MgCl2.6H2O.2CH3CoN（CH3）2的制备与表征

配合物 MgCl_2·6H_2O·2CH_3CON(CH_3) _2(CH_3CON(CH_3) _2简称 DMA)经化学分析和 x-射线结构分析,确定其化学式为[Mg(H_2O)_4(DMA)_2] Cl_2·2H_2O,晶体属单斜晶系,空间群 C_2,晶胞参数:a=1. 6391nm,b=0. 8012nm,c=0. 7374nm,β=91. 28,z=2. 晶体结构是用 Patterson 法和 Fourier 合成法解析的,经全矩阵最小二乘法修正。最后 R 因子降至0. 090. 结果表明,配合物晶体中 Mg~(2+)与四个 H_2O 分子和两个 DMA 分子以八面体方式相连,形成配阳离子[Mg(H_2O)_4(DMA)_2] ~(2+),两个 Cl~-离子和其余的两个 H_2O 分子分别充填于这些配离子之间.本文还对该配合物进行了 IR、TG-DTG 等研究.     

Diurnal freeze/thaw cycles of the ground surface on the Tibetan Plateau

The exchange of energy and water between the lithosphere and atmosphere mainly takes place at the ground surface. Therefore, freeze/thaw condition at the ground surface is an important factor in ex- amining the interactions between the land surface and atmosphere. Based on the observation data obtained by CEOP/CAMP-Tibet, the diurnal freeze/thaw cycles of the ground surface near Naqu, central Tibetan Plateau was preliminarily analyzed. The results show that the surface layer was completely frozen for approximately one month. However, the time that the ground surface experienced diurnal freeze/thaw cycles was about 6 months. The high frequency of freeze/thaw cycles at the ground surface significantly influences water and energy exchanges between ground and atmosphere over half a year. The interaction processes between the ground and atmosphere under different soil conditions (such as complete thaw, complete freeze and diurnal freeze/thaw cycles) are issues worthy of further examina- tion.     

基于MEMS技术微型蒸汽压缩式热泵的研制

利用微电子机械系统技术,基于无排气阀微型三角转子压缩机的优化设计,研制了微型蒸汽压缩式热泵的样机.考虑了压缩机与动力系统的匹配问题,对微型空冷冷凝器、微型蒸发器及毛细管长度的匹配进行了实验研究.研制的微型热泵重4 kg,几何尺寸为260 mm×250 mm×120 mm,可以产生约300 W的制冷量,制冷系数cCOP达2.0以上,采用高效锂离子电池作为动力,可持续稳定运行90 min.     

微波法合成含1,1’-联萘骨架的对称酰胺型开链冠醚

在微波辐射条件下高效合成了3种含1,1’-联萘骨架的对称酰胺型开链冠醚,产物结构经IR,1 H-NMR进行了表征.结果表明,该方法具有反应步骤短,时间短,产率高等优点,是合成含1,1’-联萘骨架的对称酰胺型开链冠醚的有效方法之一.     

A huge oceanic-type UHP metamorphic belt in southwestern Tianshan, China: Peak metamorphic age and P-T path

Recent progress in the study of the UHP metamorphic belt in southwestern Tianshan, China, is summarized in this paper. This about 80-kin-long and over 10-km-wide UHP belt has been recognized by the discovery of coesite, coesite pseudomorphs and other UHP minerals. It is the largest oceanic-type UHP metamorphic belt reported so far. It has formed due to northward subduc- tion of the Tianshan Paleo-Ocean. U-Pb dating of metamorphic rims of zircons from a coesite-bearing garnet-phengite schist yields a peak UHP metamorphic ages of 320±3.7 Ma. Combined with ages of 233-226 Ma obtained from rims of zircons from retrograded eclogites, a long retrograde metamorphic evolution （〉70 Ma） has been revealed. According to phase equilibria mod- eling, the P-T paths of both coesite-bearing eclogites and garnet-phengite schists are characterized by thermal relaxation, i.e., the metamorphic temperature peak lags behind the pressure peak, indicating that the UHP rocks experienced slow and long heating and decompression during exhumation in the subduction channel. On the basis of the field observation that a small amount of eclogite lenses is wrapped in large volumes of metapelites, and the similar P-T paths of both rock types, we propose that the ex- humation of the UHP eclogites from southwestern Tianshan, China, may have resulted from the exhumation of large volumes of low-density metapelites, which carried the denser eclogites to the Earth＇s surface.     

佳禾沟泥石流堆积物的粒度与强度关系分析

佳禾沟位于云南省维西县中路乡佳禾村,历史上曾多次发生不同规模的泥石流,并造成了人员伤亡和财产损失。通过对沟道流域沿线不同位置取样,用泥石流颗粒标度分析法并结合强度实验,发现佳禾沟泥石流松散堆积物的颗分参数μ与P(D_2)之间存在线性关系,这说明μ影响了泥石流的启动;物源区中的细颗粒的迁移、上游泥石流部分物质的随机性停歇和沟道支沟和主沟陡坡物质的随机性补给导致了颗分参数(μ,D_c)的波浪式发展。黏聚力c与μ之间的关系为线性关系,c随着μ的增加而增加。这说明细颗粒的组成控制了黏聚力c的大小,因此推断黏聚力受到细颗粒之间的胶结作用和静电作用等因素的影响。内摩擦角φ与Dc之间的关系为负线性相关,而φ随着D_c的增加而变小,粗颗粒决定了φ的发展。因此,在相同条件下,较大的μ和较小的D_c组合的土体,其强度较大;这从定量的角度上验证了颗粒级配与土体强度的关系。以上结论是否适用于其他流域需进一步验证。此外,还应结合颗粒形状,土动力学,渗透理论分析泥石流发生机理。     

Excel求解线性方程组及其在化学中的应用

运用Excel的函数功能和规划求解功能可以求解线性方程组。文章给出了Excel求解线性方程组的三种方法，并举例说明了其在化学中的应用。     

一种齿轮强度可靠性设计的改进方法

在原先齿轮强度可靠性设计中,强度和应力均按正态分布近似处理,计算精度较低。将齿面接触疲劳强度按威布尔分布、应力按正态分布处理,将齿根弯曲疲劳强度和应力均按对数正态分布处理,再根据平均安全系数和可靠度之间的关系,推导出了齿轮强度可靠性设计和校核公式。通过改进,使齿轮强度可靠性计算精度有所提高。     

The L-shell ionization of Ho and Os induced by electron impact

The atomic inner-shell ionization cross section in- duced by electron impact is a basic topic in atomic physics and radiation physics. Since the 1930s, a great number of experimental and theoretical studies have been done[1―6]. In basic research, it is a…     

紫藤化学成分和药理活性研究进展

紫藤是豆科紫藤属植物,作为观赏植物在我国多地有栽培。在民间,紫藤常常被用于治疗腹水浮肿、关节肿痛、通风、小便不利等病症。前期研究表明紫藤含丰富的化学成分,包括萜类、黄酮类、酚类、生物碱、凝集素类、有机酸等;紫藤的粗提物和单体成分表现出多种药理活性,如抗氧化、降血压、抗癌、抗病毒作用、抑菌作用、凝集作用等,说明紫藤具有重要的药物研究价值。然而,迄今为止有关紫藤化学成分和药理活性研究的工作仍未见综述报道,因此,本文首次对紫藤的化学成分和药理活性的研究进行系统综述,将为更深层次的开发利用紫藤药材资源提供理论依据。