低温热解脱氧方法研究

为研究低煤化度煤含氧官能团的化学活性及其改性机理，通过对低温热解方法条件的确定，建立了实验室规模低温热解脱氧方法，进一步考察了该方法的效果。结果表明，在实验室采用此法研究低煤化度煤低温热解脱氧是可行的。     

The strong cooperativity of dioxygen binding by dicobalt (II) diporphyrin compounds in nonaqueous solution at room temperature

Thermodynamic data were determined for the reversible binding of O₂ to two compounds of dicobalt(II) di(meso-tetra-phenyl)porphyrin derivatives with different lengths of diamidoaliphatic bridge (abbreviated to Co₂PP₈ and Co₂PP₄) in N,N-dimethylformamide at room temperature. The partial pressure of dioxygen necessary for half-oxygenation (P _1/2) and hill coefficient (n) at 298 K were determined as follows:P _1/2=54.2 kPa,n=2.0 for Co₂PP₈ andP _1/2=6.8 kPa,n=1.8 for Co₂PP₄, respectively. The rate equations of reversible oxygen binding by Co₂PP₈ were determined and the reaction path was proposed. The results of ther-modynamic and kinetic studies indicate that there exists strong cooperative effect during oxygenation of the compounds. The ESR observation reveals that the dioxygen complexes formed in the solutions are of superoxo (Co-O ₂ ⁻ ) type. Supported by the Research Foundation of the State Education Commission of China Zhou Xiaohai: born in 1962, Ph.D. Associate professor     

Studies on the reaction between Laccase ando-methoxyphenol by microcalorimetry

The reaction between Laccase ando-methoxyphenol have been studied by LKB-2107 batch microcalorimetry system. Thermodynamic parameters Δ _r H _m , ΔG _o , ΔG _T ^≠ and kinetic parameters (K _m ,k ₂) have been determined. The process of the reaction has been analyzed from changes in energy by using the transition state theory. Two methods for enhancing catalytic power of Laccase are proposed. The results shown that formation of an enzyme-substrate complex is “anticatalytic”. The enter and sole source of catalytic power is the stabilization of transition state; reactant-state interactions are by nature inhibitory and only waste catalytic power. Supported by the National Natural Science Foundation of China Wang Tianzhi: born in 1968. Ph D     

全层片组织 TiAl 基合金室温断裂机理的研究

在ＳＥＭ和ＴＥＭ下对Ｔｉ３３Ａｌ３Ｃｒ０．５Ｍｏ合金全层片组织薄板状和薄膜状试样分别进行了动态拉伸，并原位观察了试样中裂纹的形核及扩展过程．发现裂纹遇到内相界面时会发生偏转或裂尖发生钝化；主裂纹主要以使剪切带断裂而与微裂纹相连接的方式扩展并沿曲折路径进行．     

一种ARROW型弯曲波导研究

分别用射线分析法和电磁场分析法，通过保角变换在直角坐标系下研究ＡＲＲＯＷ型弯曲波导特性，导出了其模色散方程（本征模方程）。经优化设计的ＡＲＲＯＷ型弯曲波导结构，使ＴＥ０模的损耗降至为０．０３２９ｃｍ＾－１。     

RESEARCH ON THE STRUCTURE AND THE PROPERTY OF THE HYGROSCOPIC AND PERMEABLE FABRIC FOR SPORTSWEAR

Two structure models for knitting fabric are set up according to the wet-heat transmission principle of the fabric. Four kinds of knitted fabrics for sportswear are designed and produced. The wet-heat property of these fabrics is researched.     

一致凸线性距离空间的最佳联合逼近性

本文证明了一致凸线性距离空间存在唯一的最佳联合逼近元。     

福泉高速公路福州连接线乌龙江特大桥方案设计

介绍乌龙江特大桥的方案设计．根据有关要求和桥址水文地质自然条件，主跨采用下承式预应力系杆钢管混凝土拱．由于建筑高度低，因而可压低引桥及路堤高度，缩短桥长，节约投资．引桥上部结构采用部分预应力混凝土设计，下部结构采用桩柱直接支承大梁，结构合理经济     

用高阶曲线有限条法分析混凝土曲线梁桥

针对工程中提出的曲线梁桥的新课题，为了有效地进行全桥分析，获取设计所需的纵向、横向内力，文章采用高阶有限条法（ＨｉｇｈｏｒｄｅｒＦｉｎｉｔｅＳｔｒｉｐＭｅｔｈｏｄ）分析等截面曲线梁桥。其形函数用Ｈｅｒｍｉｔ函数法构造，形式简洁、运用能量原理从基于薄板的几何矩阵和基于线弹性的内力矩阵导出了单元刚度矩阵，采用ＦＯＲＴＲＡＮ－７７语言完成了编程工作．经过算例比较．说明了高阶曲线有限条法的简洁性和高精度性。     

1995年兰州市少年儿童耐力素质分析

对8546名儿童12个年龄组的耐力指标进行分析,并与1985年的资料进行比较,结果表明,兰州市少年儿童耐力素质在12岁前明显低于《国家体育锻炼标准》合格标准,13岁后出现明显的城乡差别,乡村强于城市;1995年比1985年有一定的提高,个别年龄组有下降现象。