Statistical models for intensity and phase fluctuation of laser light in a turbulent medium

The probability density function of irradiance fluctuations in a turbulent atmosphere remains an open topic of research.It is generally considered that the speckle field has an elliptical-Gaussian speckle distribution,but because of its complexity there is still no exact analytical solution.By introducing the concept of random fluctuation intensity and using an equiprobability density ellipse,exact models of the random fluctuation intensity and its phase are proposed.Through theoretical analysis and numerical simulation,it is concluded that the random fluctuation intensity and its corresponding phase are independent only under the circular-Gaussian approximation.     

A gas chromatography/mass spectrometry method for the simultaneous analysis of 50 phenols in wastewater using deconvolution technology

Phenolic compounds exist widely in the influents and effluents of sewage treatment plants (STPs) and most are un-regulated. In this study, a gas chromatography-mass spectrometry (GC-MS) method for the simultaneous analysis of 50 phenolic compounds in wastewater was developed. Deconvolution technology was used to identify contaminants that are covered by co-extracted materials. A mass spectral library containing all 50 silylated phenolic compounds was first established and used for deconvolution. Twelve typical phenolic compounds were selected to optimize the sample preparation procedures. Solid-phase extraction using a C18 cartridge coupled with an HLB cartridge was used for pre-concentration and dichloromethane was used for elution. The solutes were derivatized and analyzed by GC-MS. The blank and matrix spike recoveries ranged from 57.46% to 136.4% and 47.87% to 114.8%, respectively. Method detection limits ranged from 3.64 to 97.64 ng L⁻¹. The relative standard deviations of all the recovery experiments were lower than 13.6%. The instrument limits of quantification ranged from 0.7 to 87.7 pg. The method has been applied to analyze the influents and effluents of 5 Chinese STPs. Except for regulated phenolic compounds (phenol and 2,4,6-trichlorophenol), three un-regulated phenolic compounds, including 2-chlorophenol, 2,5-dichlorophenol and 2,4-dichloro-3-ethyl-6-nitrophenol were identified in the effluent wastewater. The detected concentrations of un-regulated phenolic compounds could possibly cause environmental effects, indicating that immediate attention is required to prevent complications.     

Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au （111） surface

The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.     

14种高原植物抑制植物病原菌活性的初步研究

采用生长速率法检测了11科14种高原植物的乙醇提取物对6种植物病原真茵的抑制活性.实验结果显示,在样品的作用浓度为1 mg/mL时,香青、铁线莲、露蕊乌头的乙醇提取物对苹果腐烂病原茵有明显的抑制作用,抑制率分别为77.10%、68.14%、67.53%;香青、露蕊乌头、金露梅、木鳖子对苹果炭疽病原茵也有值得关注的抑制作...     

斜纹夜蛾核多角体病毒感染甜菜夜蛾细胞的研究

 研究发现斜纹夜蛾核多角体病毒（Spodoptera litura nucleopolyhedrovirus,SpltNPV）不能成功感染同属甜菜夜蛾（S. exigua,Se）昆虫,为深入研究SpltNPV在离体Se301细胞中的感染进程以及病毒感染失败的原因,对感染后Se301细胞进行DNA复制、病毒基因转录以及病毒蛋白表达等检测。结果显示被感染的Se301细胞中病毒完成了DNA的复制和病毒早、晚期基因转录,但检测不到极晚期基因多角体基因（polyhedrin）的表达,病毒的蛋白表达受阻从而影响了病毒完成复制周期。 研究发现病毒蛋白表达受阻是SpltNPV在Se301细胞中无法形成子代病毒,完成整个病毒复制的主要原因,这为深入研究其感染失败机理奠定了坚实基础。     

纳米CaCO3 对物理老化前后PC/PS性能的影响

 通过差示扫描量热法和动态力学分析对PC/PS/纳米CaCO3和PC/PS/包覆纳米CaCO3复合材料物理老化前后PS相的玻璃化转变、β松弛及动态力学性能进行了研究。结果表明：纳米CaCO3有利于PS相的分子链段松弛运动,PC/PS/纳米CaCO3复合材料PS相的Tg、损耗模量峰温和β松弛温度下降;包覆纳米CaCO3增加相界面间相互作用,PC/PS/包覆纳米CaCO3复合材料PS相的Tg、β松弛温度、储存模量和损耗模量峰温均较PC/PS/纳米CaCO3提高。随着物理老化时间的延长,PC/PS及复合材料PS相的Tg和β松弛温度提高,松弛热焓ΔH增加,其中,PC/PS/包覆纳米CaCO3的提高幅度较小。物理老化使得PC/PS/纳米CaCO3的存储模量提高。     

R41跨临界单级压缩带回热器热泵系统研究

建立了跨临界单级压缩带回热器热泵系统的理论模型,并对R41(一氟甲烷)与CO2的循环特性进行了热力性能和火用的分析比较.结果表明:两种工质在常温下进行跨临界循环,R41系统的整体性能优于CO2系统.在选定工况下,R41系统比CO2系统的最优高压侧压力平均降低40.6%以上,系统性能系数平均提高14.2%以上,系统火用效率平均提高14.3%,且R41系统在单位质量制热量和压缩机排气温度方面均优于CO2系统.最后提出了通过减小气体冷却器传热温差、降低节流压差,以及合理利用蒸发器冷量来提高系统火用效率的观点.     

多波段光度计定标及误差分析

摘要根据Langley法定标的原理,在河北省灵寿县对4台多波段太阳光度计MICROTOPSⅡ进行定标,并采用最小二乘法得到了很好的定标结果。分别计算了仪器的视场角、通道的半波宽度、大气状况以及气体吸收等方面对定标结果造成的影响,并且对水汽吸收通道（936nm）采用修正的Langley法定标,得到4台仪器各自5个通道的定...     

单频GPS基线精化解算的经验模式分解方法

为了削弱非模型化误差对单频GPS基线解算的影响,引入经验模式分解法对原始双差观测值进行自适应滤波消噪.在此基础上应用消噪后的双差观测值结合LAMBDA方法进行整周模糊度确定,进而计算基线固定解.算例分析结果表明:此方法可以有效增强基线解算的可靠性并能明显改善定位精度.     

(2S)-cis-3-[[(2-吡咯烷基-4-巯基)羰基]氨基]苯甲酸盐酸盐的合成

报道一条适合工业化生产合成厄他培南侧链盐酸盐的方法.采用低价易得的4R-羟基-L-脯氨酸为原料,经过氨基保护、羟基活化、硫代,水解等步骤合成了标题化合物.其中除氨基保护步骤外,其余步骤采取"一锅法"合成.收率达到70.4%.