Shear-thickening behavior of Fe-ZSM5 zeolite slurry and its removal with alumina/boehmites

A cryogenic scanning electron microscopy (cryo-SEM) technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were found to contain agglomerations, which may break the flow of the pastes and cause shear-thickening behaviors. However, the shear-thickening behaviors can be eliminated by the addition of halloysite and various boehmites because of improved particle packing. Furthermore, compared with pure Fe-ZSM5 zeolite samples and its composite samples with halloysite, the samples with boehmite (Pural SB or Disperal) additions exhibited network structures in their cryo-SEM images; these structures could facilitate the storage and release of flow water, smooth paste flow, and avoid shear-thickening. By contrast, another boehmite (Versal 250) formed agglomerations rather than network structures after being added to the Fe-ZSM5 zeolite paste and resulted in shear-thickening behavior. Consequently, the results suggest that these network structures play key roles in eliminating the shear-thickening behavior.     

WO3 nanoflakes decorated with CuO clusters for enhanced photoelectrochemical water splitting

The low quantum efficiency arising from poor charges transfer and insufficient light absorption is one of the critical challenges toward achieving highly efficient water splitting in photoelectrochemical cells. Three dimensions(3D) structures and heterojunctions have received intensive research interests recent years due to their excellent ability to separate photo-generated charges as well as the enhanced light harvesting property. Herein,3 D Cu O/WO_3 structure was fabricated through a facile solvothermal method followed by chemical bath deposition. The loading of Cu O clusters on WO_3 nanoflake arrays results in a much improved photocurrent density compared with that of pristine WO_3 nanoflake arrays, which reaches 1.8 m A/cm2 at 1.23 V vs. the reversible hydrogen electrode. The electrochemical impedance spectroscopy measurement demonstrates that the improved performance of Cu O/WO_3 electrode is attributed to the accelerated charge transfer kinetics as a result of the desirable band alignment in Cu O/WO_3 heterojunction. This work demonstrates a facile strategy to construct superior WO_3 electrode, which will ultimately allow for efficient storage of solar energy into hydrogen.     

不同株系丹参有效成分比较研究

为比较不同株系之间丹参有效成分的差异,采用高效液相色谱法测定丹参中包括丹参酮ⅡA在内的4种脂溶性成分和包括丹酚酸B在内的3种水溶性成分的含量,并应用SPSS软件对所得数据进行分析。通过对两大类成分的比较,发现10种株系丹参中,3、7号株系的脂溶性成分含量较高,可考虑培育为脂溶性成分提取原料;而1、9、10号株系的水溶性成分较高,可考虑培育为水溶性成分提取原料。显著性分析结果表明,所测10种不同株系丹参在其主要水溶性和脂溶性成分上存在显著差异。该研究可以为丹参优良种质的筛选提供依据。     

模糊综合评价法在低碳新农村发展评价中的应用——以河北省为例

对低碳新农村发展水平进行评价能够更好地了解其发展状况,指导低碳新农村建设.从构建低碳新农村发展水平评价指标体系出发,利用模糊综合评价法构建评价模型,对低碳新农村发展水平进行综合评价,并通过河北省低碳新农村发展水平评价的实例对模型进行了验证.     

基于3S技术的辽宁省凌河口湿地生态环境需水量研究

以3S技术为基础,对研究区内土地利用信息进行提取,并对凌河口湿地功能区进行划分,这是凌河口湿地生态环境需水计算的数据基础。根据凌河口湿地的具体情况,其生态环境需水量由湖泊-养殖塘生态需水、芦苇和水稻生态需水、湿地土壤生态需水组成。综合分析生态环境需水的现有计算方法,结合凌河口湿地各生态系统类型的特点,建立适合于研究区的生态环境需水计算方法。计算结果表明:适宜生态环境需水量为28 666×104 m3/a;多年平均降雨下的最小生态环境需水量为7 174×104m3/a,并给出了不同降雨频率下的最小生态环境需水量。为便于水资源配置,给出了适宜与最小生态环境逐月用水过程。     

论锦州港在粮食物流黄金水道中的作用

港口在黄金水道中发挥着重要作用,港口的发展对黄金水道影响深远,港口物流在现代物流体系中占有重要地位。作为黄金水道重要港口之一的锦州港,加强其港口物流建设,对黄金水道乃至中国的整体粮食物流发展都具有重要意义。     

荧光法测定海洋生物体中石油烃总量

将生物样品经氢氧化钠皂化,采用二氯甲烷萃取,残留物用石油醚溶解,采用荧光分光光度计,于激发波长310 nm,发射波长360 nm处进行总量测定.分析结果表明,方法的检测下限值为1.89μg/L,重复性较好.样品分析结果精密度,其相对误差不超出8%,准确度内控样加标,回收率测定结果在86%~102%之间.     

基于GM(1,1)模型的高速公路边坡稳定性研究

目的由于气象、地形及施工条件等的影响,高速公路边坡可能会发生滑塌,造成巨大的危害。针对边坡稳定性问题,分析边坡稳定性的影响因素。方法以现场边坡监控数据为依据,运用灰色预测GM(1,1)模型进行边坡稳定性预测。结果研究结果表明模型预测值与实测值误差较小,采用该预测模型可为技术人员提供数据支持,并根据所预测的结果来采取必要的安全措施以保证边坡的稳定性。结论灰色理论的运用和必要的监控对于确保边坡安全具有重要的指导意义。     

XML查询中的频繁路径选择

 提出了满足DTD结构情况下XML查询语句中频繁路径的选择算法,即从大量的XML查询路径表达式中找出最频繁出现的路径.首先对XML查询语句进行离散化处理,然后基于不产生候选集的频繁模式挖掘算法,实现了XML频繁查询路径的选择,最后基于DTD结构重构包含频繁路径的XML查询.实验研究表明,所提出方法具有一定的有效性及合理性.     

基质吸力对非饱和粉质砂土抗剪强度的影响

从宏观吸力控制型直剪试验和微观土体颗粒结构分析两方面入手,在压力板仪试验分析非饱和粉质砂土水土特性的基础上,采用不同吸力条件下的直剪试验和2种不同含水量土样结构的微观扫描研究,分析非饱和粉质砂土抗剪强度和基质吸力之间的关系。研究结果表明:与黏性土不同,当粉质砂土含水量逐渐降低时,土体基质吸力对土体抗剪强度的贡献效果并不是一直增加,而是存在一个"峰值效应",这种现象的出现是由于粉质砂土微观结构的组成特点以及随含水率减小所含水分的存在形式不断改变这两方面因素,致使基质吸力作用面积不断变化造成的。另外,土体的应力环境也会影响吸力对土体强度贡献的大小。