保障南水北调东线输水水质安全的合理措施．     

含未知参数的多分量Chirp信号的分数阶傅里叶分析

目的 提出基于分数阶傅里叶变换（ＦＲＦＴ）的含未知参数的多分量Ｃｈｉｒｐ信号的检测和参数估计方法。方法 由分数阶傅里叶变换的Ｃｈｉｒｐ基分解特性及其与时频分布的关系论证多分量Ｃｈｉｒｐ信号的分数阶傅里叶分析方法,并通过计算机模拟验证方法的有效性。结果与结论 和联合的Ｗｉｇｎｅｒ－Ｖｉｌｌｅ分布（ＷＶＤ）及Ｈｏｕｇｈ变换（ＨＴ）方法相比,基于ＦＲＦＴ的含未知参数的多分量Ｃｈｉｒｐ信号的分析方法,不用     

基于Apriori算法的多维关联规则挖掘研究

关联规则是数据挖掘中的一个重要研究方向.经典的Apriori算法是一种最有影响的挖掘布尔型关联规则频繁项集的算法,但其并不适合挖掘近年来兴起的多维数据模型.在改进Apriori算法的基础上,提出了一种"二次剪枝"的算法,此算法适用于挖掘多维关联规则,并且在一定程度上提高了算法效率.     

Mechanism of brittle-ductile transition of a glass-ceramic rigid substrate

The hardness, elastic modulus, and scratch resistance of a glass-ceramic rigid substrate were measured by nanoindentation and nanoscratch, and the fracture toughness was measured by indentation using a Vickers indenter. The results show that the hardness and elastic modulus at a peak indentation depth of 200 nm are 9.04 and 94.70 GPa, respectively. These values reflect the properties of the glass-ceramic rigid substrate. The fracture toughness value of the glass-ceramic rigid substrate is 2.63 MPa·m1/2. The material removal mechanisms are seen to be directly related to normal force on the tip. The critical load and scratch depth estimated from the scratch depth profile after scratching and the friction profile are 268.60 mN and 335.10 nm, respectively. If the load and scratch depth are under the critical values, the glass-ceramic rigid substrate will undergo plastic flow rather than fracture. The formula of critical depth of cut described by Bifnao et al. is modified based on the difference of critical scratch depth