含钛高强钢中夹杂物析出行为研究

以不同钛含量(0.032%~0.153%)的高强钢为研究对象,利用SEM、EDS等对钢中氧化物及氮化物夹杂的形貌、组成、数量及尺寸分布进行表征,结合热力学与动力学计算,对TiN的析出行为进行分析。结果表明,当钢中Ti含量较低(0.032%)时,冶炼过程会形成富含MgAl_2O_4的多边形高熔点固态夹杂,易造成水口堵塞;当Ti含量大于0.106%时,钢中形成了富含TiAl_2O_5的液态球形夹杂,可通过上浮去除,不易堵塞水口;Ca处理能将低钛钢中的夹杂改性为低熔点的铝酸钙,不仅降低了水口堵塞风险,还能还原夹杂物中的Ti,提高Ti的收得率。含钛高强钢中夹杂物平均尺寸为1~2μm,氮化物平均尺寸为1~3μm,其均随着Ti含量的增加而稍有增加。当Ti含量小于0.04%时,将钢中N含量控制在0.0018%以下,能有效减小TiN的析出尺寸;当Ti含量大于0.1%时,实际工业生产中很难阻止TiN的液析,但可通过提高钢中细小氧化物的数量,来细化TiN的尺寸。     

Preparation and characterization of 3-(triethoxysilyl) propyl isocyanate self-assembled monolayer on surface of chip

Monolayer of 3-(triethoxysilyl) propyl isocyanate was prepared on the slide by self-assembled tech-nique. X-ray photoelectron spectroscopy (XPS) was employed to analyze the elementary composition of the film. Contact angle of distilled water was measured to characterize the surface state. It was shown that 3-(triethoxysilyl) propyl isocyanate had been successfully assembled on the slide. The in-crease of contact angle to 80° demonstrated that the hydrophobicity of the surface of chip was in-creased signific...     

Implementation of an efficient segregated algorithm-IDEAL on 3D collocated grid system

The segregated algorithm-IDEAL (inner doubly-iterative efficient algorithm for linked-equations) is an efficient and stable algorithm. In this algorithm, there exist inner doubly-iterative processes for pressure equation, which almost completely overcome two approximations in SIMPLE algorithm. Thus the coupling between velocity and pressure is fully guaranteed, greatly enhancing the convergence rate and stability of iteration process. In this paper, implementation of the IDEAL algorithm on a 3D collocated grid system is conducted. The interface velocity is calculated by the modified momentum interpolation method (MMIM), by which the converged result is independent of the under-relaxation factor. Finally, five three-dimensional incompressible fluid flow and heat transfer problems are provided to compare the convergence rate and robustness between the IDEAL and three other most widely-used algorithms (SIMPLER, SIMPLEC and PISO). By the comparison it can be concluded that the IDEAL algorithm is more robust and efficient than the three other algorithms. Supported by the Key Project of National Natural Science Foundation of China (Grant No. 50636050), Fundamental Projects of Research and Development in China (973) (Grant Nos. 2006CB601203 and 2007CB206902)     

新型洁厕宝蓝泡泡的研究

采用浸渍法将溶于乙醇的邻苯二甲酸二乙酯组装到Si-MCM-41的孔道中,试剂的组装量达43.5%[m（邻苯二甲酸二乙酯）/m（Si-MCM-41）];用XRD、IR和固体紫外法对试剂组装体进行了表征;通过测定组装体在载体中的各种释放性能,表明制得了邻苯二甲酸二乙酯/Si-MCM-41缓释放体系.采用同样方法得到十二烷基苯磺酸钠/Si-MCM-41缓释放体系,甲醛/Si-MCM-41缓释放体系.     

增效炔醚合成工艺的改进

为优化增效炔醚M B-599的合成工艺,改进了合成路线.以邻苯二酚为原料,经甲基化、乙酰化、还原制得1-（3,4-二甲氧苯基）乙醇,并与丙炔醇缩合为炔醚,制备端炔格氏试剂,最后与碘甲烷反应制得目标化合物,其收率与反应成本得到了一定的改善,并找到了一条新的合成路线.     

ESP课程实验教学探索

随着社会经济文化的发展和大学英语教学改革的深化,专门用途英语（ESP）课程极有可能成为21世纪大学英语课程的主流。目前,多数ESP课程教学刚刚起步,其教学方式比较单一,教学理念尚不成熟。文章以四级后续ESP《职场英语》的教学实验为实例,探讨了如何借助建构主义的理论观,在ESP课程教学中将情景式、协作式以及交际式的教学模式相结合,实现《职场英语》课程教学的实用化和趣味化。     

四苯基卟啉衍生物的合成、表征及光物理和电化学性质

为寻求更高效的发光材料,通过改进的Alder法合成了四苯基卟啉、含吸电子基团的四(对硝基苯基)卟啉和含推电子基团的四(对甲氧基苯基)卟啉,对这些化合物进行了红外、质谱、元素分析等表征,并测试了其紫外、荧光与电化学性质,探讨了取代基对卟啉化合物光物理性能及电化学性质的影响.     

光纤光栅传感系统在结构损伤识别中的应用

简述了光纤光栅传感器的传感原理,说明它具有良好的传感性能.为了表明光纤光栅传感能够用于结构的损伤识别,制作了带孔的悬臂梁结构,用盖板封住或去掉来模拟结构的完好和损伤,在结构开孔处和参考点处分别粘贴光纤光栅传感器测量结构的应变模态,通过结构应变模态在损伤前后的变化识别结构的损伤.试验结果表明,光纤光栅传感器具有很高的测量精度,能很好地识别结构的损伤.     

浅谈如何提高文献检索课的教学质量

针对学生的知识水平和结构、教师的专业素质、教学设备等影响文献检索课教学质量的因素,提出了提高文献检索课教学质量的相关策略。     

三维网络SiC_n/20Cr钢复合材料的界面固相反应及显微组织

采用真空-气铸法制备了SiCn/20Cr钢复合材料,并对SiC/20Cr钢复合材料的界面进行了研究.结果表明:SiC和20Cr在复合材料的界面产生较强固相反应,SiC分解出的Si与Fe结合生成Fe-Si化合物,SiC分解出的C以石墨态沉积下来.固相反应的区域由碳化硅反应区、金属反应区和碳沉积区组成.碳元素在碳沉积区的沉积形态与沉积点到SiC的距离有关.TEM证实了金属反应区的产物为(Cr,Fe)23C6及Fe3Si,其中Fe3Si的形成为SiC的分解提供了热力学驱动力.