Low temperature hydrothermal synthesis and electrochemical performances of LiFePO4 microspheres as a cathode material for lithium-ion batteries

Mesoporous LiFePO4 microspheres were simply synthesized by a low temperature(130℃),template-free hydrothermal route using low cost LiOH,Fe(NO3)3 and NH4H2PO4 as starting raw materials.These microspheres are composed of densely aggregated LiFePO4 nanoparticles and filled with interconnected mesochannels,which demonstrates not only a high tap density(≥1.4 g cm-3),a high capacity of 150 mAh g-1(～90% of its theoretical capacity) at 0.5 C rate,but also a ≥ 80% utilization of its theoretical capacity at a high rate of 1 C.In addition,the hydrothermal synthesis developed in this work is simple and cost-effective,it may provide a new route for production of the LiFePO4 material in battery applications.     

加固用CFRTP模压成型工艺及片材力学性能研究

针对传统的混凝土结构加固用纤维增强热固性复合材料的一系列缺点，提出用热塑性树脂来制备加固用复合材料．并且研究了连续芳纶纤维Keylar49增强热塑性树脂基复合材料的模压成型工艺和片材力学性能．所研制的复合材料力学性能达到国外现有加固材料指标．纤维和片材的SEM照片表明该材料的破坏是韧性破坏，且纤维和树脂存在最佳配比，在该配比下树脂能良好地浸润纤维束．     

R600a/CO2一级分凝和二级分凝自复叠制冷循环的性能研究

基于天然工质应用于自复叠制冷循环的研究，对一级分凝和二级分凝自复叠制冷循环进行了理论分析，讨论了使用天然工质R600a／CO2作为非共沸制冷剂时制冷剂的配比、冷凝温度、蒸发温度和冷凝蒸发器冷凝侧出口过冷度对2种循环系统性能的影响．结果表明：2种循环均存在最佳的制冷剂配比，其中二级分凝循环还存在最佳中间温度；在一定的冷凝温度和蒸发温度下，二级分凝自复叠制冷循环与一级分凝自复叠制冷循环相比，性能系数大，单位质量制冷量大，压力比高；随着冷凝温度和蒸发温度的升高，二级分凝循环的性能系数提高得更多．     

中山川油区储层物性及裂缝特征研究

通过大量的岩心观察、铸体薄片鉴定、岩心和薄片的古地磁定向分析,以及油井注水实验结果的分析,对中山川油区长4+5—长6储层的物性及裂缝特征进行了研究.结果表明:油区的主力油层以低成熟度的细粒—中粒长石石英砂岩为主,储层孔隙种类较多,原生的粒间孔及次生的溶蚀孔为储层的主要储集空间;储层水平和网状裂缝非常发育,具有张裂缝特征,构造型的NE向裂缝占主要地位.在区域最大主应力的控制下,人工压裂裂缝的方向主要为NE-NNE向.     

Wavelet fractal character of overlapping signal

A new method based on the combining of the wavelet theory with the fractal theory and named wavelet fractal peak position method (WFPPM) is introduced to extract the number of the components and the relevant peak positions from overlapping signals in chemistry .The overlapping signal is first transformed into continuous wavelet transform value of time domain in certain dilation range via continuous wavelet transform (CWT),and then changed into capacity dimensions (Dc),The number of the components and the relevant positions of overlapping peaks can be identified easily according to the change of Dc.An investigation concerning the influence of different dilation ranges on the peak positions extracted by WFPPM is also provided .Studies show that the WFPPM is an efficient tool for extracting the peak positions and identifying the number of peaks from unresoloved signals,even when this kind of overlapping is significantly serious,Relative errors of lless than 1.0% in peak positions are found when WFPPM is used in the processing of the cadmium (Ⅱ)-indium(Ⅲ) mixture system .The analytical results demonstrate that the desired peak positions can be extracted conveniently ,accurately and rapidly from an unresoled signal via WFPPM,Tremendous developing and applications based on currently reported WFPPM in extracting overlapping signals would be expected in the near future.     

SOI双槽隔离结构的耐压特性

理论推导了绝缘体上硅(SOI)双槽隔离结构的耐压模型.该模型表明,在SOI双槽隔离结构中,因隔离氧化层压降的不均衡,高压侧隔离氧化层提前发生介质击穿,从而导致SOI双槽隔离结构的临界击穿电压小于理论值.增大沟槽纵横比和减小槽间距可以减弱隔离氧化层上压降的不均衡性,提高SOI双槽隔离结构的临界击穿电压.Sentaurus器件仿真软件的模拟结果和华润上华半导体有限公司0.5μm 200 V SOI工艺平台下的流片测试结果均证明,减小槽间距和增大沟槽纵横比是提高双槽隔离结构临界击穿电压的有效方法,同时也证明了该耐压模型的正确性.     

燃烧室结构形状对柴油机经济性和排放的影响

对于直喷式柴油机来说，燃烧室结构形状直接影响到燃烧室的气体运动及燃烧过程的进行．最终影响柴油机的经济性和排放性能．本文从小型直喷式柴油机的燃烧过程出发，通过试验对比．结合缸内燃烧放热过程的计算，分析探讨了三种燃烧室结构形状对燃烧放热及柴油机性能的影响，为设计开发新产品提供一定的参考依据．     

闭环供应链定价模型及实证分析

在随机需求条件下,构建基于制造商、零售商和第3方物流商(3PL)组成的具有产品再制造功能的闭环供应链定价模型.分别在集中决策与分散决策情况下,采用博弈理论对模型进行分析.结果表明：相对于分散决策而言,集合决策下销售价格更低、回收价格更高、销售量更大,集中决策的系统利润明显大于分散决策.通过对机电行业的实证分析,证明了闭环供应链定价模型的有效性和实用性.     

明胶包埋壳聚糖/海藻酸钠茶多酚的缓释性能

以海藻酸钠和壳聚糖为壁材制备了茶多酚微胶囊,确定了最佳制备工艺条件为壳聚糖质量分数1．0％、海藻酸钠质量分数2．0％～3．0％、氯化钙质量分数5．0％,所制得的茶多酚微胶囊的包埋率最大,用明胶包埋茶多酚微胶囊,制备了茶多酚缓释复合体系,结果表明,用明胶包埋后的微胶囊可使茶多酚的缓释性能及稳定性有较大的提高。     

复杂地形下甘肃舟曲江顶崖滑坡自动提取方法

为精确获取甘肃省舟曲县南峪乡江顶崖在复杂地形下的滑坡区域分布,利用数字正射影像和数字高程模型准确获取滑坡区域,分析滑坡信息。在基于影像监督分类的基础上,叠加一定的影响因子约束分析进一步筛选滑坡区,利用数学形态学中的腐蚀、膨胀、开运算三种运算方式处理图像实现对滑坡区域自动识别提取。实验结果说明通过与数字正射影像叠加解译和在精度评价中生产者精度为81.25%,用户精度为92.85%验证能够较好地避免因复杂地形中丰富地物类型所带来的干扰,实现对复杂地形下舟曲县南峪乡江顶崖滑坡的自动识别提取,结果表明三种方法的结合可以为识别提取复杂地形下的滑坡区域提供借鉴。