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231.
The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.  相似文献   
232.
Since Gibbs synthesized a general equilibrium statistical ensemble theory, generalizing the Gibbsian theory to non-equilibrium phenomena has been a dream for some theorists. However, the status of the theory for the non-equilibrium ensemble formalism is not as well established as the Gibbsian ensemble theory. In this work, we explore the formalism behind the non-equilibrium statistical ensemble theory based on the sub-dynamic kinetic equation originating from the Brussels-Austin school and develop...  相似文献   
233.
Almost half of the total rural area of Guizhou Province and many regions within the 11 adjacent provinces in southwestern China have a long history(at least 70 years) of endemic fluorosis,including dental fluorosis and osteofluorosis along with its associated deformities and disabilities.Over decades of research,this specific type of endemic fluorosis has been defined as coal-burning fluorosis,which is distinct from drinking-water fluorosis.It is generally acknowledged that indoor burning and combustion of high-fluorine coal leads to food contamination,and fluorine then enters the human body.However,the exact chemical form of fluorine during its release and transfer to the body is still unknown.In the present study,21 domestic coal samples from outcrop and semi-outcrop coal collected in five villages with fluorosis were analyzed by time-of-flight secondary ion mass spectrometry(TOF-SIMS).The total mass fraction of sulfur in the samples ranged from 0.24%-5.58% and total fluorine content ranged 90.2-149.2 mg/kg.H3O+,H2SO4+ and HSO4-were detected in the samples by TOF-SIMS,which indicated that sulfuric acid hydrate(H2SO4.H2O) was present in the samples.F-was detected in all of these,which suggested the samples contain ionic fluorine compounds.Under certain circumstances,such as heating or burning,the prevalence and coexistence of the acid(H2SO4.H2O) and base(F-) would lead to a neutralization reaction producing volatile hydrogen fluoride(HF,bp = 19.5℃).This would be the chemical form of fluorine released from the coal.Further studies using HF and SO2 test tubes on headspace gas over coal samples heated to 200℃ in the laboratory and on headspace gas over stoves or chimney tops at rural residences confirmed the release of HF.  相似文献   
234.
Using liquid Fe 60 Cu 40 alloy as a model, the structure of liquid Fe-Cu alloy systems is investigated in the temperature range 1200 2200 K, covering a large metastable undercooled regime, to understand the phase separation of liquid Fe-Cu alloys on the atomic scale. The total pair distribution functions (PDFs) indicate that liquid Fe 60 Cu 40 alloy is ordered in the short range and disordered in the long range. If the atom types are ignored, the total atom number densities and PDFs demonstrate that the atoms are distributed homogenously in the liquid alloy. However, the segregation of Fe and Cu atoms is very obvious with decreasing temperature. The partial PDFs and coordination numbers show that the Cu and Fe atoms are not apt to get together on the atomic scale at low temperatures; this will lead to large fluctuations and phase separation in liquid Fe-Cu alloy.  相似文献   
235.
A flat submerged membrane combined with a TiO 2 /UV photocatalytic reactor (FSMPR) was employed in batch mode to remove humic acid (HA). HA removal efficiency was characterized by UV 254 absorbance, UV-vis spectra, dissolved organic carbon (DOC) concentration, specific UV absorbance (SUVA), and trihalomethane formation potential (THMFP). The FSMPR process was effective in removing more than 86% of DOC and nearly 100% of UV 254 absorbance, while the THMFPs of samples were reduced to < 19 μ g/L after 150 min of treatment. In addition, changes in transmembrane pressure (TMP) with and without UV were evaluated; TiO 2 /UV was effective at controlling membrane fouling by HA. Analysis of the molecular weight (MW) distributions and three-dimensional excitation-emission matrix (EEM) fluorescence spectra of HAs revealed that the effectiveness in membrane fouling control is a result of changes in HA molecular characteristics. The TiO 2 /UV photocatalytic reactor caused the degradation of high MW, hydrophobic humic-like molecules to low MW, hydrophilic protein-like molecules, although this fraction was not completely removed during 150 min of treatment and was less responsible for membrane fouling.  相似文献   
236.
The present study attempts to investigate the role of rigid claws and smooth adhesive pads in the locust Locusta migratoria manilensis,when attaching to various substrates.We measured the attachment forces on sandpaper and silicate glass plate of locusts with intact attachment system,and those with either the pretarsal claws or the tarsal pads having been entirely destroyed,to explore the role of pads and claws when a locust is walking on various substrates.To obtain information about morphological characteristics and material properties of the claws,we examined the intact and fractured claws by scanning electron microscopy,and tested the fractural force in a fracture experiment.We proposed a mechanical model for locust climbing on a slanting surface to analyze the conduction and final result of the attachment forces generated by the attachment organs on the fore-,mid-and hindlegs.Attachment forces generated by locusts with destroyed pads were similar to those generated by locusts with intact attachment system on both substrates,which presumably indicated that the claws have a significantly important role when attaching to various substrates.The result of the fracture experiment demonstrated that the claws are made of relatively stiff material,and their shear strength ranged between 39-45 MPa.Mechanical analysis of locust climbing on slanting surface showed that the force generated by the hindlegs suspended the whole body of locust up from the surface and pushed the body forward,while the midlegs steadily suspended the centre of gravity and the forelegs pulled the suspended body forward.The results obtained contribute to the further interpretation of the interaction mechanisms between insect attachment system and substrates,and supply information for designing and manufacturing slippery plates for trapping plague locusts.  相似文献   
237.
Emission inventories of primary particles and pollutant gases for China   总被引:12,自引:0,他引:12  
Detailed high-resolution emission inventories of primary particles(PM2.5,BC and OC) and pollutant gases(SO2,NOx,NH3,CO and VOCs) for China in 2007 were constructed on the basis of the latest fuel consumption data,mostly at the county level,and from socio-economic statistics and data on fossil and biomass fuels obtained from government agencies.New emission factors reflecting local features were also used.The calculated emissions were 13.212 Mt PM2.5,1.4 Mt BC,2.946 Mt OC,31.584 Mt SO2,23.248 Mt NOx,16.017 Mt NH3,164.856 Mt CO and 35.464 Mt VOCs.The national and regional emissions were gridded with 0.5°× 0.5° resolution for use in air quality models.Larger emissions were found in eastern and central China than in western China.The emissions estimated here are roughly equal to those obtained in previous studies,but with different contributions from because of seasonal changes in residential heating and biomass combustion.Finally,uncertainties in inventories were analyzed.  相似文献   
238.
Denoted by M(A), QM(A) and SQM(A) the sets of all measures, quantum measures and subadditive quantum measures on a σ-algebra A, respectively. We observe that these sets are all positive cones in the real vector space F(A) of all real-valued functions on A and prove that M(A) is a face of SQM(A). It is proved that the product of m grade-1 measures is a grade-m measure. By combining a matrix M μ to a quantum measure μ on the power set A n of an n-element set X, it is proved that μ ≪ ν (resp. μ ⊥ ν) if and only if M μM ν (resp. M μ M ν =0). Also, it is shown that two nontrivial measures μ and ν are mutually absolutely continuous if and only if μ·νQM(A n ). Moreover, the matrices corresponding to quantum measures are characterized. Finally, convergence of a sequence of quantum measures on A n is introduced and discussed; especially, the Vitali-Hahn-Saks theorem for quantum measures is proved.  相似文献   
239.
Large seasonal water-level fluctuations may influence isotopic signatures of primary producers and the types and amounts of these potential food sources accessible to aquatic fauna of Poyang Lake,the largest freshwater lake in China.In this study,the isotopic signatures of primary producers and consumers were determined,stable carbon and nitrogen isotope analysis and mixing models were combined to investigate the influence of water levels on the diet and isotopic composition of Poyang Lake fish and inverteb...  相似文献   
240.
This study analyzes the changes in glacier zones and snow composition of Glacier No.1 in the Tianshan Mountains of China since 1961,and their possible relations with climate.It is found that precipitation dominated the snow composition and that air temperature and precipitation controlled the distribution of glacier zones,but interannual change in precipitation had a relatively large effect on glacier zones and snow composition during 1963–1981 (P10) and 1963–1989 (P11).However,during 1982–2007 (P20) and 19...  相似文献   
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