Microstructure and properties of nano-TiN modified Ti（C,N）-based cermets fabricated by powder injection molding and die pressing

Powder injection molding （PIM） and die pressing were employed to fabricate nano-TiN modified Ti（C,N）- based cermets. The shrinkage behavior, microstructure, porosity, and mechanical properties of the samples with and without nano-TiN addition fabricated by PIM and die pressing were analyzed. It is demonstrated that for either PIM or die pressing, the porosities are obviously reduced, the mechanical properties are significantly improved after adding nano-TiN, and the hard particles are refined; the rim phase thickness obviously becomes thinner, and the number of dimples in fracture also increases. Compared the samples fabricated by die pressing, it is difficult for PIM to obtain dense Ti（C,N）-based cermets. Due to the too much existence of pores and isolated carbon, the mechanical properties of the sintered samples by PIM are inferior to those of the sintered ones by die pressing.     

一种改进的自适应粒子群优化算法

针对粒子群优化算法中出现对大规模问题搜索失败,分析了粒子群优化算法的收敛性,指出了粒子速度与搜索失败的关系,提出了一种根据速度信息自适应调整参数的粒子群优化算法,该算法在满足收敛性的条件下,搜索过程中粒子根据理想的速度自适应调整参数进行搜索。修改后的算法经过大量测试函数上的模拟实验验证,并与其他算法进行了比较。实验结果表明,该算法能克服基本PSO算法在求解高维、多峰等复杂非线性优化问题时易陷入局部最优和不收敛等搜索失败的问题。     

Semi-crosslinked polyacrylamides as high-resolution and dynamic self-coating sieving matrices for protein capillary electrophoresis

This paper describes non-gel capillary sieving electrophoresis employing semi-crosslinked polyacrylamide as a high performance and low viscous replaceable separation matrix for separation of non-denatured protein separation. Arising from the fine sieving and dynamic coating ability of this polymer, a mixture of basic proteins lysozyme, cytochrome C, ribonuclease A, and trypsin was resolved with excellent reproducibility. Mixing different semi-crosslinked polyacrylamides together further improves the separation. The separtion mechanism was analyzed. With network structure developed to an intermediate state between crosslinked gel and linear polymer solutions, these semi-crosslinked polyacrylamide polymers demonstrate a promise as a new class of size sieving separation medium, not only in capillary electrophoresis, but also in microfluidic chip separation schemes.     

Preparation and magnetic properties of CoFe2O4/TiO2 composite films

Using （Ti（OC4H9）4） and metal chlorates as starting materials, CoFe2O4/TiO2 composite films were prepared by sol-gel method. The effects of heat treatment temperature and pH of the precursor on microstructure and magnetic properties were studied. The phase structure of the samples was examined by X-ray diffraction. The microstructure was examined by scanning electron microscope, atomic force microscope and polarized microscope. The magnetic property was measured by vibrating sample magnetometer. The results show that the crystals of different phases grow up independently. CoFe2O4 is uniformly embedded into the TiO2 matrix in the prepared composite films, and the growth of composite films is dependent on the heat treatment temperatures and PH of the precursor. The average size of CoFe2O4 crystal is 19 nm in Nanocomposite film prepared when the heat treatment temperature is 800℃ and the pH of the precursor is between 2 and 3. The magnetism of the composite films is enhanced as the heat treatment temperature increases.     

Cm·Pn的距离不大于β的任意两点可区别的边染色

给出了图Cm·Pn的距离不大于β的任意两点可区别的边色数,并研究了某些情况下Cm·Pn的点可区别的边色数.     

A geometric robust watermarking algorithm based on DWT-DCT and Zernike moments

This paper proposed a novel multibits watermarking algorithm providing robustness against geometric attacks. The robustness is achieved from three aspects： （1） Choosing the inscribed disk of the host image as the Zernike moments computation domain and the square in the disk as the watermarking embedding domain. （2） Embedding the watermark in the cascade discrete wavelet transform-discrete cosine transform （DWT-DCT） domain by modulating the specified coefficient pair in each sub block. （3） Saving two selected Zernike moments of the original watermarked image to estimate and correct the geometric attacks before watermark extraction. Experimental results show that the proposed algorithm is robust to any angle of rotation attacks and wide range of scaling attacks, and as well, a variety of other attacks such as lossy compression, common signal processing.     

基于递归网络的混沌时间序列预测

为了能对时问序列充分建模,从混沌的慨念入手,将混沌与神经网络相结合,利用人工神经网络的拟合特性,提出了递归网络的混沌时间序列预测方法。给出了递归神经网络预测的基本理论、数学模型、及具体步骤,并通过由杜芬方程所产生的混沌时间序列对该神经网络进行了模拟实验。仿真结果表明,该方法远好于前馈网络的预测效果,其预测误差在10^-15的数量级上。     

不确定离散线性脉冲系统的状态反馈镇定

从不同角度研究具有多面体参数不确定性的离散时间线性脉冲系统的鲁棒镇定问题.在系统的状态及控制量受时域约束的情况下,给出了一种能够保证闭环系统鲁棒稳定性且约束始终满足的线性状态反馈控制器设计方法.应用该方法,可以通过计算有限的线性不等式来获得鲁棒镇定控制器的反馈增益.数值仿真验证了方法的有效性.     

Effect of trace Ce and B additions on the microstructure of Nb-3Si-22Ti alloys

The effects of trace Ce and B additions on the microstructure Nb-22Ti-3Si alloys were studied. The microstructure of the alloys was observed by scanning electron microscope (SEM), and their phase compositions were analyzed with X-ray diffraction (XRD) and Electro-Probe micro-analyzer (EPMA). The distributions of the elements were detected by Spectrum analyzer. The interface of the phases in the alloys was investigated by transmission electron microscopy (TEM). The results indicated that two phases of Nbss and Nb3Si presented in Nb-22Ti-3Si, Nb-22Ti-3Si-0.2Ce and Nb-22Ti-3Si-0.2B alloys. The segregation of Ti at the interface between Nbss and Nb3Si was promoted and the volume fraction of silicides in the alloy increased with the trace B and Ce addition to the Nb-22Ti-3Si alloy respectively. And there was no single and definite orientation relationship between Nb3Si and Nbss in Nb-22Ti-3Si, Nb-22Ti-3Si-0.2Ce and Nb-22Ti-3Si-0.2B alloys. Compared with the Nb-22Ti-3Si alloy, the Nbss superlattice structure was found in Nb-22Ti-3Si-0.2Ce and Nb-22Ti-3Si-0.2B alloys.     

Al-Mg/Ti-Mg脱氧钢中夹杂物诱发点蚀行为研究

以不同脱氧方式熔炼的海洋工程用钢为研究对象,利用SEM、EDS及Image-Pro Plus 6.0软件对钢中夹杂物形貌、组成及尺寸分布等进行表征,通过3.5%NaCl溶液中阳极极化及腐蚀实验对钢中夹杂物诱发点蚀的行为进行探究。结果表明,与Al-Mg脱氧钢相比,Ti-Mg脱氧钢中形成了含有TiO_x的复合氧化物,夹杂数量更多且平均尺寸更小(小于1μm),有利于MnS的异质形核析出及弥散分布;低腐蚀活性的含TiOx复合氧化物及高度分散、异质局部析出MnS夹杂具有较低的点蚀敏感性及自腐蚀催化作用,降低了点蚀的诱发及扩展,有效提高了钢的抗点蚀性能。